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Alcohols
Oxidation with Sodium Perborate and Sodium Percarbonate
other
Author(s):
M. J. Porter
Publication date
(Online):
2008
Publisher:
Georg Thieme Verlag KG
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Book Chapter
Publication date (Print):
2008
Publication date (Online):
2008
Page
: 1
DOI:
10.1055/sos-SD-036-00024
SO-VID:
d4feafb3-8b22-4802-b706-28427cc41696
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Book chapters
pp. 1
Addition of Organozinc Reagents
pp. 1
Oxidation with Dioxiranes
pp. 1
Addition to Carboxylic Anhydrides
pp. 1
Of Other Acyclic Hydroxyalkenes by Osmium(VIII) Oxide
pp. 1
Synthesis of Product Subclass 1
pp. 1
Synthesis of ()-Pantolactone
pp. 1
Using Catalytic Chiral Lithium Amides
pp. 1
Synthesis by Ozonolysis–Reduction
pp. 1
The Aldol Reaction
pp. 1
Resolution of 2-Phenylcyclohex-2-en-1-ol
pp. 1
Elimination of Allylic Cyclic Carbonates
pp. 1
Direct Catalytic Aldol Reactions
pp. 1
With Organocuprates
pp. 1
Using Metal Borohydrides and Related Reagents
pp. 1
Oxidation with Metal Porphyrins
pp. 1
Anion Translocation/[1,2]-Wittig Rearrangement
pp. 1
Reduction of 4,5-Dihydroisoxazoles
pp. 1
Direct Aldol Reactions Using Chiral Organometallic Catalysts
pp. 1
Oxidation of Chiral Allylic Selenides
pp. 1
Diastereoselective Reduction of Ketones Possessing an α-Stereogenic Center
pp. 1
Oxidation with Ozone
pp. 1
Ring Opening of 2,3-Epoxy Alcohols
pp. 1
Resolution of -Indane-1,2-diol
pp. 1
Nucleophilic Cleavage
pp. 1
Stereoselective Reduction of β-Hydroxy Ketones
pp. 1
In Trifluoromethanesulfonates
pp. 1
Using Lipase B
pp. 1
Using Standard Conditions
pp. 1
Synthesis of Product Subclass 5
pp. 1
[3+2]-Cycloaddition Reactions of Allylsilanes
pp. 1
Using Copper Lewis Acids
pp. 1
Resolution of (2,2-Dimethyl-1,3-dioxolan-4-yl)methanol
pp. 1
Lewis Acid Hydrolysis
pp. 1
Resolution of 1-(2-Bromophenyl)-1-phenylprop-2-yn-1-ol
pp. 1
Using Zinc–Titanium Reagents
pp. 1
Nonenzymatic Resolution of Allylic Alcohols
pp. 1
Using Tin Lewis Acids
pp. 1
Resolution of Hexan-2-ol
pp. 1
Using Metal Aluminum Hydrides and Related Systems
pp. 1
Dihydroxylation
pp. 1
Resolution of 1-(2-Thienyl)pentan-1-ol
pp. 1
Isomerization of Allylic Alcohols
pp. 1
Using Organolithium Reagents
pp. 1
Synthesis of Product Class 6
pp. 1
Oxidation with Chromium Compounds
pp. 1
Titanium(IV)-Mediated Cyclopropanation of Esters
pp. 1
Antibody-Catalyzed Aldol Additions
pp. 1
Diastereoselective Reduction of Ketones Possessing a β-Stereogenic Center
pp. 1
Alkylation of Oxazolidinone Derivatives
pp. 1
Resolution of 1-Phenylethanol via Inclusion Complexation
pp. 1
Resolution of -2-Azidocyclohexanol
pp. 1
Diols by Cleavage of Cyclic Dioxystannanes
pp. 1
Oxidation with Oxaziridines
pp. 1
Oxidation with 2,3-Dichloro-5,6-Dicyanobenzo-1,4-quinone
pp. 1
Using an Ephedrine/Ruthenium Mediated Enantioselective Hydrogenation
pp. 1
[2+2] Photoadditions between Enol Ethers and Alkenes
pp. 1
In Esters
pp. 1
Using Ozone and Then an Aluminum Hydride Reductant
pp. 1
