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      Low-temperature thermodynamics with quantum coherence

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      Nature Communications
      Nature Pub. Group

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          Abstract

          Thermal operations are an operational model of non-equilibrium quantum thermodynamics. In the absence of coherence between energy levels, exact state transition conditions under thermal operations are known in terms of a mathematical relation called thermo-majorization. But incorporating coherence has turned out to be challenging, even under the relatively tractable model wherein all Gibbs state-preserving quantum channels are included. Here we find a mathematical generalization of thermal operations at low temperatures, ‘cooling maps', for which we derive the necessary and sufficient state transition condition. Cooling maps that saturate recently discovered bounds on coherence transfer are realizable as thermal operations, motivating us to conjecture that all cooling maps are thermal operations. Cooling maps, though a less-conservative generalization to thermal operations, are more tractable than Gibbs-preserving operations, suggesting that cooling map-like models at general temperatures could be of use in gaining insight about thermal operations.

          Abstract

          Thermal operations, a model of thermodynamic processes for small quantum systems out of equilibrium, are well-understood in absence of coherence. Here the authors introduce cooling processes, a generalization of thermal operations and find necessary and sufficient conditions for coherent state transitions via cooling processes.

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          Most cited references18

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          Fundamental limitations for quantum and nanoscale thermodynamics.

          The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit-when the number of particles becomes very large. Here we study thermodynamics in the opposite regime-at both the nanoscale and when quantum effects become important. Applying results from quantum information theory, we construct a theory of thermodynamics in these limits. We derive general criteria for thermodynamical state transitions, and, as special cases, find two free energies: one that quantifies the deterministically extractable work from a small system in contact with a heat bath, and the other that quantifies the reverse process. We find that there are fundamental limitations on work extraction from non-equilibrium states, owing to finite size effects and quantum coherences. This implies that thermodynamical transitions are generically irreversible at this scale. As one application of these methods, we analyse the efficiency of small heat engines and find that they are irreversible during the adiabatic stages of the cycle.
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            Emulation of a quantum spin with a superconducting phase qudit.

            In quantum information processing, qudits (d-level systems) are an extension of qubits that could speed up certain computing tasks. We demonstrate the operation of a superconducting phase qudit with a number of levels d up to d = 5 and show how to manipulate and measure the qudit state, including simultaneous control of multiple transitions. We used the qudit to emulate the dynamics of single spins with principal quantum number s = 1/2, 1, and 3/2, allowing a measurement of Berry's phase and the even parity of integer spins (and odd parity of half-integer spins) under 2pi-rotation. This extension of the two-level qubit to a multilevel qudit holds promise for more-complex quantum computational architectures and for richer simulations of quantum mechanical systems.
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              Resource theory of quantum states out of thermal equilibrium.

              The ideas of thermodynamics have proved fruitful in the setting of quantum information theory, in particular the notion that when the allowed transformations of a system are restricted, certain states of the system become useful resources with which one can prepare previously inaccessible states. The theory of entanglement is perhaps the best-known and most well-understood resource theory in this sense. Here, we return to the basic questions of thermodynamics using the formalism of resource theories developed in quantum information theory and show that the free energy of thermodynamics emerges naturally from the resource theory of energy-preserving transformations. Specifically, the free energy quantifies the amount of useful work which can be extracted from asymptotically many copies of a quantum system when using only reversible energy-preserving transformations and a thermal bath at fixed temperature. The free energy also quantifies the rate at which resource states can be reversibly interconverted asymptotically, provided that a sublinear amount of coherent superposition over energy levels is available, a situation analogous to the sublinear amount of classical communication required for entanglement dilution.
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                Author and article information

                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Pub. Group
                2041-1723
                03 July 2015
                2015
                : 6
                : 7689
                Affiliations
                [1 ]Department of Mathematics and Statistics and Institute for Quantum Science and Technology, University of Calgary , 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4
                Author notes
                Author information
                http://orcid.org/0000-0001-8155-6120
                Article
                ncomms8689
                10.1038/ncomms8689
                4506506
                26138621
                fe3594ab-327a-4c99-b47a-46ef4a71d7a4
                Copyright © 2015, Nature Publishing Group, a division of Macmillan Publishers Limited. All Rights Reserved.

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 10 October 2014
                : 29 May 2015
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