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      Estudo das propriedades reológicas, mecânicas e de blindagem eletromagnética de misturas elastoméricas envolvendo borracha nitrílica (NBR) e borracha nitrílica carboxilada (XNBR) Translated title: Study of rheological, mechanical and electromagnetic shielding properties of Nitrile rubber (NBR) and Carboxylated Nitrile rubber (XNBR) blends

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          Abstract

          Resumo Neste trabalho foram avaliadas as propriedades reológicas, mecânicas e de blindagem eletromagnética de misturas elastoméricas envolvendo borracha nitrílica (NBR) e borracha nitrílica carboxilada (XNBR) formuladas com 30 pcr de negro de fumo condutor. As proporções de NBR/XNBR estudadas foram 100/0, 80/20, 50/50, 20/80, 10/90 e 0/100. Os resultados obtidos demonstraram que o aumento no teor de XNBR reduziu a taxa de vulcanização (CRI), contudo as propriedades mecânicas aumentaram em relação às amostras com alto teor de NBR. Através da análise de microscopia eletrônica de varredura foi observada uma melhor dispersão do negro de fumo condutor nas composições ricas em XNBR, que também apresentaram maior resistência ao inchamento. Estes resultados corroboram com os valores encontrados para a resistência à tração. A maior atenuação na faixa do radar foi observada também para a amostra contendo somente a borracha nitrílica carboxilada, o valor de atenuação encontrado foi de 50% da energia emitida, aproximadamente -3 dB.

          Translated abstract

          Abstract This work evaluated the rheological, mechanical and electromagnetic shielding properties of nitrile rubber (NBR) and carboxylated nitrile rubber (XNBR) blends added with 30 phr of conductive carbon black. The NBR/XNBR ratios studied were 100/0, 80/20, 50/50, 20/80, 10/90 e 0/100. The results obtained showed that increasing the content of XNBR in the blends, reduced the vulcanization rate (CRI), but the mechanical properties have increased in relation to the samples with high NBR content. Through the analysis of scanning electron microscopy showed that the carbon black were dispersed best in compositions rich on XNBR elastomer, these samples also showed higher resistance to swelling. Result that corroborates with the values found for tensile strength. The greater attenuation on radar range was also observed to the sample containing only nitrile rubber, the attenuation value was 50% of the absorbed energy, approximately -3 dB.

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          Most cited references20

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          Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials

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            Superhydrophobic and conductive carbon nanofiber/PTFE composite coatings for EMI shielding.

            This paper presents a solvent-based, mild method to prepare superhydrophobic, carbon nanofiber/PTFE-filled polymer composite coatings with high electrical conductivity and reports the first data on the effectiveness of such coatings as electromagnetic interference (EMI) shielding materials. The coatings are fabricated by spraying dispersions of carbon nanofibers and sub-micron PTFE particles in a polymer blend solution of poly(vinyledene fluoride) and poly(methyl methacrylate) on cellulosic substrates. Upon drying, coatings display static water contact angles as high as 158° (superhydrophobic) and droplet roll-off angles of 10° indicating self-cleaning ability along with high electrical conductivities (up to 309 S/m). 100 μm-thick coatings are characterized in terms of their EMI shielding effectiveness in the X-band (8.2-12.4 GHz). Results show up to 25 dB of shielding effectiveness, which changed little with frequency at a fixed composition, thus indicating the potential of these coatings for EMI shielding applications and other technologies requiring both extreme liquid repellency and high electrical conductivity.
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              Intrinsic electromagnetic radiation shielding/absorbing characteristics of polyaniline-coated transparent thin films

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                Author and article information

                Contributors
                Role: ND
                Role: ND
                Role: ND
                Role: ND
                Journal
                po
                Polímeros
                Polímeros
                Associação Brasileira de Polímeros (São Carlos, SP, Brazil )
                0104-1428
                1678-5169
                2017
                : 27
                : spe
                : 14-19
                Affiliations
                [01] Rio de Janeiro Rio de Janeiro orgnameUniversidade Estadual da Zona Oeste Brazil
                [02] Rio de Janeiro Rio de Janeiro orgnameUniversidade Federal do Rio de Janeiro orgdiv1Instituto de Macromoléculas Professora Eloisa Mano Brazil
                Article
                S0104-14282017000700014
                10.1590/0104-1428.1973
                034af69a-4a46-4783-8a13-ddac8de0821a

                This work is licensed under a Creative Commons Attribution 4.0 International License.

                History
                : 14 November 2014
                : 16 December 2015
                Page count
                Figures: 0, Tables: 0, Equations: 0, References: 15, Pages: 6
                Product

                SciELO Brazil


                borracha nitrílica,blindagem eletromagnética,XNBR,vulcanização,nitirle rubber,shielding electromagnetic,vulcanization

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