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      Key Components and Design Strategy for a Proton Exchange Membrane Water Electrolyzer

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          Abstract

          As the most attractive energy carrier, hydrogen production through electrochemical water splitting (EWS) is promising for resolving the serious environmental problems derived from the rapid consumption of fossil fuels globally. The proton exchange membrane water electrolyzer (PEMWE) is one of the most promising EWS technologies and has achieved great advancements. To offer a timely reference for the progress of the PEMWE system, the latest advancements and developments of PEMWE technology are systematically reviewed. The key components, including the electrocatalysts, PEM, and porous transport layer (PTL) as well as bipolar plate (BPP), are first introduced and discussed, followed by the membrane electrode assembly and cell design. The highlights are put on the design of the electrocatalyst and the relationship of each component on the performance of the PEMWE. Moreover, the current challenges and future perspectives for the development of PEMWE are also discussed. There is a hope that this review can provide a timely reference for future directions in PEMWE challenges and perspectives.

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          Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions.

          A fundamental change has been achieved in understanding surface electrochemistry due to the profound knowledge of the nature of electrocatalytic processes accumulated over the past several decades and to the recent technological advances in spectroscopy and high resolution imaging. Nowadays one can preferably design electrocatalysts based on the deep theoretical knowledge of electronic structures, via computer-guided engineering of the surface and (electro)chemical properties of materials, followed by the synthesis of practical materials with high performance for specific reactions. This review provides insights into both theoretical and experimental electrochemistry toward a better understanding of a series of key clean energy conversion reactions including oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER). The emphasis of this review is on the origin of the electrocatalytic activity of nanostructured catalysts toward the aforementioned reactions by correlating the apparent electrode performance with their intrinsic electrochemical properties. Also, a rational design of electrocatalysts is proposed starting from the most fundamental aspects of the electronic structure engineering to a more practical level of nanotechnological fabrication.
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            A comprehensive review on PEM water electrolysis

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              Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles

              Hydrogen fuel is considered as the cleanest renewable resource and the primary alternative to fossil fuels for future energy supply. Sustainable hydrogen generation is the major prerequisite to realize future hydrogen economy. The electrocatalytic hydrogen evolution reaction (HER), as the vital step of water electrolysis to H2 production, has been the subject of extensive study over the past decades. In this comprehensive review, we first summarize the fundamentals of HER and review the recent state-of-the-art advances in the low-cost and high-performance catalysts based on noble and non-noble metals, as well as metal-free HER electrocatalysts. We systemically discuss the insights into the relationship among the catalytic activity, morphology, structure, composition, and synthetic method. Strategies for developing an effective catalyst, including increasing the intrinsic activity of active sites and/or increasing the number of active sites, are summarized and highlighted. Finally, the challenges, perspectives, and research directions of HER electrocatalysis are featured.
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                Author and article information

                Contributors
                Journal
                Small Structures
                Small Structures
                Wiley
                2688-4062
                2688-4062
                June 2023
                October 27 2022
                June 2023
                : 4
                : 6
                Affiliations
                [1 ] School of Materials and Chemistry University of Shanghai for Science and Technology 516 Jungong Road Shanghai 200093 P. R. China
                [2 ] CAS Key Laboratory of Materials for Energy Conversion Shanghai Institute of Ceramics Chinese Academy of Sciences (SICCAS) Shanghai 200050 P. R. China
                [3 ] Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST) 1037 Luoyu Road Wuhan 430074 P. R. China
                Article
                10.1002/sstr.202200130
                f6ff5cc3-2211-40e7-8e3e-134d0fdfc763
                © 2023

                http://creativecommons.org/licenses/by/4.0/

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