Substitution of Allylic Halides
pp. 1
Using Metal Aluminum Hydrides
pp. 1
Using Metal Borohydrides and Related Compounds
pp. 1
Resolution of 2-(4-Methoxyphenyl)cyclohexanol
pp. 1
[1,2]-Wittig Rearrangement of Benzyl Ethers
pp. 1
Hydroboration–Reduction of Allyl Ketones
pp. 1
Using Chiral Boron Reagents
pp. 1
Nucleophile-Assisted Ring Opening Followed by Radical Reduction
pp. 1
By Isourea Ether Formation Followed by Stereospecific S2 Inversion Using Formic Acid
pp. 1
Meerwein–Ponndorf–Verley Reduction
pp. 1
With Zinc Carbenoids from Other Esters
pp. 1
Resolution of ()-1-(Trimethylsilyl)oct-1-en-3-ol
pp. 1
Of Cyclobutane-1,2-diones
pp. 1
Reduction of Endoperoxides
pp. 1
Addition of Allylic Manganese Reagents in Water
pp. 1
Synthesis of Product Subclass 2
pp. 1
Direct Addition of Allyl- and Propargylzinc Reagents
pp. 1
Enantioselective Hydroxylation with a Ruthenium–Porphyrin Catalyst
pp. 1
Using Boranes or Alane and Related Reagents
pp. 1
Addition of Organocopper Compounds
pp. 1
From Oxasilacycloalkanes
pp. 1
Acidic Hydrolysis
pp. 1
Cyclopropanation of Lithium Enolates with Acylsilanes
pp. 1
Using Metal Borohydrides
pp. 1
By Treatment with Carbon Monoxide
pp. 1
Resolution of 2-Chloro-1-phenylethanol
pp. 1
Amine-Catalyzed Aldol Additions
pp. 1
Ring Contraction
pp. 1
Resolution of ()-Undeca-1,5-dien-3-ol
pp. 1
Ethylmagnesiation Catalyzed by Dichlorobis(cyclopentadienyl)zirconium(IV) followed by In Situ Oxygenation
pp. 1
Intramolecular Metallo-Ene Reactions of Aldehydes and Ketones Containing Allylmetal Groups
pp. 1
Oxidation with Basic Hydrogen Peroxide
pp. 1
Resolution of 2-Methylhexan-1-ol Using Lipase
pp. 1
Hydrolysis of Epoxides
pp. 1
Diols by Cleavage of Cyclic Acetals
pp. 1
Oxidation of Organomercury Compounds
pp. 1
Using Aluminum Hydrides and Borohydride Reducing Agents
pp. 1
Using Mercury(II) Acetate–Sodium Borohydride
pp. 1
Oxidation with Peroxy Acids
pp. 1
Electrochemical Reduction
pp. 1
Resolution of Hexane-1,2-diol
pp. 1
Dehydrodimerization of Alcohols
pp. 1
Reduction of β-Hydroxy Ketones
pp. 1
Resolution of -2-(1-Methyl-1-phenylethyl)cyclohexanol
pp. 1
Reaction of Lithium Dianions with Carboxy Compounds
pp. 1
Enantioselective Additions via Transmetalation to Rhodium
pp. 1
Dihydroxylation of Dienes and Trienes by Osmium(VIII) Oxide
pp. 1
Lithium Additions
pp. 1
By Displacement of Halides
pp. 1
Synthesis of Product Class 5
pp. 1
Alkyne Additions to Aldehydes
pp. 1
Reactions with β-Bromo Esters via β-Bromo Ketones
pp. 1
By Isourea Ether Formation Followed by Stereospecific S2 Inversion Using Acetic Acid
pp. 1
Group 13 Metal Alcoholates
pp. 1
1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Other Reagents
pp. 1
Using a Chiral Diphosphine
pp. 1
Alkyne Additions to Ketones
pp. 1
Cleavage by Metal Catalysis
pp. 1
Reduction of Ketones
pp. 1
Using an Asymmetric Mitsunobu Reaction
pp. 1
Using Boranes and Related Systems
pp. 1
In Acetals
pp. 1
Resolution of 2-(-Butylamino)-1-(2,2-dimethyl-4-1,3-benzodioxin-6-yl)ethanol
pp. 1
Nucleophilic Addition of Boronic Acids to Imines (The Petasis Reaction)
