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      Doping of Laser‐Induced Graphene and Its Applications

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          Abstract

          Laser‐induced graphene (LIG) has attracted extensive attention owing to its facile preparation of graphene and direct engraving patterns for devices. Various applications are demonstrated such as sensors, supercapacitors, electrocatalysis, batteries, antimicrobial, oil and water separation, solar cells, and heaters. In recent years, doping has been employed as a significant strategy to modulate the properties of LIG and thereby improve the performance of LIG devices. Due to the patternable manufacture, controllable morphologies, and the synergistic effect of doped atoms and graphene, the doped LIG devices exhibit a high sensitivity of sensing, pseudocapacitance performance, and biological antibacterial. This paper reviews the latest novel research progress of heteroatom and nanoparticles doped LIG in synthesis, properties, and applications. The fabrications of LIG and typical doping approaches are presented. Special attention is paid to two doping processes of LIG: the one‐step laser irradiation method and the two‐step laser modification consisting of deposition, drop‐casting, and duplicated laser pyrolysis. Doped LIG applications with improved performance are mainly highlighted. Taking advantage of doped LIG's properties and device performances will provide excellent opportunities for developing artificial intelligence, data storage, energy, health, and environmental applications.

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          Laser scribing of high-performance and flexible graphene-based electrochemical capacitors.

          Although electrochemical capacitors (ECs), also known as supercapacitors or ultracapacitors, charge and discharge faster than batteries, they are still limited by low energy densities and slow rate capabilities. We used a standard LightScribe DVD optical drive to do the direct laser reduction of graphite oxide films to graphene. The produced films are mechanically robust, show high electrical conductivity (1738 siemens per meter) and specific surface area (1520 square meters per gram), and can thus be used directly as EC electrodes without the need for binders or current collectors, as is the case for conventional ECs. Devices made with these electrodes exhibit ultrahigh energy density values in different electrolytes while maintaining the high power density and excellent cycle stability of ECs. Moreover, these ECs maintain excellent electrochemical attributes under high mechanical stress and thus hold promise for high-power, flexible electronics.
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            Roll-to-roll production of 30-inch graphene films for transparent electrodes.

            The outstanding electrical, mechanical and chemical properties of graphene make it attractive for applications in flexible electronics. However, efforts to make transparent conducting films from graphene have been hampered by the lack of efficient methods for the synthesis, transfer and doping of graphene at the scale and quality required for applications. Here, we report the roll-to-roll production and wet-chemical doping of predominantly monolayer 30-inch graphene films grown by chemical vapour deposition onto flexible copper substrates. The films have sheet resistances as low as approximately 125 ohms square(-1) with 97.4% optical transmittance, and exhibit the half-integer quantum Hall effect, indicating their high quality. We further use layer-by-layer stacking to fabricate a doped four-layer film and measure its sheet resistance at values as low as approximately 30 ohms square(-1) at approximately 90% transparency, which is superior to commercial transparent electrodes such as indium tin oxides. Graphene electrodes were incorporated into a fully functional touch-screen panel device capable of withstanding high strain.
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              The reduction of graphene oxide

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                Author and article information

                Contributors
                Journal
                Advanced Materials Technologies
                Adv Materials Technologies
                Wiley
                2365-709X
                2365-709X
                August 2023
                April 10 2023
                August 2023
                : 8
                : 16
                Affiliations
                [1 ] Institute of Photonic Chips University of Shanghai for Science and Technology Shanghai 200093 China
                [2 ] Centre for Artificial‐Intelligence Nanophotonics, School of Optical‐Electrical and Computer Engineering University of Shanghai for Science and Technology Shanghai 200093 China
                [3 ] Queensland University of Technology (QUT) Centre for Robotics Queensland University of Technology Brisbane Queensland 4000 Australia
                Article
                10.1002/admt.202300244
                37693798
                8e77fd43-45ec-48af-897e-874852f9ab6b
                © 2023

                http://onlinelibrary.wiley.com/termsAndConditions#vor

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