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      Graphene aerogel composites derived from recycled cigarette filters for electromagnetic wave absorption

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          Abstract

          Graphene aerogels with excellent electromagnetic wave absorption properties are fabricated by using cigarette filters as templates via a simple dip-coating method.

          Abstract

          Assembling graphene nanosheets into three dimensional aerogels has attracted considerable interest due to their unique properties and potential applications in many fields. Here, graphene aerogels constructed from interconnected graphene nanosheet-coated carbon fibers are fabricated by using cigarette filters as templates via a simple dip-coating method. The composite aerogels are ultralight ( ρ = 7.6 mg cm −3) yet have high mechanical strength (0.07 MPa); when used as electromagnetic wave absorbers, they showed a minimum reflection loss value of −30.53 dB at 14.6 GHz and the bandwidth of reflection loss less than −10 dB (90% absorption) was 4.1 GHz. Furthermore, coating polypyrrole onto the composite aerogels can increase the minimum reflection loss value to −45.12 dB. Our results provide a promising approach to fabricate graphene-based composite aerogels with a strong electromagnetic wave absorption ability.

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          Novel carbon nanotube-polystyrene foam composites for electromagnetic interference shielding.

          A novel carbon nanotube-polystyrene foam composite has been fabricated successfully. The electromagnetic interference (EMI) shielding effectiveness measurements indicated that such foam composites can be used as very effective, lightweight shielding materials. The correlation between the shielding effectiveness and electrical conductivity and the EMI shielding mechanism of such foam composites are also discussed.
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            Highly aligned graphene/polymer nanocomposites with excellent dielectric properties for high-performance electromagnetic interference shielding.

            Nanocomposites that contain reinforcements with preferred orientation have attracted significant attention because of their promising applications in a wide range of multifunctional fields. Many efforts have recently been focused on developing facile methods for preparing aligned graphene sheets in solvents and polymers because of their fascinating properties including liquid crystallinity and highly anisotropic characteristics. Self-aligned in situ reduced graphene oxide (rGO)/polymer nanocomposites are prepared using an all aqueous casting method. A remarkably low percolation threshold of 0.12 vol% is achieved in the rGO/epoxy system owing to the uniformly dispersed, monolayer graphene sheets with extremely high aspect ratios (>30000). The self-alignment into a layered structure at above a critical filler content induces a unique anisotropy in electrical and mechanical properties due to the preferential formation of conductive and reinforcing networks along the alignment direction. Accompanied by the anisotropic electrical conductivities are exceptionally high dielectric constants of over 14000 with 3 wt% of rGO at 1 kHz due to the charge accumulation at the highly-aligned conductive filler/insulating polymer interface according to the Maxwell-Wagner-Sillars polarization principle. The highly dielectric rGO/epoxy nanocomposites with the engineered structure and properties present high performance electromagnetic interference shielding with a remarkable shilding efficiency of 38 dB.
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              Lightweight, Multifunctional Polyetherimide/Graphene@Fe3O4 Composite Foams for Shielding of Electromagnetic Pollution

              Novel high-performance polyetherimide (PEI)/graphene@Fe3O4 (G@Fe3O4) composite foams with flexible character and low density of about 0.28-0.4 g/cm(3) have been developed by using a phase separation method. The obtained PEI/G@Fe3O4 foam with G@Fe3O4 loading of 10 wt % exhibited excellent specific EMI shielding effectiveness (EMI SE) of ~41.5 dB/(g/cm(3)) at 8-12 GHz. Moreover, most the applied microwave was verified to be absorbed rather than being reflected back, resulting from the improved impedance matching, electromagnetic wave attenuation, as well as multiple reflections. Meanwhile, the resulting foams also possessed a superparamagnetic behavior and low thermal conductiviy of 0.042-0.071 W/(m K). This technique is fast, highly reproducible, and scalable, which may facilitate the commercialization of such composite foams and generalize the use of them as EMI shielding materials in the fields of spacecraft and aircraft.
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                Author and article information

                Journal
                JMCCCX
                Journal of Materials Chemistry C
                J. Mater. Chem. C
                Royal Society of Chemistry (RSC)
                2050-7526
                2050-7534
                2015
                2015
                : 3
                : 45
                : 11893-11901
                Affiliations
                [1 ]Center for Composite Materials and Structures
                [2 ]Harbin Institute of Technology
                [3 ]Harbin 150080
                [4 ]P. R. China
                [5 ]Department of Materials Science and Engineering
                [6 ]College of Engineering
                [7 ]Peking University
                [8 ]Beijing 100871
                Article
                10.1039/C5TC03127C
                fece87a9-ac0a-4733-a951-7cedc2837871
                © 2015
                History

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