pp. 1
With Enolates and Equivalent Compounds
pp. 1
Resolution of -2-Phenylcyclohexanol
pp. 1
Intramolecular Radical Additions to Aldehydes and Ketones
pp. 1
Using Lipozyme
pp. 1
[1,2]-Acyl and -Allyl Transfer
pp. 1
Using Silicon Reagents
pp. 1
Cyclopropanation of Enol Derivatives
pp. 1
Synthesis of Product Subclass 3
pp. 1
Synthesis by Transmetalation of an Alcoholate
pp. 1
Oxidation of Organoboron Compounds
pp. 1
Lithium Alcoholates
pp. 1
Synthesis of ()- and ()-1-Phenylethanol Using a Sequential Enzyme Resolution/Mitsunobu Inversion Process
pp. 1
Resolution of 4-Phenylbut-3-yn-2-ol and 3-Phenylbut-3-en-2-ol
pp. 1
Ring Expansion
pp. 1
Reduction of Alkynones
pp. 1
Enantioselective Reduction of Ketones
pp. 1
Synthesis by Reductive Lithiation of C—O Bonds
pp. 1
Synthesis of Product Class 9
pp. 1
Oxidation with Ruthenium Compounds
pp. 1
Cyclopropanation of Alkenes with Alkoxycarbenes or Acyloxycarbenoids
pp. 1
Reactions of Aldehydes/Ketones with α-Halo Ketones (Reformatsky Reaction)
pp. 1
Sharpless Dihydroxylation
pp. 1
Intramolecular Ring Opening of Epoxides
pp. 1
Direct Addition Using Unusual Reaction Conditions
pp. 1
Acid-Mediated Rearrangements
pp. 1
Reactions of Achiral Allylboron Reagents with Chiral Aldehydes
pp. 1
Pinacol Reactions of 1,4-Diketones
pp. 1
Using Organocopper Reagents
pp. 1
Resolution of 1-Phenylethanol by Enantioselective Reduction
pp. 1
Catalyzed by Epoxide Hydrolase
pp. 1
Cyclization of Epoxide-Derived Radicals
pp. 1
Catalytic Addition of In Situ Generated Organochromium Species
pp. 1
Using Chiral Aluminum Reagents
pp. 1
-[2,3]-Wittig Rearrangement
pp. 1
Epoxide Ring Opening with Nitrogen Nucleophiles
pp. 1
Reactions of α-Substituted Epoxides and Ketones
pp. 1
Reduction of Nitriles
pp. 1
Synthesis of Acyclic Secondary Alkanols Possessing a Stereogenic Center Containing No Heteroatoms
pp. 1
Alcohols by Cleavage of Carbonates and Carbamates
pp. 1
From Silacyclopentanes
pp. 1
Synthesis of ()- and ()-1-Phenylethanol by Deracemization
pp. 1
Transition-Metal-Catalyzed Hydrogenation
pp. 1
With Chiral Allyl Groups
pp. 1
Using Palladium Lewis Acids
pp. 1
Rhodium-Catalyzed Enantioselective Diboration of Alkenes
pp. 1
1,2-Diols
pp. 1
Oxidation of Alkanes
pp. 1
Addition of Organolithium Reagents to Epoxides
pp. 1
Using Amano P Lipase
pp. 1
Miscellaneous Procedures
pp. 1
[2+2]-Cycloaddition Reactions of α,β-Unsaturated Carbonyl Compounds with Enol Ethers
pp. 1
Miscellaneous Methods
pp. 1
Direct Addition of Alkenyl- and Alkynylmagnesium Halides
pp. 1
Using 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
pp. 1
Rearrangement of Epoxides Using Other Reagents
pp. 1
Using an Octapeptide
pp. 1
By Hydrogenation
pp. 1
Direct Addition of Alkyl- and Arylmagnesium Halides
pp. 1
Enantioselective Addition of Organoaluminum Reagents
pp. 1
Group 14 Alcoholates
pp. 1
Resolution of -Cyclohexane-1,2-diol
pp. 1
Reduction of Epoxides with Samarium(II) Iodide
pp. 1
Michael Addition–Reduction of α,β-Unsaturated Enones
pp. 1
Reduction of Aldehydes
pp. 1
