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1,3-Dienes
Other Catalytic Carbopalladation Routes to 1,3-Dienes
other
Author(s):
E. Negishi
,
G. Wang
Publication date
(Online):
2009
Publisher:
Georg Thieme Verlag KG
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Book Chapter
Publication date (Print):
2009
Publication date (Online):
2009
Page
: 1
DOI:
10.1055/sos-SD-046-00171
SO-VID:
7263a310-5e2f-4125-8657-a9712c7235bb
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Book chapters
pp. 1
Extrusion of Sulfur Dioxide
pp. 1
Using Metallic Zinc
pp. 1
Cycloisomerization of 1,6-Enynes
pp. 1
Cycloisomerization of 1,6- and 1,7-Enynes
pp. 1
In the Presence of a Proton Source
pp. 1
1,3-Dienes Having Endocyclic and Exocyclic Double Bonds
pp. 1
Chelation-Guided -Carbometalation with Alkenyl- and Alkynylmetals
pp. 1
Nickel-Catalyzed Aldehyde–Alkyne Coupling
pp. 1
The Keck Variation
pp. 1
Of Electron-Withdrawing Carbon-Substituted Arenes with Alkyl Organolithium Species
pp. 1
Of Alkali Metal Phenolate Salts
pp. 1
Rhodium-Catalyzed Cycloaddition
pp. 1
Synthesis of 1,3-Dienes with an Electron-Withdrawing Group at C2
pp. 1
Tetra-, Penta-, and Hexasubstituted 1,3-Dienes Containing One or Two Fully Substituted Alkenyl Groups Excluding 1,1,2,3-Tetrasubstituted 1,3-Dienes
pp. 1
Iridium-Catalyzed Cycloisomerization To Give Vinylcycloalkenes
pp. 1
Intramolecular Acylation
pp. 1
Cobalt-Mediated C—H Activation
pp. 1
1,3-Dienes Containing the Parent Vinyl and/or 1-Monosubstituted Vinyl Groups
pp. 1
Formation of the α,β-Alkene
pp. 1
Acid-Catalyzed Isomerization
pp. 1
Cobalt-Catalyzed Polyene–Alkyl Halide–[(Trimethylsilyl)methyl]magnesium Chloride Coupling Reaction
pp. 1
Using the Rosenmund Catalyst
pp. 1
Alkylations of Polyenes
pp. 1
Cyclopentadienones by Iron-Mediated [2 + 2 + 1] Cycloaddition
pp. 1
Acid-Mediated Isomerization
pp. 1
Carbon Monoxide Extrusion from β-Allenyl Aldehydes
pp. 1
[1,5]-Sigmatropic Shifts of Vinylallenes
pp. 1
1,4-Disubstituted ,-1,3-Dienes by [2C + 2C] Alkynyl–Alkenyl Coupling via Organoboron Migratory Insertion Reactions
pp. 1
Alkoxylation of -Alkoxy-Substituted Phenols (Synthesis of -Quinone Acetals)
pp. 1
Ligand Exchange
pp. 1
Base-Catalyzed Isomerization
pp. 1
Platinum- and Gold-Catalyzed Cycloisomerization To Give Vinylcycloalkenes
pp. 1
Hydride Addition
pp. 1
Extrusion of Carbon Dioxide
pp. 1
By Imino-Diels–Alder Reaction
pp. 1
Preparation of Other Substitution Patterns via Thermolysis
pp. 1
Synthesis via Zirconacyclopentadienes
pp. 1
1,3-Dienes from 1,2-Fused Cyclobutenes
pp. 1
Cyclization of Diynes
pp. 1
Synthesis from α,β-Unsaturated Carbonyl Compounds and Alkylsilanes
pp. 1
Elimination of 4-Methylpyridin-2-amine from -{1-[4-(Dimethylamino)phenyl]pent-4-enyl}-4-methylpyridin-2-amine Using Rhodium(I)
