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A Basket Tetradecavanadate Cluster with Blue Luminescence
June 2005
June 2005
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Abstract
A blue luminescent tetradecavanadate compound, [Et4N]5[V14O36Cl], has been synthesized.
It possesses an unprecedented half-open basket framework. Through the {ABAB}-type
stacking, the {V14O36} clusters form infinite one-dimensional channels with considerable
accessible volume in the crystalline state.