Biocatalytic Oxidation
pp. 1
Synthesis by Homologation of Alcohols Using Carbon Monoxide/Hydrogen
pp. 1
Double Allylboration Reactions
pp. 1
Reactions Proceeding via the Intermediate Carboxylic Acid or Ester
pp. 1
Addition of Organozinc Reagents
pp. 1
Synthesis of Secondary Aliphatic Alkanols
pp. 1
Reduction of Amides
pp. 1
Synthesis by Nucleophilic Addition
pp. 1
With Alkoxylated Fischer Carbene Complexes
pp. 1
Synthesis by Alkylative Hydroxylation
pp. 1
Using Zinc Reagents
pp. 1
Intramolecular Reactions of β-Functionalized Carbonyl Compounds
pp. 1
Fluoride-Mediated Cleavage
pp. 1
Cleavage by Reaction with Fluoride
pp. 1
Reduction of Hydroperoxides and Peroxides
pp. 1
Reduction of Unactivated Epoxy Alcohols
pp. 1
By Coupling of a Terminal Alkyne
pp. 1
Cyclobutanols
pp. 1
Reduction of Sulfonylated Epoxy Alcohols
pp. 1
Reactions of Dithianes with Epoxides
pp. 1
Synthesis by Rearrangements
pp. 1
Ring Opening of β-Hydroxy δ-Lactones
pp. 1
Reactions Proceeding via the Intermediate Aldehyde
pp. 1
Using Chiral Ruthenium Catalysts
pp. 1
Rearrangement of α-Allyloxy Enolates
pp. 1
Ozonation of Alkenylstannanes
pp. 1
Enantioselective Additions of Organolithium Derivatives
pp. 1
Deprotection of Chiral Acetals Derived from Ene Acetals
pp. 1
Synthesis of (3β,5α)-Cholestan-3-ol
pp. 1
Synthesis Using Organoboron Reagents
pp. 1
Using Alane and Related Compounds
pp. 1
Alcohols by Cleavage of Ethers
pp. 1
Of Zinc Enolates
pp. 1
Propargylation and Rearrangement of Allylic Alcohols
pp. 1
1,4-Diols
pp. 1
Asymmetric Copper-Catalyzed Alkenylations of Carbonyl Compounds
pp. 1
Using Samarium(II) Iodide
pp. 1
Samarium(II)-Mediated Ketyl Alkene Cyclizations
pp. 1
By Treatment with Carbon Monoxide in the Presence of Hydrides
pp. 1
Intramolecular Kulinkovich Reactions
pp. 1
Fluoride Hydrolysis
pp. 1
Substitution of Oxygen Functionalities
pp. 1
Reductive Lithiation of Acyclic Ethers
pp. 1
Direct Addition Using Barbier Conditions
pp. 1
Using a Combination of Novozym 435 and a Ruthenium Complex
pp. 1
1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Boron Reagents
pp. 1
Using Ozone and Then a Borohydride or Borane Reductant
pp. 1
-Selective Reduction of β-Hydroxy Ketones by Diethyl(methoxy)borane and Sodium Borohydride
pp. 1
Resolution of 2-Phenylpropan-1-ol
pp. 1
Resolution of -4-(Dimethylamino)--(2-hydroxycyclohexyl)benzamide
pp. 1
Hydrolysis of Alkyl Halides
pp. 1
Asymmetric Dihydroxylation
pp. 1
Chromium and Molybdenum Alcoholates
pp. 1
Resolution of -2-(Dimethylcarbamoyloxy)cyclohexanol
pp. 1
Hydroboration and Carbonylation of Trienes
pp. 1
Prévost–Woodward Dihydroxylation
pp. 1
Intramolecular Morita–Bayliss–Hillman Reactions
pp. 1
Cyclopropanation of Allylic Alcohols
pp. 1
Aqueous Hydrolysis
pp. 1
By an Aldol–Reduction Sequence
pp. 1
Enzyme-Catalyzed Aldol Additions
pp. 1
Addition to Carboxylic Acid Esters
pp. 1
[1,4]-Wittig Rearrangements
pp. 1
Catalytic Aldol Additions of Silicon Enolates Using Lewis Acids
pp. 1
Resolution of ()-1-Cyclohexylbut-2-en-1-ol
pp. 1
Resolution of -2-[Methyl(phenyl)amino]cyclohexanol
