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      A permittivity regulating strategy to achieve high-performance electromagnetic wave absorbers with compatibility of impedance matching and energy conservation

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          Abstract

          With the variation of permittivity, MoS 2/rGO composites with a broad frequency bandwidth and strong absorbing performance can be obtained due to their optimal compatibility of impedance matching and attenuation loss ability.

          Abstract

          Permittivity plays crucial but reverse roles in impedance matching and attenuation loss in terms of electromagnetic wave absorption. In addition to unilateral superior performance, an ideal absorber needs to take into consideration both impedance matching and energy conservation. In order to acquire absorbing materials with moderate impedance matching and attenuation ability simultaneously, we have fabricated MoS 2/rGO composites via a facile and effective hydrothermal approach. The dielectric constant of the obtained composite can be regulated by varying the molar ratio of the precursors and an optimal balance between impedance matching and energy conservation is eventually obtained upon addition of 6 mL GO. The maximum reflection loss is −67.1 dB at 14.8 GHz and the effective electromagnetic wave absorption bandwidth for RL < −10 dB covers from 12.08 to 18.00 GHz (5.92 GHz) with a small thickness of 1.95 mm. Moreover, the relationship between the matching thickness and the highest reflection loss value has also been discussed in detail. The results not only suggest that the MoS 2/rGO composites developed through a simple procedure here can act as an ideal absorber with strong absorption, a broad frequency bandwidth and small thickness, but also offer a good reference for the design of microwave absorbers, including the compatibility of impedance matching and attenuation loss ability as well as matching thickness.

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          Most cited references40

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          CoNi@SiO2 @TiO2 and CoNi@Air@TiO2 Microspheres with Strong Wideband Microwave Absorption.

          The synthesis of CoNi@SiO2 @TiO2 core-shell and CoNi@Air@TiO2 yolk-shell microspheres is reported for the first time. Owing to the magnetic-dielectric synergistic effect, the obtained CoNi@SiO2 @TiO2 microspheres exhibit outstanding microwave absorption performance with a maximum reflection loss of -58.2 dB and wide bandwidth of 8.1 GHz (8.0-16.1 GHz, < -10 dB).
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            Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam.

            The broadband and tunable high-performance microwave absorption properties of an ultralight and highly compressible graphene foam (GF) are investigated. Simply via physical compression, the microwave absorption performance can be tuned. The qualified bandwidth coverage of 93.8% (60.5 GHz/64.5 GHz) is achieved for the GF under 90% compressive strain (1.0 mm thickness). This mainly because of the 3D conductive network.
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              Single-layer MoS2 nanopores as nanopower generators

              Making use of the osmotic pressure difference between fresh water and seawater is an attractive, renewable and clean way to generate power and is known as 'blue energy'. Another electrokinetic phenomenon, called the streaming potential, occurs when an electrolyte is driven through narrow pores either by a pressure gradient or by an osmotic potential resulting from a salt concentration gradient. For this task, membranes made of two-dimensional materials are expected to be the most efficient, because water transport through a membrane scales inversely with membrane thickness. Here we demonstrate the use of single-layer molybdenum disulfide (MoS2) nanopores as osmotic nanopower generators. We observe a large, osmotically induced current produced from a salt gradient with an estimated power density of up to 10(6) watts per square metre--a current that can be attributed mainly to the atomically thin membrane of MoS2. Low power requirements for nanoelectronic and optoelectric devices can be provided by a neighbouring nanogenerator that harvests energy from the local environment--for example, a piezoelectric zinc oxide nanowire array or single-layer MoS2 (ref. 12). We use our MoS2 nanopore generator to power a MoS2 transistor, thus demonstrating a self-powered nanosystem.
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                Author and article information

                Journal
                NJCHE5
                New Journal of Chemistry
                New J. Chem.
                Royal Society of Chemistry (RSC)
                1144-0546
                1369-9261
                2017
                2017
                : 41
                : 3
                : 1259-1266
                Affiliations
                [1 ]College of Materials Science and Technology
                [2 ]Nanjing University of Aeronautics and Astronautics
                [3 ]Nanjing 211100
                [4 ]P. R. China
                [5 ]Laboratory of Solid State Microstructures
                [6 ]Nanjing University
                [7 ]Nanjing 210093
                Article
                10.1039/C6NJ03052A
                3de26edd-ab54-4183-bf44-73407b40c1f9
                © 2017
                History

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