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      Mimicking the Natural World with Nanoarchitectonics for Self‐Assembled Superstructures

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          Abstract

          Scientists are often inspired by nature, where naturally occurring morphologies, such as those that resemble animals and plants, can be created in the lab. In this review, we have provided an overview on complex superstructures of animals, plants and some similar shapes from the natural world. We begin this review with a discussion about the formation of various animal‐like shapes from small organic molecules and polymers, and then move onto plants and other selected shapes. Literature surveys reveal that most of the polymers studied tend to form micellar structures, with some exceptions. Nevertheless, small organic molecules tend to form not only micellar structures but also other animal shapes such as worms and caterpillars. These superstructures tend to have high surface areas and variable surface morphology, making them very useful material for applications in various field such as catalysis, solar cells, and biomedicine, amongst others.

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          Functional Naphthalene Diimides: Synthesis, Properties, and Applications.

          This comprehensive review surveys developments over the past decade in the field of naphthalene diimides (NDIs). It explores their application toward: supramolecular chemistry; sensors; host-guest complexes for molecular switching devices, such as catenanes and rotaxanes; ion-channels by ligand gating; gelators for sensing aromatic systems; catalysis through anion-π interactions; and NDI intercalations with DNA for medicinal applications. We have also explored new designs, synthesis, and progress in the field of core-substituted naphthalene diimides (cNDIs), and their implications in areas such as artificial photosynthesis and solar cell technology. Also presented are some interesting synthetic routes and procedures that can be used toward further development of NDI-bearing compounds for future applications. Finally, we conclude with our views on NDI chemistry for future research endeavors, and we outline what we believe are the key obstacles that need to be overcome for NDIs to see real world applications.
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            Classification of nanostructures by dimensionality and concept of surface forms engineering in nanomaterial science

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              Self-assembled MoS2/3D worm-like expanded graphite hybrids for high-efficiency microwave absorption

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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                The Chemical Record
                The Chemical Record
                Wiley
                1527-8999
                1528-0691
                January 2023
                September 23 2022
                January 2023
                : 23
                : 1
                Affiliations
                [1 ] School of Chemical Sciences Goa University Goa 403206 India
                [2 ] School of Applied Sciences RMIT University Melbourne, Victoria 3001 Australia
                Article
                10.1002/tcr.202200180
                046b7b8e-c0a3-47b0-9b52-ad5af9c242d4
                © 2023

                http://onlinelibrary.wiley.com/termsAndConditions#vor

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