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      Evidence of water on the lunar surface from Chang’E-5 in-situ spectra and returned samples

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          Abstract

          The distribution range, time-varying characteristics, and sources of lunar water are still controversial. Here we show the Chang’E-5 in-situ spectral observations of lunar water under Earth’s magnetosphere shielding and relatively high temperatures. Our results show the hydroxyl contents of lunar soils in Chang’E-5 landing site are with a mean value of 28.5 ppm, which is on the weak end of lunar hydration features. This is consistent with the predictions from remote sensing and ground-based telescopic data. Laboratory analysis of the Chang’E-5 returned samples also provide critical clues to the possible sources of these hydroxyl contents. Much less agglutinate glass contents suggest a weak contribution of solar wind implantation. Besides, the apatite present in the samples can provide hydroxyl contents in the range of 0 to 179 ± 13 ppm, which shows compelling evidence that, the hydroxyl-containing apatite may be an important source for the excess hydroxyl observed at this young mare region.

          Abstract

          Laboratory analysis of returned Chang’E-5 samples from the lunar surface show their hydroxyl contents to be on the weak end of lunar hydration features.

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          Major lunar crustal terranes: Surface expressions and crust-mantle origins

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            Volatile content of lunar volcanic glasses and the presence of water in the Moon's interior.

            The Moon is generally thought to have formed and evolved through a single or a series of catastrophic heating events, during which most of the highly volatile elements were lost. Hydrogen, being the lightest element, is believed to have been completely lost during this period. Here we make use of considerable advances in secondary ion mass spectrometry to obtain improved limits on the indigenous volatile (CO(2), H(2)O, F, S and Cl) contents of the most primitive basalts in the Moon-the lunar volcanic glasses. Although the pre-eruptive water content of the lunar volcanic glasses cannot be precisely constrained, numerical modelling of diffusive degassing of the very-low-Ti glasses provides a best estimate of 745 p.p.m. water, with a minimum of 260 p.p.m. at the 95 per cent confidence level. Our results indicate that, contrary to prevailing ideas, the bulk Moon might not be entirely depleted in highly volatile elements, including water. Thus, the presence of water must be considered in models constraining the Moon's formation and its thermal and chemical evolution.
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              The sun’s total and spectral irradiance for solar energy applications and solar radiation models

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                Author and article information

                Contributors
                licl@nao.cas.cn
                shurong@mail.sitp.ac.cn
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                14 June 2022
                14 June 2022
                2022
                : 13
                : 3119
                Affiliations
                [1 ]GRID grid.9227.e, ISNI 0000000119573309, Key Laboratory of Lunar and Deep Space Exploration, National Astronomical Observatories, , Chinese Academy of Sciences, ; Beijing, 100101 China
                [2 ]GRID grid.410726.6, ISNI 0000 0004 1797 8419, University of Chinese Academy of Sciences, ; Beijing, 100049 China
                [3 ]GRID grid.9227.e, ISNI 0000000119573309, Key Laboratory of Space Active Opto-electronics Technology, Shanghai Institute of Technical Physics, , Chinese Academy of Sciences, ; Shanghai, 200083 China
                [4 ]GRID grid.9227.e, ISNI 0000000119573309, State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, , Chinese Academy of Sciences, ; Beijing, 100029 China
                [5 ]GRID grid.9227.e, ISNI 0000000119573309, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, , Chinese Academy of Sciences, ; Beijing, 100190 China
                [6 ]GRID grid.452783.f, ISNI 0000 0001 0302 476X, Beijing Institute of Spacecraft System Engineering, ; Beijing, 100094 China
                [7 ]GRID grid.512471.4, Beijing Aerospace Control Center, ; Beijing, 100094 China
                [8 ]GRID grid.9227.e, ISNI 0000000119573309, Xi’an Institute of Optics and Precision Mechanics, , Chinese Academy of Sciences, ; Xi’an, 710119 China
                [9 ]GRID grid.464215.0, ISNI 0000 0001 0243 138X, Beijing Institute of Space Mechanics Electricity, , China Academy of Space Technology, ; Beijing, 100076 China
                [10 ]GRID grid.9227.e, ISNI 0000000119573309, Institute of Geochemistry, , Chinese Academy of Sciences, ; Guiyang, 550081 China
                Author information
                http://orcid.org/0000-0002-9328-6532
                http://orcid.org/0000-0002-4875-3429
                http://orcid.org/0000-0002-2418-4495
                http://orcid.org/0000-0002-0817-2742
                http://orcid.org/0000-0001-8562-9737
                http://orcid.org/0000-0001-8187-2780
                http://orcid.org/0000-0002-7560-6707
                http://orcid.org/0000-0002-9421-7387
                http://orcid.org/0000-0002-7946-2333
                Article
                30807
                10.1038/s41467-022-30807-5
                9198042
                35701397
                a37476e6-368c-4f61-bdc5-ab6037cc94d7
                © The Author(s) 2022

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 24 September 2021
                : 6 May 2022
                Funding
                Funded by: the Key Research program of Chinese Academy of Sciences, Grant NO. ZDBS-SSW-JSC007
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                © The Author(s) 2022

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                planetary science
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                planetary science

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