(BEDT-TFF)\(_2\)I\(_3\) charge transfer salts are reported to show superconductivity and pressure induced quasi two-dimensional Dirac cones at the Fermi level. By performing state of the art ab initio calculations in the framework of density functional theory, we investigate the structural and electronic properties of the three most prominent structural phases \(\alpha\), \(\beta\) and \(\kappa\). From symmetry analysis we come to the conclusion that even under high pressure a tiny gap remains for the \(\alpha\)-phase. For the nonsymmophic \(\kappa\)-phase, under a chemical strain induced by the substitution I\(\rightarrow\)F, we find a topologically protected Dirac point. The calculated electronic structures presented here are added to the organic materials database (OMDB).