pp. 1
Cleavage by Substitution with Iodide
pp. 1
Reductive Lithiation of Cyclic Ethers
pp. 1
Diols by Cleavage of Cyclic Carbonates
pp. 1
Cyclopropanation of Esters and Acyl Sulfonamides (Kulinkovich Reaction)
pp. 1
Hydride-Type Reduction of Alkynals
pp. 1
Reduction of Thioesters
pp. 1
Addition of Other Organometallic Reagents
pp. 1
Nucleophilic Additions to Epoxides
pp. 1
Intramolecular Aldol Reactions
pp. 1
Resolution of 5-(Hydroxymethyl)oxazolidin-2-one
pp. 1
Intramolecular Nucleophilic Addition Reactions
pp. 1
Reduction of Ozonides
pp. 1
Reactions with β-Stannylated Compounds
pp. 1
Using (Trimethylstannyl)methyl Ethers
pp. 1
Addition of Organomanganese Compounds
pp. 1
Using Achiral Lithium Amides
pp. 1
Using a Palladium-Catalyzed Deracemization Reaction
pp. 1
Enzymatic Resolution of Allylic Alcohols
pp. 1
Basic Hydrolysis
pp. 1
Group 15 Metal Alcoholates
pp. 1
Catalytic, Enantioselective Additions of Organozinc Reagents
pp. 1
Enzymatic Dihydroxylation
pp. 1
Aldol Reactions of Aldehydes with Hydroxyacetone
pp. 1
Diols by Cleavage of Cyclic Boronates
pp. 1
Achiral Reductants and Substrate-Controlled Diastereoselective Reduction
pp. 1
Using a Planar-Chiral 4-(Dimethylamino)pyridine Complex
pp. 1
Using Metal Aluminum Hydrides and Alkoxyaluminum Hydrides
pp. 1
Hydroxylation of Allylic Alcohols
pp. 1
Using Heterogeneous Nickel Catalysts
pp. 1
Resolution of 1,1′-Binaphthalene-2,2′-diol
pp. 1
Additions via Transmetalation to Rhodium
pp. 1
Additions of Organometallic Reagents to α,β-Unsaturated Carbonyl Compounds
pp. 1
Using Single-Electron-Transfer Agents
pp. 1
Synthesis by [2,3]-Wittig Rearrangement
pp. 1
β-Heteroatom-Functionalized Alcohols
pp. 1
Using Aluminum Hydrides
pp. 1
Stereoselective Epoxidation of Allylic Alcohols
pp. 1
Oxidation of Benzylic C—H Groups
pp. 1
[2+2] Cycloadditions of Allylic Alcohols
pp. 1
Dihydroxylation of Alkenes
pp. 1
Synthesis of Product Subclass 4
pp. 1
Reaction by Radical Formation
pp. 1
Using Aluminum Hydride and Alkoxyaluminum Hydride Reducing Agents
pp. 1
Addition of Allylic Indium Reagents
pp. 1
Directed Dihydroxylation
pp. 1
Kulinkovich Reactions with Substituted Alkenes
pp. 1
Using an Octapeptide Derived from a Split-and-Pool Library
pp. 1
Thiol–Alkene Co-oxidation
pp. 1
Using Nonenantioselective Aluminum Hydride Reagents
pp. 1
Reduction of Unsaturated 1,4-Diketones
pp. 1
Resolution of 1-Phenoxypropan-2-ol
pp. 1
Synthesis of Product Subclass 6
pp. 1
Cyclopropanols
pp. 1
Transition-Metal-Catalyzed Reduction
pp. 1
1,6-Diols
pp. 1
Using Organostannanes and Organostibines
pp. 1
Alcohols by Cleavage of Acetals
pp. 1
Addition of Organometallic Reagents to Vinyl Epoxides
pp. 1
Synthesis from Organosilanes
pp. 1
Dihydroxylation of Allylic Alcohols
pp. 1
Retro-Brook Rearrangements
pp. 1
Addition of Other Organometallics
pp. 1
Gold- and Rhodium-Catalyzed Aldol Additions
pp. 1
Transition-Metal-Catalyzed Alkenylation of Carbonyl Compounds
pp. 1
Direct Addition of Alkyl- and Aryllithiums
pp. 1
Using Osmium(VIII) Oxide Encapsulated in a Polyurea Matrix
