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      Polymerization and Applications of Poly(methyl methacrylate)–Graphene Oxide Nanocomposites: A Review

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          Abstract

          Graphene oxide (GO)-incorporated poly(methyl methacrylate) (PMMA) nanocomposites (PMMA-GO) have demonstrated a wide range of outstanding mechanical, electrical, and physical characteristics. It is of interest to review the synthesis of PMMA-GO nanocomposites and their applications as multifunctional structural materials. The attention of this review is to focus on the radical polymerization techniques, mainly bulk and emulsion polymerization, to prepare PMMA-GO polymeric nanocomposite materials. This review also discusses the effect of solvent polarity on the polymerization process and the types of surfactants (anionic, cationic, nonionic) and initiator used in the polymerization. PMMA-GO nanocomposite synthesis using radical polymerization-based techniques is an active topic of study with several prospects for considerable future improvement and a variety of possible emerging applications. The concentration and dispersity of GO used in the polymerization play critical roles to ensure the functionality and performance of the PMMA-GO nanocomposites.

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          Most cited references129

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          Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives

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            Dispersion behaviour of graphene oxide and reduced graphene oxide.

            The dispersion behaviour of graphene oxide (GO) and chemically reduced GO (rGO) has been investigated in a wide range of organic solvents. The effect of the reduction process on the GO solubility in eighteen different solvents was examined and analysed, taking into consideration the solvent polarity, the surface tension and the Hansen and Hildebrand solubility parameters. rGO concentrations up to ∼9 μg/mL in chlorinated solvents were achieved, demonstrating an efficient solubilization strategy, extending the scope for scalable liquid-phase processing of conductive rGO inks for the development of printed flexible electronics.
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              Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers

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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                15 December 2022
                27 December 2022
                : 7
                : 51
                : 47490-47503
                Affiliations
                [1]School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, Engineering Campus , 14300Nibong Tebal, Penang, Malaysia
                Author notes
                Author information
                https://orcid.org/0000-0001-8311-4932
                https://orcid.org/0000-0002-5591-6265
                Article
                10.1021/acsomega.2c04483
                9798503
                36591191
                9feaf906-5a0e-4251-97e9-16e133ab6806
                © 2022 The Authors. Published by American Chemical Society

                Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained ( https://creativecommons.org/licenses/by/4.0/).

                History
                : 19 July 2022
                : 02 December 2022
                Funding
                Funded by: Ministry of Higher Education, Malaysia, doi 10.13039/501100003093;
                Award ID: FRGS/1/2020/TK0/USM/01/5
                Categories
                Review
                Custom metadata
                ao2c04483
                ao2c04483

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