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      Environment-friendly wood fibre composite with high bonding strength and water resistance

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          Abstract

          With the growing depletion of wood-based materials and concerns over emissions of formaldehyde from traditional wood fibre composites, there is a desire for environment-friendly binders. Herein, we report a green wood fibre composite with specific bonding strength and water resistance that is superior to a commercial system by using wood fibres and chitosan-based adhesives. When the mass ratio of solid content in the adhesive and absolute dry wood fibres was 3%, the bonding strength and water resistance of the wood fibre composite reached the optimal level, which was significantly improved over that of wood fibre composites without adhesive and completely met the requirements of the Chinese national standard GB/T 11718-2009. Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) characterizations revealed that the excellent performance of the binder might partly be due to the amide linkages and hydrogen bonding between wood fibres and the chitosan-based adhesive. We believe that this strategy could open new insights into the design of environment-friendly wood fibre composites with high bonding strength and water resistance for multifunctional applications.

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          Most cited references34

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          Observations by high-resolution carbon-13 nuclear magnetic resonance of cellulose I related to morphology and crystal structure

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            Protein adsorption of dialdehyde cellulose-crosslinked chitosan with high amino group contents.

            Crosslinked chitosan was prepared by Schiff base formation between the aldehyde groups of dialdehyde cellulose (DAC) and the amino groups of chitosan and a subsequent reduction. DAC was obtained through periodate oxidation of cellulose and solubilization in hot water at 100°C for 1h. Three grades of DAC-crosslinked chitosan were prepared by adding various amounts DAC. The degrees of crosslinking as determined by amino group content were 3.8, 8.3, and 12.1%, respectively. DAC-crosslinked chitosan showed higher stability in the pH 2-9 range and no cytotoxicity was identified over the course of a 21-day long-term stability test. Also, DAC-crosslinked chitosan showed remarkably high bovine serum albumin (BSA) adsorption capacity at pH 5.5 as a result of the increased amino group content, due to the reaction between DAC and chitosan molecular chains occurring at multiple points even though DAC-crosslinked chitosan showed a lower degree of crosslinking.
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              Collagen/cellulose hydrogel beads reconstituted from ionic liquid solution for Cu(II) adsorption.

              A novel adsorbent, biodegradable collagen/cellulose hydrogel beads (CCHBs), was prepared by reconstitution from a 1-butyl, 3-methylimidazolium chloride ([C4mim]Cl) solution. The adsorption properties of the CCHBs for Cu(II) ion removal from aqueous solutions were investigated and compared with those of cellulose hydrogel beads (CHBs). The CCHBs have a three-dimensional macroporous structure whose amino groups are believed to be the main active binding sites of Cu(II) ions. The equilibrium adsorption capacity (qe) of the CCHBs is greatly influenced by the collagen/cellulose mass ratio, and steeply increases until the collagen/cellulose mass ratio exceeds 2/1. The maximum adsorption is obtained at pH 6. The qe of Cu(II) ions increases with increased initial concentration of the solution. Based on Langmuir isotherms, the maximum adsorption capacity (qm) of CCHB3 (collagen/cellulose mass ratio of 3/1) is 1.06 mmol/g. The CCHBs maintain good adsorption properties after the fourth cycle of adsorption-desorption.
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                Author and article information

                Journal
                R Soc Open Sci
                R Soc Open Sci
                RSOS
                royopensci
                Royal Society Open Science
                The Royal Society Publishing
                2054-5703
                April 2018
                4 April 2018
                4 April 2018
                : 5
                : 4
                : 172002
                Affiliations
                Key Laboratory of Bio-Based Material Science and Technology of the Ministry of Education, Northeast Forestry University , Harbin 150040, People's Republic of China
                Author notes
                Author for correspondence: Minghui Guo e-mail: gmh1964@ 123456126.com

                Electronic supplementary material is available online at https://dx.doi.org/10.6084/m9.figshare.c.4033939.

                Author information
                http://orcid.org/0000-0002-5840-672X
                Article
                rsos172002
                10.1098/rsos.172002
                5936918
                5381a8d0-dde7-4062-b0cf-6280905377b8
                © 2018 The Authors.

                Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.

                History
                : 29 November 2017
                : 2 March 2018
                Funding
                Funded by: Special Fund for Forest Scientific Research in the Public Welfare;
                Award ID: 201504501-1
                Funded by: Fundamental Research Funds for the Central Universities;
                Award ID: 2572016AB66
                Categories
                1006
                117
                Engineering
                Research Article
                Custom metadata
                April, 2018

                wood fibre composite,chitosan-based adhesive,bonding strength,water resistance,bonding mechanism

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