pp. 1
Using Ionic Liquids
pp. 1
Using Zirconium Lewis Acids
pp. 1
Using a Chiral Pyridinium Acyl-Transfer Reagent
pp. 1
Resolution of ()-Pent-3-en-2-ol
pp. 1
Using an Oxazolidinone as a Benzoyl- or Phosphoryl-Transfer Reagent
pp. 1
Using Stoichiometric Chiral Lithium Amides
pp. 1
Synthesis of ()- and ()-1-Phenylethanol via Enzymatic Ester Formation
pp. 1
Alcohols by Cleavage of Siloxanes
pp. 1
Using Nonenantioselective Ruthenium Catalysts
pp. 1
Synthesis of Product Class 4
pp. 1
Using Organozinc Reagents
pp. 1
Using Boron Lewis Acids
pp. 1
Synthesis of Product Subclass 1
pp. 1
Nucleophilic Ring Opening of Oxetanes with Phosphorus-Stabilized Carbanions
pp. 1
Synthesis of (1,2,5)-Menthol
pp. 1
Synthesis by Deprotonation of an Alkanol
pp. 1
γ-Heteroatom-Functionalized Alcohols
pp. 1
Synthesis from 1,3-Dihalo Ketones
pp. 1
By Reductive Lithiation
pp. 1
Oxidation of Alkoxysilanes with Peroxy Acids
pp. 1
Reduction of Esters
pp. 1
Synthesis by Reductive Hydration of Alkynes
pp. 1
Resolution of 1-Phenylbutan-1-ol
pp. 1
Additions to Titanium Enolates
pp. 1
Reduction of 2,3-Epoxy Alcohols
pp. 1
Phosphate-Based Carbanion Rearrangements
pp. 1
Epoxide Homologations
pp. 1
By Rearrangement of 2,3-Epoxy Alcohols
pp. 1
Reductive Cleavage
pp. 1
Enantioselective [1,2]-Wittig Rearrangement
pp. 1
With Allyl Groups Containing Stereocenters at C1 or C4
pp. 1
Resolution of 1-Phenylpropan-1-ol
pp. 1
Synthesis by Carbonylation of Boranes
pp. 1
Cyclization of Epoxyalkenes
pp. 1
In 4-Toluenesulfonates
pp. 1
Treatment of α-Halo Epoxides with Samarium(II) Iodide
pp. 1
Using Nonenantioselective Boron Reagents
pp. 1
Using Organolithium Reagents
pp. 1
Synthesis by Transmetalation
pp. 1
Using Organolithium Reagents
pp. 1
Synthesis of Tertiary Aliphatic Alkanols
pp. 1
Using Borohydrides
pp. 1
Synthesis of Product Subclass 2
pp. 1
Boron-Tethered Radical Cyclization
pp. 1
Using a Tripeptide
pp. 1
Intramolecular Alkyne–Aldehyde (Ynal) Cyclizations
pp. 1
Using Alane and Other Neutral Organoaluminum Reagents
pp. 1
Oxidation of Organosilicon Compounds
pp. 1
Intramolecular Cyclization of Hydroxy Vinylcyclopropanes
pp. 1
Photoprotonation-Initiated Hydration of Alkenes
pp. 1
With Samarium(II) Iodide/Diiodomethane
pp. 1
Synthesis of Product Subclass 7
pp. 1
Higher Group 1 Metal Alcoholates
pp. 1
Epoxide Ring Opening with Heteroatom-Stabilized Carbanions
pp. 1
With Chiral Ligands on Boron
pp. 1
Using Cyanide Anion
pp. 1
Via an Inclusion Complex
pp. 1
Reduction of Allylic Alcohols
pp. 1
Addition to Carbon Dioxide
pp. 1
Non-Transition-Metal Methods
pp. 1
Synthesis of Product Class 11
pp. 1
Synthesis of Product Subclass 1
pp. 1
Using Porcine Pancreatic Lipase
pp. 1
By Oxidation
pp. 1
Using Dissolving Metal Conditions
pp. 1
Substitution of Sulfonate Anions
pp. 1
Allylic Rearrangements
pp. 1
Diastereoselective Additions to Cyclic Carbonyl Derivatives
pp. 1
Intramolecular Nucleophilic Additions to Aldehydes, Ketones, and Acetals
pp. 1
Using an Asymmetric Katsuki–Jacobsen Epoxidation Reaction
pp. 1