pp. 1
1,3-Dienes Having Two Exocyclic Double Bonds
pp. 1
By Rearrangement of -Arylhydroxylamine Derivatives
pp. 1
Preparation of 1,4-Disubstituted 1,3-Dienes via Thermolysis
pp. 1
Titanium-Mediated Carbometalation of Internal Alkynes
pp. 1
Hydroxylation of -Alkyl-Substituted Anilines (Synthesis of -Quinol Imines)
pp. 1
Intramolecular Diels–Alder Trapping of the Diene
pp. 1
Dehydroxylation–Desulfonylation by the Loss of Acetoxy and Benzenesulfonate Functions
pp. 1
Electron-Transfer-Mediated Isomerization
pp. 1
Other Strategies
pp. 1
Cross Metathesis of Alkynes with Alkenes
pp. 1
To Give 6-Alkoxy-6-alkylcyclohexa-2,4-dien-1-ones
pp. 1
1,4-Disubstituted ,-1,3-Dienes by [2C + 2C] Alkenyl–Alkenyl Coupling via Organoboron Migratory Insertion Reactions
pp. 1
Hydrogenation Reactions
pp. 1
Elimination of Two Hydrogens and Two Heteroatoms or Heteroatom-Containing Groups
pp. 1
Synthesis from Phosphine Oxides and Enals
pp. 1
Photochemical Six-Electron Electrocyclizations
pp. 1
Thermal Extrusion of Sulfur Dioxide from 2,5-Dihydrothiophene 1,1-Dioxides
pp. 1
Synthesis of 1,3-Dienes with an Electron-Withdrawing Group at C1
pp. 1
Reaction of Alkynes with Pentacarbonyliron
pp. 1
Other Organozirconium Migratory Insertion Reactions for the Synthesis of 1,3-Dienes
pp. 1
Nickel-Catalyzed Cyclization of Diynes
pp. 1
Driven by Extended Conjugation
pp. 1
Photochemical Reactions of Cyclobutenes
pp. 1
Synthesis by Other Elimination Procedures
pp. 1
Intermolecular Diels–Alder Trapping of the Diene
pp. 1
--Heteroannular 1,3-Dienes
pp. 1
Elimination of a Carbon Fragment and a Heteroatom-Containing Group
pp. 1
Gold-Catalyzed Cycloisomerization
pp. 1
Epoxidation of Polyenes
pp. 1
Isomerization of Unconjugated Dienes
pp. 1
Extrusion of a Bridging Carbon Monoxide from Strained Rings
pp. 1
Stoichiometric Synthesis of 1,3-Dienes by Metal-Mediated [2C + 2C] Coupling via Carbometalation
pp. 1
Photochemical Rearrangements of 1,2,6-Trienes
pp. 1
Loss of a Sulfonic Acid
pp. 1
Polycyclization Using Grubbs' Catalysts
pp. 1
Cycloisomerization of Allenynes
pp. 1
Of Ynones
pp. 1
Reaction of Cyclic (η-Dienyl)iron Complexes with Nucleophiles
pp. 1
Extrusion from Cyclic Sulfinate Esters
pp. 1
Of Functionalized Unconjugated Dienes
pp. 1
Synthesis of 1,3-Diene-Containing Oligoenes and Oligoenynes of Natural Origin and Related Compounds
pp. 1
The Wittig Reaction
pp. 1
Palladium(0)-Mediated Substitution of Doubly Allylic Acetates and Carbonates
pp. 1
Titanium-Catalyzed Cycloaddition
pp. 1
Endocyclic 1,3-Dienes
pp. 1
Using Bis(η-cyclopentadienyl)(dihalozinc)(μ-methylene)titanium
pp. 1
Thermally Induced Rearrangements of Propargyl Vinyl Ethers
pp. 1
Using the Hoveyda–Blechert Catalyst
pp. 1
Elimination of a Carbon Fragment and a Heteroatom
