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      The meniscus-guided deposition of semiconducting polymers

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          Abstract

          The electronic devices that play a vital role in our daily life are primarily based on silicon and are thus rigid, opaque, and relatively heavy. However, new electronics relying on polymer semiconductors are opening up new application spaces like stretchable and self-healing sensors and devices, and these can facilitate the integration of such devices into our homes, our clothing, and even our bodies. While there has been tremendous interest in such technologies, the widespread adoption of these organic electronics requires low-cost manufacturing techniques. Fortunately, the realization of organic electronics can take inspiration from a technology developed since the beginning of the Common Era: printing. This review addresses the critical issues and considerations in the printing methods for organic electronics, outlines the fundamental fluid mechanics, polymer physics, and deposition parameters involved in the fabrication process, and provides future research directions for the next generation of printed polymer electronics.

          Abstract

          A primary advantage of polymer semiconductors compared to silicon-based semiconductors lies in its capability of being solution-processed for the large-scale fabrication of electronics that can be flexible, stretchable, implantable, biodegradable, and self-healing. Here, Gu and Shaw et al. review recent developments in meniscus-guided coating that can control thin-film morphology.

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          Wetting: statics and dynamics

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            Capillary flow as the cause of ring stains from dried liquid drops

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              A general relationship between disorder, aggregation and charge transport in conjugated polymers.

              Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have amorphous and ordered phases exhibiting varying degrees of order, has proved difficult owing to the contribution of electronic processes at various length scales. The growing technological appeal of these semiconductors makes such fundamental knowledge extremely important for materials and process design. We propose a unified model of how charge carriers travel in conjugated polymer films. We show that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolecular aggregation is sufficient for efficient long-range charge transport. This generalization explains the seemingly contradicting high performance of recently reported, poorly ordered polymers and suggests molecular design strategies to further improve the performance of future generations of organic electronic materials.
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                Author and article information

                Contributors
                zbao@stanford.edu
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                7 February 2018
                7 February 2018
                2018
                : 9
                : 534
                Affiliations
                [1 ]ISNI 0000000419368956, GRID grid.168010.e, Department of Chemical Engineering, , Stanford University, ; Stanford, CA 94305 USA
                [2 ]ISNI 0000 0001 0725 7771, GRID grid.445003.6, Stanford Synchrotron Radiation Lightsource, , SLAC National Accelerator Laboratory, ; Menlo Park, CA 94025 USA
                [3 ]ISNI 0000 0001 2295 628X, GRID grid.267193.8, Present Address: School of Polymer Science and Engineering, , University of Southern Mississippi, ; Hattiesburg, MS 39406 USA
                Author information
                http://orcid.org/0000-0002-1123-3673
                http://orcid.org/0000-0003-1182-5537
                http://orcid.org/0000-0002-9676-5029
                http://orcid.org/0000-0002-7513-1166
                http://orcid.org/0000-0002-0972-1715
                Article
                2833
                10.1038/s41467-018-02833-9
                5803241
                29416035
                e9cce433-4d75-4aa8-9d91-922af61052df
                © The Author(s) 2018

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 2 June 2016
                : 4 January 2018
                Categories
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                © The Author(s) 2018

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