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      Magnetic Structure and Interactions in the Quasi-1D Antiferromagnet CaV\(_2\)O\(_4\)

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          Abstract

          CaV\(_2\)O\(_4\) is a spin-1 antiferromagnet, where the magnetic vanadium ions are arranged on quasi-one-dimensional (1D) zig-zag chains with potentially frustrated antiferromagnetic exchange interactions. High temperature susceptibility and single-crystal neutron diffraction measurements are used to deduce the non-collinear magnetic structure, dominant exchange interactions and orbital configurations. The results suggest that at high temperatures CaV\(_2\)O\(_4\) behaves as a Haldane chain, but at low temperatures, orbital ordering lifts the frustration and it becomes a spin-1 ladder.

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          Author and article information

          Journal
          09 December 2008
          2009-05-22
          Article
          10.1103/PhysRevB.79.180409
          0812.1808
          c84f01ef-baf9-44b5-99c4-5bf4afcb6dc1

          http://arxiv.org/licenses/nonexclusive-distrib/1.0/

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          Phys. Rev. B 79, 180409(R) (2009); 4 pages
          5 pages, 4 figures
          cond-mat.str-el

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