pp. 1
Other Catalytic Carbopalladation Routes to 1,3-Dienes
pp. 1
Europium-Catalyzed Isomerization
pp. 1
Extrusion of Cyclopentadiene
pp. 1
Modification at the Periphery of Tricarbonyl(η-1,3-diene)iron Complexes
pp. 1
Using Alternative Promoters
pp. 1
Codimerization Reaction between 1,3-Dienes and Alkynes
pp. 1
Chiral Manganese(III)–salen Catalyzed Epoxidation
pp. 1
Trisubstituted 1,3-Dienes Excluding Those Containing a Vinyl or Vinylidene Group
pp. 1
Palladium-Catalyzed Isomerization
pp. 1
Ring-Closing Metathesis of Alkenes with Conjugated Dienes
pp. 1
Alkylation of -Substituted Phenols
pp. 1
Elimination of Acetic Acid
pp. 1
Synthesis by 1,4-Elimination
pp. 1
By Wessely Oxidation
pp. 1
Alkoxylation of -Alkyl-Substituted Phenols (Synthesis of -Quinol Ethers)
pp. 1
Carbon Monoxide Extrusion from Monocyclic Cyclopent-3-en-1-ones
pp. 1
Base-Induced Isomerization and Thermal Elimination of 2,3-Dihydrothiophene 1,1-Dioxides
pp. 1
Tetrasubstituted 1,3-Dienes Excluding Those Containing a Fully Substituted Alkenyl Group
pp. 1
Reactions of (π-Allyl)tricarbonyliron Lactone Complexes
pp. 1
Expulsion of Oxygen from Oxiranes
pp. 1
Synthesis Using Chromium-Based Reagents
pp. 1
Desulfurization of Thiiranes
pp. 1
Loss of Hydrogen and an Alkoxy or Aryloxy Group
pp. 1
Synthesis by 1,2,3,4-Elimination
pp. 1
Addition to Tricarbonyl(η-triene)iron Complexes
pp. 1
Synthesis of Open-Chain 1,3,5-Trienes
pp. 1
Preparation of Terminal 1,3-Dienes via Thermolysis
pp. 1
Synthesis from Alkenylphosphonates and Carbonyl Compounds
pp. 1
Synthesis Using Zinc-Based Reagents
pp. 1
Ruthenium-Catalyzed Dimerization of Propargyl Alcohols
pp. 1
Double Stobbe Reaction
pp. 1
Chiral-Dioxirane-Catalyzed Epoxidation
pp. 1
Cyclopropanation
pp. 1
Stoichiometric Synthesis of 1,3-Dienes by Metal-Mediated Coupling Reactions via Migratory Insertion
pp. 1
Zirconium-Promoted Ene–Yne Coupling and Alkyne Dimerization
pp. 1
Nickel-Catalyzed Aldehyde–Alkyne and Aldehyde–Enyne Coupling
pp. 1
Single-Step Reactions
pp. 1
Platinum-Catalyzed Cycloisomerization To Give Vinylcycloalkenes
pp. 1
Under Kinetic Conditions with Subsequent Elimination
pp. 1
Cross Metathesis of Alkenes with Conjugated Dienes
pp. 1
Elimination of a Hydrogen Halide
pp. 1
Birch Reductions
pp. 1
1,3-Dienes via Heterofunctionalized 1,3-Dienes
pp. 1
Synthesis by 1,2-Elimination
pp. 1
-Cyclohexanediols by Enzymatic Dihydroxylation of Arenes
pp. 1
Other Alkylidenation Reactions
pp. 1
Six-Membered Rings by Cycloisomerization of 1,5-Enynes
pp. 1
Ruthenium-Catalyzed Cycloisomerization To Give Vinylcycloalkenes
pp. 1
Metathesis of Internal Alkynes with Acyclic Alkenes
pp. 1
Elimination of a Shared Oxygen Atom
pp. 1
Thermal Six-Electron Electrocyclizations To Give Cyclohexa-1,3-dienes
pp. 1
