Random critical point separates brittle and ductile yielding transitions in amorphous materials

Abstract

<p id="d4318525e253">Understanding how amorphous solids yield in response to external deformations is crucial both for practical applications and for theoretical reasons. Here we show that despite large differences in the materials’ microscopic interactions, a degree of universality emerges as there are only two ways in which amorphous solids respond to a deformation: One, typical of well-annealed materials, is characterized by an abrupt failure with a macroscopic stress drop and the sudden emergence of sharp shear bands; the other, typical of poorly annealed materials, shows merely a smooth crossover. By varying the preparation protocol, one can change the response of a given material from one to the other, and this change is controlled by a random critical point. </p><p class="first" id="d4318525e256">We combine an analytically solvable mean-field elasto-plastic model with molecular dynamics simulations of a generic glass former to demonstrate that, depending on their preparation protocol, amorphous materials can yield in two qualitatively distinct ways. We show that well-annealed systems yield in a discontinuous brittle way, as metallic and molecular glasses do. Yielding corresponds in this case to a first-order nonequilibrium phase transition. As the degree of annealing decreases, the first-order character becomes weaker and the transition terminates in a second-order critical point in the universality class of an Ising model in a random field. For even more poorly annealed systems, yielding becomes a smooth crossover, representative of the ductile rheological behavior generically observed in foams, emulsions, and colloidal glasses. Our results show that the variety of yielding behaviors found in amorphous materials does not necessarily result from the diversity of particle interactions or microscopic dynamics but is instead unified by carefully considering the role of the initial stability of the system. </p>