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      Sustainability of Southern African Ecosystems under Global Change : Science for Management and Policy Interventions 

      Catchment and Depositional Studies for the Reconstruction of Past Environmental Change in Southern Africa

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          Abstract

          Terrestrial signals in marine sedimentary archives are often used for reconstructing past environments, vegetation and climate, as well as for determining sediment fluxes, pathways, and depositional sites and changes in erosional runoff. It is therefore important to understand the origin, transport, and depositional processes of the various terrestrial sedimentary components in a depositional system. In this chapter, we use examples from southern Africa to show how source-to-sink studies have led to a clearer interpretation of downcore proxy records. Twelve rivers in four river catchment areas of various scales and in distinct climatic settings and geological formations are included in this compilation. We also discuss studies from the current-swept South African east coast, the broad western and southern margins, and investigations from protected marine embayment settings. We consider a large suite of commonly used proxies (plant wax isotopes, elemental composition, and fossil pollen) as well as hydroacoustic surveying techniques (PARASOUND and multibeam bathymetric profiling). Sampling strategies and sample types that may be used in catchment analyses are discussed. Challenges and limitations of the above-mentioned approaches are outlined. In conclusion, we underline the importance of a thorough source-to-sink approach to paleo-environmental reconstructions using terrigenous proxies.

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          Leaf epicuticular waxes.

          The external surface of the higher plants comprises a cuticular layer covered by a waxy deposit. This deposit is believed to play a major part in such phenomena as the water balance of plants and the behavior of agricultural sprays. The wax contains a wide range of organic compounds. These complex mixtures are amenable to modern microchromatographic and microspectrometric analytical procedures. The few surveys which have been made of the species distribution of certain classes of constituents indicate that such distribution may be of limited taxonomic value; however, the wax composition of a species may differ for different parts of the same plant and may vary with season, locale, and the age of the plant. This fascinating subject, in which the disciplines of botany, biochemistry, chemistry, and physics overlap and interact, is still in a very active state. Much remains to be learned about the composition and fine structure of the wax deposits, and, for this, experimental study of wax crystallization and permeation through artificial membranes will be required. Enzymic studies, radiolabeling, and electron microscopy will be needed to reveal the mode of biogenesis of the wax constituents and their site of formation and subsequent pathway through the cuticle to the leaf surface.
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            Distribution of n-paraffins as a clue to recognition of source beds

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              Molecular Paleohydrology: Interpreting the Hydrogen-Isotopic Composition of Lipid Biomarkers from Photosynthesizing Organisms

              Hydrogen-isotopic abundances of lipid biomarkers are emerging as important proxies in the study of ancient environments and ecosystems. A decade ago, pioneering studies made use of new analytical methods and demonstrated that the hydrogen-isotopic composition of individual lipids from aquatic and terrestrial organisms can be related to the composition of their growth (i.e., environmental) water. Subsequently, compound-specific deuterium/hydrogen (D/H) ratios of sedimentary biomarkers have been increasingly used as paleohydrological proxies over a range of geological timescales. Isotopic fractionation observed between hydrogen in environmental water and hydrogen in lipids, however, is sensitive to biochemical, physiological, and environmental influences on the composition of hydrogen available for biosynthesis in cells. Here we review the factors and processes that are known to influence the hydrogen-isotopic compositions of lipids—especially n-alkanes—from photosynthesizing organisms, and we provide a framework for interpreting their D/H ratios from ancient sediments and identify future research opportunities.
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                Author and book information

                Book Chapter
                2024
                January 06 2024
                : 815-843
                10.1007/978-3-031-10948-5_28
                814ab189-8557-47cd-9dd1-449fdc87efa4
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