Of 2-(Hydroxymethyl)phenols To Give Spiroepoxycyclohexa-2,4-dien-1-ones
pp. 1
Elimination of Carbon Monoxide
pp. 1
Elimination of Hydrogen and a Heteroatom
pp. 1
Elimination by Zeolite NaY
pp. 1
Hydroxylation of -Alkyl-Substituted Phenols (Synthesis of -Quinols)
pp. 1
Cyclization of Enynes
pp. 1
Synthesis from Arenes
pp. 1
Elimination of Sulfur Dioxide
pp. 1
Addition to Carboxylic Acid Derivatives
pp. 1
Ring-Rearrangement Metathesis
pp. 1
Cobalt(I)-Mediated Cycloisomerization of 1,n-Enynes
pp. 1
1,3-Dienes through Modification of 4C Compounds
pp. 1
Reaction of (η-Dienyl)metal Complexes with Nucleophiles
pp. 1
Titanium-Promoted Ene–Yne Coupling and Alkyne Dimerization
pp. 1
Conversion of Propargyl Ethers into 1,3-Dienes
pp. 1
Amidation of -Alkyl-Substituted Aniline Derivatives (Synthesis of -Quinol Imide Amides)
pp. 1
Double Dehydrochlorination
pp. 1
Elimination of Two Hydrogen Atoms and a Shared Oxygen Atom
pp. 1
Dihydroxylation of Polyenes
pp. 1
Synthesis from Carbonyl Compounds and Allyl Sulfones
pp. 1
Nickel-Catalyzed Aldehyde–Enyne Coupling
pp. 1
Alkenylation of -Alkyl-Substituted Anilines
pp. 1
Tandem Retro-Diels–Alder/Sulfur Dioxide Extrusion from Cyclic Sulfones
pp. 1
Loss of Nitrate and Acetate (or Methanesulfonate)
pp. 1
Acyloxylation of -Alkoxy-Substituted Phenols (Synthesis of -Quinone Alkoxy Acetates)
pp. 1
Synthesis of Cyclooctatetraenes
pp. 1
Extrusion of Maleic Anhydride
pp. 1
Synthesis from Alkenylphosphine Oxides and Aldehydes or Ketones
pp. 1
Synthesis of 1,3-Dienes by Palladium-Catalyzed Cross-Coupling Reactions
pp. 1
Dienes from 2,5-Dihydro-1-pyrroles
pp. 1
The Peterson Reaction
pp. 1
2:1 Co-oligomerization of Alkynes and Alkenes
pp. 1
[6 + 4] Cycloadditions of Tropones
pp. 1
Elimination of Two Oxygen-Containing Groups
pp. 1
Under Basic Conditions with Thermodynamic Control
pp. 1
Reaction of Cyclic Sulfones with Ultrasonically Dispersed Potassium
pp. 1
Isomerization of Alkynes
pp. 1
Of Arenoxasulfonium Ylides by [2,3]-Sigmatropic Rearrangement
pp. 1
Intermolecular Acylation
pp. 1
From Non-Ester Substrates
pp. 1
Transition-Metal-Catalyzed Isomerization of Methylenecyclopropanes
pp. 1
Addition to Imines
pp. 1
Elimination of Benzenesulfinic Acid
pp. 1
Metathesis of Alkynes with Cycloalkenes
pp. 1
Cobalt(I)-Mediated Cyclization To Give Cross-Conjugated Trienes
pp. 1
1,3-Dienes via 1,3-Enynes and 1,3-Diynes
pp. 1
Terminal 1,3-Dienes via The Vinylogous Ramberg–Bäcklund Reaction
pp. 1
Titanium(II)-Mediated Cyclization To Give Cross-Conjugated Trienes
pp. 1
Elimination of a Shared Heteroatom or Group
pp. 1
Coupling of Alkynes
pp. 1
Metathesis of Terminal Alkynes with Other Acyclic Alkenes
pp. 1
Elimination of Hydrogen and an Oxygen Atom Bonded to Carbon
pp. 1
The Ando Method
pp. 1
Alkynylation of -Alkyl-Substituted Phenols
