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      Synthesis and Characterization of Novel Epoxy Geopolymer Hybrid Composites

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          Abstract

          The preparation and the characterization of novel geopolymer-based hybrid composites are reported. These materials have been prepared through an innovative synthetic approach, based on a co-reticulation in mild conditions of commercial epoxy based organic resins and a metakaolin-based geopolymer inorganic matrix. This synthetic strategy allows the obtainment of a homogeneous dispersion of the organic particles in the inorganic matrix, up to 25% in weight of the resin. The materials obtained present significantly enhanced compressive strengths and toughness with respect to the neat geopolymer, suggesting their wide utilization for structural applications. A preliminary characterization of the porous materials obtained by removing the organic phase from the hybrid composites by means of heat treatments is also reported. Possible applications of these materials in the field of water purification, filtration, or as lightweight insulating materials are envisaged.

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          Geopolymers: Inorganic polymeric new materials

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            The role of inorganic polymer technology in the development of ‘green concrete’

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              Understanding the relationship between geopolymer composition, microstructure and mechanical properties

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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                09 September 2013
                September 2013
                : 6
                : 9
                : 3943-3962
                Affiliations
                [1 ]Department of Engineering, University of Naples Parthenope, INSTM Research Group Napoli Parthenope, Centro Direzionale Napoli, Isola C4, Naples 80143, Italy; E-Mails: laura.ricciotti@ 123456uniparthenope.it (L.R.); claudio.ferone@ 123456uniparthenope.it (C.F.); francesco.colangelo@ 123456uniparthenope.it (F.C.); raffaele.cioffi@ 123456uniparthenope.it (R.C.)
                [2 ]Department of Chemical Science, University of Naples Federico II, Complesso Universitario di Monte S. Angelo, via Cintia, Napoli 80126, Italy; E-Mail: oreste.tarallo@ 123456unina.it
                Author notes
                [* ] Author to whom correspondence should be addressed; E-Mail: giuseppina.roviello@ 123456uniparthenope.it ; Tel.: +39-081-54767811; Fax: +39-081-5476777.
                Article
                materials-06-03943
                10.3390/ma6093943
                5452667
                d3587678-2b11-4c0b-a417-9128dc711b89
                © 2013 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                : 09 June 2013
                : 01 August 2013
                : 02 September 2013
                Categories
                Article

                geopolymer,hybrid composites,epoxy resin,metakaolin
                geopolymer, hybrid composites, epoxy resin, metakaolin

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