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      Two new bioactive triterpene glycosides from the sea cucumber Pseudocolochirus violaceus.

      Journal of Asian natural products research
      Animals, Cell Line, Tumor, Glycosides, chemistry, isolation & purification, toxicity, Humans, Molecular Structure, Sea Cucumbers, Triterpenes

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          Abstract

          By activity-guided fractionation, two new triterpene glycosides, violaceusides A (1) and B (2), were isolated from the sea cucumber Pseudocolochirus violaceus as active compounds causing morphological abnormality of Pyricularia oryzae mycelia. By extensive 2D NMR techniques and chemical evidence, the structures of the two new glycosides were established as 16beta-acetoxy-3-O-[3-O-methyl-beta-D-glucopyranosyl-(1 --> 3)-beta-D-xylopyranosyl-(1 --> 4)-beta-D-quinovopyranosyl-(1 --> 2)-4-O-sodiumsulphate-beta-D-xylopyranosyl]-holosta-7,24-diene-3beta-ol (1) and 16beta-acetoxy-3-O-[3-O-methyl-beta-D-glucopyranosyl-(1 --> 3)-beta-D-xylopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 2)-4-O-sodiumsulphate-beta-D-xylopyranosyl]-holosta-7,24-diene-3beta-ol (2), respectively. The two glycosides also exhibited significant cytotoxicity against HL-60 and BEL-7402 cancer cell lines.

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          Author and article information

          Journal
          16753775
          10.1080/10286020500034972

          Chemistry
          Animals,Cell Line, Tumor,Glycosides,chemistry,isolation & purification,toxicity,Humans,Molecular Structure,Sea Cucumbers,Triterpenes

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