pp. 1
2,3-Ring-Fused Cyclohexa-1,3-dienes from 3,4-Ring-Fused 1,3,5-Trienes
pp. 1
[6 + 4] Cycloadditions of Fulvenes
pp. 1
Double Dehydroiodination
pp. 1
Elimination of Four Bromine Atoms
pp. 1
Base-Mediated Isomerization
pp. 1
Oxidative Cyclization of Tricarbonyl(1,3-diene)iron Complexes
pp. 1
Extrusion of Alkenes
pp. 1
Preparation of 2,3-Disubstituted 1,3-Dienes via Thermolysis
pp. 1
Zirconocene-Mediated Skeletal Rearrangements
pp. 1
Under Standard Basic Conditions
pp. 1
Substitution of Tricarbonyl(2,4-dien-1-ol)iron Derivatives
pp. 1
Synthesis of Cyclodecatetraenes
pp. 1
Hydrozirconation
pp. 1
Extrusion of Nitrogen from Hydrazine-Derived Azo Compounds
pp. 1
5,6-Fused Cyclohexa-1,3-dienes from Cycloalka-1,3,5-trienes
pp. 1
Extrusion of Nitrogen
pp. 1
Zirconacene-Derivative-Promoted Cyclization of Diynes
pp. 1
Unsaturated Carbocycles via a Combination of Thermally Induced Electrocyclizations
pp. 1
Addition of Oximes to -Alkyl-Substituted Phenols (Synthesis of -Quinol Oximes)
pp. 1
Of Aliphatic Alkynes
pp. 1
Synthesis via Intermediate Tricarbonyl(1,3-diene)iron Complexes
pp. 1
Organocatalyzed Isomerization of Ynones
pp. 1
Synthesis from Allyl Phosphorus Ylides and Carbonyl Compounds
pp. 1
Thermally and Photochemically Induced Isomerization
pp. 1
Oxidative Cyclization of Cyclohexa-1,3-diene(cyclopentadienyl)cobalt Complexes
pp. 1
Metathesis of Alkynes with Ethene
pp. 1
Cyclization of (1,3-Diene)iron Complexes with Pendent Double Bonds
pp. 1
Rhodium-Catalyzed Isomerization To Give Cross-Conjugated Trienes
pp. 1
Rearrangements Mediated by Thionyl Chloride
pp. 1
1,3-Dienes via the Heck Reaction
pp. 1
Acyclic 1,3-Dienes from Multisubstituted Cyclobutenes
pp. 1
Extrusion of Carbon Monoxide
pp. 1
1,3-Dienes via Oxymetalation Reactions
pp. 1
Extrusion of 4-Phenyl-3-1,2,4-triazole-3,5(4)-diones and Related Molecules
pp. 1
Reaction of Cyclic (η-Dienyl)manganese Complexes with Nucleophiles
pp. 1
Hydroalumination
pp. 1
Titanium-Mediated Skeletal Rearrangement
pp. 1
Palladium-Catalyzed Coupling of Substituted (1,3-Diene)iron Complexes
pp. 1
Addition to Ketones
pp. 1
Palladium-Catalyzed Cycloisomerization To Give Vinylcyclopentenes
pp. 1
Carbon Dioxide Extrusion from Six-Membered Lactones
pp. 1
Carbon Dioxide Extrusion with In Situ Trapping of the Diene
pp. 1
Isomerization by Sigmatropic Rearrangements
pp. 1
Grob Fragmentation
pp. 1
Metal-Catalyzed Isomerization
pp. 1
Gold- and Platinum-Catalyzed Cycloisomerization To Give Cross-Conjugated Trienes
pp. 1
Loss of an Oxygen-Containing Group and a Halogen Atom
pp. 1
Synthesis of 1,3-Dienes by Controlled Alkyne Dimerization via -Carbometalation
pp. 1
Cobalt-Mediated Cycloaddition
pp. 1
Isomerization by Other Processes
pp. 1
The Horner–Wittig Reaction
pp. 1
