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      Asymmetric synthesis of ethano-Tröger bases using CuTC-catalyzed diazo decomposition reactions.

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      Journal: Organic & Biomolecular Chemistry

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          Abstract

          Nonracemic ethano-bridged Tröger bases are prepared using CuTC-catalyzed decompositions of diazo compounds. Excellent levels of diastereo- and enantio-control (dr and ee up to 12:1 and 95% respectively) are now obtained with aryl diazoketone precursors.

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          PubMed ID:: 22131040
          DOI:: 10.1039/c1ob06751f

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