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      Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst

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          Abstract

          Magnesium bis(hydridotriphenylborate), a solvent-separated ion pair [Mg(thf) 6][HBPh 3] 2, is a versatile catalyst for hydroboration of polar unsaturated substrates including CO 2.

          Abstract

          Magnesium bis(hydridotriphenylborate), isolated as a solvent-separated ion pair [Mg(thf) 6][HBPh 3] 2, effectively catalyzed the hydroboration of several unsaturated substrates including CO 2.

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          NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

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            The Mononuclear Molybdenum Enzymes.

            Russ Hille (1996)
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              Enantioselective Organocatalytic Transfer Hydrogenation Reactions using Hantzsch Esters

              Within the realm of catalytic asymmetric hydrogenation, the focus continues to be on the use of chiral metal complexes in conjunction with a hydrogen source. Recently, the widespread development of organocatalysis, including the invention of iminium activation, has led to the discovery of many new enantioselective transformations. Based on this strategy, a number of bioinspired processes for the enantioselective organocatalytic transfer hydrogenation of alpha,beta-unsaturated carbonyl compounds and imines have been discovered. These topics will be the focus of this Account.
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                Author and article information

                Journal
                CHCOFS
                Chemical Communications
                Chem. Commun.
                Royal Society of Chemistry (RSC)
                1359-7345
                1364-548X
                2016
                2016
                : 52
                : 89
                : 13155-13158
                Affiliations
                [1 ]Institute of Inorganic Chemistry
                [2 ]RWTH Aachen University
                [3 ]Aachen
                [4 ]Germany
                [5 ]Graduate School of Engineering Science
                [6 ]Osaka University
                [7 ]Toyonaka
                [8 ]Japan
                Article
                10.1039/C6CC06805G
                0ef068df-5ae2-4d3b-9dbd-769610d84bcd
                © 2016
                History

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