Titanium-Promoted Cyclization of Diynes
pp. 1
Dehydrohalogenation
pp. 1
Using the Schrock Catalyst
pp. 1
Carbon Dioxide Extrusion from Vinyl-Substituted β-Lactones
pp. 1
1,4-Disubstituted 1,3-Dienes
pp. 1
Cross Metathesis of Alkenes Followed by Elimination
pp. 1
Elimination of Two Bromine Atoms
pp. 1
Using Grubbs' Catalysts
pp. 1
Under Lewis Acidic Conditions
pp. 1
Elimination of Two Carbon Atoms
pp. 1
Palladium(II)-Assisted Cope Rearrangements
pp. 1
Cycloisomerization of Dienynes
pp. 1
Single Stobbe Reaction
pp. 1
Tandem Lactone Formation–Carbon Dioxide Extrusion
pp. 1
Nickel-Catalyzed Cycloaddition
pp. 1
1,3,5-Trienes from 2,7-Dihydrothiepin 1,1-Dioxides
pp. 1
Cyclohexa-1,3-dienes from Acyclic 1,3,5-Trienes
pp. 1
The Horner–Wadsworth–Emmons Reaction
pp. 1
Isomerization of 1,4-Dienes
pp. 1
Loss of Acetic Acid and Carbon Dioxide
pp. 1
Synthesis by Tandem Oxidation–Wittig Reaction
pp. 1
Thermal Rearrangements of Polyenes
pp. 1
Oxidative Cyclization of (1,3-Diene)metal Complexes
pp. 1
Synthesis Using Miscellaneous Reagents
pp. 1
Synthesis from Phosphorus Ylides and Enones or Enals
pp. 1
Juliá–Colonna Asymmetric Epoxidation
pp. 1
Loss of Hydrogen and a Selenium-Containing Group
pp. 1
Cracking of Dicyclopentadiene
pp. 1
Using Titanacyclobutenes
pp. 1
Loss of Silicon- and Nitrogen-Containing Groups
pp. 1
Acyclic 1,3-Dienes from 3,4-Unsubstituted Cyclobutenes
pp. 1
Release of 1,3-Dienes by Demetalation of Tricarbonyl(1,3-diene)iron Complexes
pp. 1
Synthesis Using Titanium-Based Reagents
pp. 1
Ruthenium-Catalyzed Cycloisomerization
pp. 1
Isomerization of Allenes
pp. 1
Loss of Silicon- and Oxygen-Bearing Groups
pp. 1
Conjugated Vinylic Cycloalkenes
pp. 1
Acyloxylation of -Alkyl-Substituted Phenols (Synthesis of -Quinol Acetates)
pp. 1
Ruthenium-Catalyzed Cycloisomerization of Enynes
pp. 1
Reactions at Groups Other Than Carbonyl or Heterocarbonyl Adjacent to Tricarbonyl(η-1,3-diene)iron Complexes
pp. 1
Loss of Acetic Acid or Trifluoroacetic Acid
pp. 1
Knoevenagel and Related Condensations
pp. 1
Of Sulfone-Substituted Arenes
pp. 1
Iridium-Catalyzed Cycloaddition
pp. 1
Double Dehydrobromination
pp. 1
1,6-Fused Cyclohexa-1,3-dienes from 1,2-Fused 1,3,5-Trienes
pp. 1
Reaction of Acyclic (η-Dienyl)iron Complexes with Nucleophiles
pp. 1
Halomethylenation and Related Reactions
pp. 1
Six-Membered Rings by [2 + 2 + 2] Cycloaddition
pp. 1
Modification at the Periphery of (π-Allyl)tricarbonyliron Lactone Complexes
pp. 1
Arylation of -Alkyl-Substituted Phenols
pp. 1
Palladium-Catalyzed Cycloisomerization
pp. 1
Metal-Mediated Isomerization
pp. 1
Other In Situ Trapping Reactions
pp. 1
Extrusion from Cyclic Sulfones in the Presence of Lithium Aluminum Hydride
pp. 1
Lactone Formation
pp. 1
Acylation of Tricarbonyl(1,3-diene)iron Complexes
pp. 1
Synthesis of 1,3-Dienes with Two Electron-Withdrawing Groups at C1
pp. 1
Palladium-Catalyzed Cycloisomerization of Enynes
pp. 1
Oxidative Demetalation
pp. 1
Simultaneous Diene Formation
pp. 1
Alkenylation of -Alkyl-Substituted Phenols
pp. 1
Under Catalytic Conditions
pp. 1
Diacyloxylation of Phenols (Synthesis of -Quinone Diacetates)
pp. 1
Using Raney Nickel Catalyst
pp. 1
Polycyclization Using the Hoveyda–Blechert Catalyst
pp. 1
Sequential Diene Formation
pp. 1
Thermolysis Followed by In Situ Trapping
pp. 1
Dehydration
pp. 1
Extrusion of 4-Phenyl-3-1,2,4-triazole-3,5(4)-dione by Thermolysis
pp. 1
Isomerization of Methylenecyclopropanes
pp. 1
Elimination of Two Bromine Atoms or Two Heteroatom-Containing Groups
pp. 1
Hydrometalation Reactions
pp. 1
Of Unfunctionalized Unconjugated Dienes
pp. 1
Using Standard Conditions
pp. 1
1,3-Dienes from 1,4-Fused Cyclobutenes
pp. 1
Isomerization by Allylic Substitution Reactions
pp. 1
Application of the Ramberg–Bäcklund Reaction to an Iterative Ring-Growing Procedure
pp. 1
Elimination of Two Heteroatoms or Heteroatom-Containing Groups
pp. 1
Extrusion of 4-Phenyl-3-1,2,4-triazole-3,5(4)-dione in the Presence of a Reducing Agent
pp. 1
Cyclization of Allenynes
pp. 1
Cycloalka-1,3-dienes from 3,4-Fused Cyclobutenes (Ring Expansion)
pp. 1
Using Bis(η-cyclopentadienyl)dimethyltitanium(IV) (The Petasis Reagent)
pp. 1
Extrusion from Related Diazines
pp. 1
Extrusion from In Situ Generated Thiirane 1,1-Dioxides (The Ramberg–Bäcklund Reaction)
pp. 1
Using Hydrazine
pp. 1
Cobalt-Mediated Syntheses of Alkaloids and Steroids
pp. 1
Reaction of Electrophiles with Tricarbonyl(dienoate)iron or Tricarbonyl(dienone)iron Complexes
pp. 1
Synthesis from Diynes
pp. 1
Acyloxylation of -Alkyl-Substituted Aniline Derivatives (Synthesis of -Quinol Imide Acetates)
pp. 1
Zirconium-Mediated Cycloaddition
pp. 1
Cope Rearrangements of Enynes
pp. 1
From Stabilized Ylides
pp. 1
Nickel-Mediated C—H Activation
pp. 1
Nucleophilic Addition to Carbonyl and Heterocarbonyl Functions Adjacent to Tricarbonyl(η-1,3-diene)iron Complexes
pp. 1
Loss of Hydrogen and an Arylsulfinyl Group
pp. 1
Synthesis from α,β-Unsaturated Carbonyl Compounds and Alkyl Sulfones
pp. 1
Seven-Membered Rings by Cycloaddition or Cycloisomerization of Diynes
pp. 1
Hydroboration
pp. 1
Rhodium-Catalyzed Cycloisomerization
pp. 1
Multistep Reactions
pp. 1
1,4-Disubstituted ,-1,3-Dienes by [2C + 2C] Alkynyl–Alkynyl Coupling via Boron- or Zirconium-Mediated Migratory Insertion
pp. 1
Dehalogenation
pp. 1
Elimination of a Shared Atom Such as Oxygen or Sulfur
pp. 1
Elimination of a Silicon-Containing Group and a Heteroatom
pp. 1
Ethene-Assisted Metathesis
pp. 1
Of Alkenyl-Substituted Arenes with Alkenyl Organolithium Species
pp. 1
By Hetero-Claisen Rearrangement of -Arylhydroxylamine Derivatives
pp. 1
Decarboxylative Extrusion from β-Lactones
pp. 1
Methylenation
pp. 1
Elimination of Sulfur Dioxide via Variations of the Ramberg–Bäcklund Reaction
pp. 1
Synthesis of 1,3-Dienes with Electron-Withdrawing Groups at C2 and C3
pp. 1
Carbon Monoxide Extrusion with In Situ Trapping of the Diene
pp. 1
Synthesis of 1,3-Dienes with Electron-Withdrawing Groups at C1 and C3
pp. 1
Of Phosphinamide-Substituted Arenes
pp. 1
Acyclic 1,3-Dienes
pp. 1
The Julia Reaction and Its Variations
pp. 1
Synthesis from Phosphonates and Enones or Enals
pp. 1
Extrusion of Nitrogen from Pyridazine-Derived Azo Compounds
pp. 1
Other Reduction Processes
pp. 1
Elimination of Hydrogen and Oxygen from Peroxides
pp. 1
Using the Tebbe Reagent
pp. 1
Ring-Closing Metathesis of Enynes
pp. 1
The Vinylogous Peterson Elimination
pp. 1
[6 + 4] Cycloadditions between Buta-1,3-dienes and Hexa-1,3,5-trienes
pp. 1
Using the Lindlar Catalyst
pp. 1
Cyclopentadiene as a Protecting Group
pp. 1
Amination of -Alkyl-Substituted Phenol Derivatives
pp. 1
Hexa-1,3,5-trienes from Diallylic Sulfones
pp. 1
Zirconium-Mediated Carbometalation of Alkynes
pp. 1
Other Approaches
pp. 1
Thermal Cracking of Cyclohexene
pp. 1
Reductive Dearomatization of Arenes by Addition of Organolithiums Followed by Electrophilic Trapping
pp. 1
Using a Palladium on Charcoal Catalyst
pp. 1
Using the P-2 Nickel Catalyst
pp. 1
Using a Poisoned Lindlar Catalyst
pp. 1
Iridium(I)-Catalyzed Cycloisomerization of Enynes
pp. 1
Thermally Induced Rearrangements
pp. 1
Synthesis from Enynes
pp. 1
Carbon Monoxide Extrusion To Afford Cyclooctatetraenes
pp. 1
From Nonstabilized Ylides
pp. 1
Thermal Electrocyclic Ring-Opening Reactions of Cyclobutenes
pp. 1
Ruthenium-Catalyzed Cycloaddition
pp. 1
Formation of the γ,δ-Alkene
pp. 1
Photochemical Extrusion of Sulfur Dioxide from 2,5-Dihydrothiophene 1,1-Dioxides
pp. 1
1,2-Fused Cyclohexa-1,3-dienes from 2,3-Fused 1,3,5-Trienes
pp. 1
Elimination of Water or Its Equivalent
pp. 1
Nickel-Catalyzed Polyene–Aldehyde Reductive Coupling Reaction with Triethylborane
pp. 1
Loss of Hydrogen and a Nitrogen-Containing Group
pp. 1
Alkylation of -Alkyl-Substituted Aniline Derivatives
pp. 1
Of Sulfonamide-Substituted Arenes
pp. 1
Synthesis from Carbonyl Compounds and Allylsilanes
pp. 1
Under Stoichiometric Conditions
pp. 1
The Still–Gennari Modification
pp. 1
Thermally Induced Sigmatropic Rearrangements
pp. 1
Acyclic 1,3-Dienes from 3-Substituted Cyclobutenes
pp. 1
Synthesis of 1,3-Dienes by Catalytic Carbometalation and Oxymetalation Reactions
pp. 1
Reduction Using Metallic Zinc
pp. 1
Other Reactions
pp. 1
Addition to Aldehydes
pp. 1
Double Dehydration
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