Oxidation of Organolithium, Organomagnesium, Organozinc, and Organocopper Compounds
pp. 1
Enantioselective Hydroxylation with Vaulted Metalloporphyrin Catalysts
pp. 1
Reduction of Hydroxylamines
pp. 1
Resolution of Methyl 2-Hydroxy-3-(4-methoxyphenyl)-3-[(2-nitrophenyl)sulfanyl]propanoate
pp. 1
Addition across Carbonyl Bonds
pp. 1
Synthesis from α,β-Unsaturated Carbonyl Compounds
pp. 1
Using Lipase
pp. 1
Cycloaddition Reactions of Enol Ethers
pp. 1
Addition of Phosphorus Ylides to Carbonyl Compounds
pp. 1
Stoichiometric Asymmetric Reduction with Chiral Aluminum Hydrides
pp. 1
Addition of Allylic Boron Reagents
pp. 1
Chelation-Controlled Addition of Organometallics
pp. 1
Ring Opening of Epoxides with Organometallic Reagents
pp. 1
Using a Polymer-Supported Diamine
pp. 1
1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Ruthenium Catalysts
pp. 1
Using , and Horseradish Peroxidase
pp. 1
Using Silanes
pp. 1
Using Stannanes and Related Systems
pp. 1
Synthesis Using Organotin Reagents
pp. 1
Asymmetric C-Alkylation of Alcohols by Deprotonation/Addition
pp. 1
Additions to Magnesium Enolates
pp. 1
Asymmetric Transfer Hydrogenation
pp. 1
In Tertiary Haloalkanes
pp. 1
Addition of Organozirconocene Compounds
pp. 1
Addition of Organolithium and Organomagnesium Reagents
pp. 1
Enantioselective Additions of Lithium/Magnesium Binary Reagents
pp. 1
Titanium and Zirconium Alcoholates
pp. 1
Epoxide Ring Opening with Sulfur, Selenium, or Tellurium Nucleophiles
pp. 1
Using Indium Reagents
pp. 1
Synthesis of Product Subclass 3
pp. 1
Resolution of 2,2-Dimethyl-1,3-diphenylpropane-1,3-diol
pp. 1
Using Organosilanes and Related Systems
pp. 1
Rhenium-Catalyzed Rearrangements
pp. 1
Synthesis of Product Subclass 10
pp. 1
Palladium-Catalyzed C-Alkylation of Allylic Alcohols
pp. 1
1,5-Diols
pp. 1
Addition of Carbon Groups to Alkynals
pp. 1
Using a Ferrocene-Based Chiral 4-(Dimethylamino)pyridine
pp. 1
Synthesis by Combination with Organolithium Substrates
pp. 1
δ-Heteroatom-Functionalized Alcohols
pp. 1
Elimination of β-Hydroxy Selenides
pp. 1
Addition of 1,1-Bimetallic Reagents to α-Substituted Ketones
pp. 1
Aziridine Substitution Reactions
pp. 1
Miscellaneous Additions
pp. 1
Resolution of -2-(Benzoyloxy)cyclohexanol
pp. 1
Oxymercuration Followed by Reduction
pp. 1
Using Mercury(II) Acetate–Sodium Amalgam
pp. 1
Hydroxysulfenylation Using Electrophilic Sulfur
pp. 1
Intramolecular Carbonyl-Ene Reactions of Unsaturated Aldehydes and Ketones
pp. 1
Resolution of 2-Methylpent-1-en-3-ol
pp. 1
Direct Addition of Organocopper Reagents
pp. 1
Oxidation of Alkoxysilanes with Molecular Oxygen
pp. 1
[2,3]-Wittig Rearrangements
pp. 1
Regioselective Reduction of Diepoxy Alcohols
pp. 1
Epoxide Ring Opening with Oxygen Nucleophiles
pp. 1
Group 16 Metal Alcoholates
pp. 1
Asymmetric Iridium-Catalyzed Substitutions of Allylic Carbonates
pp. 1
Nucleophilic Ring Opening of Oxetanes
pp. 1
Reduction of Alkynals
pp. 1
Using [(Allyloxy)methyl]-4,5-Dihydrooxazoles and [(Allyloxy)methyl]-5,6-Dihydro-1,3-oxazines
pp. 1
With Transition Metals
pp. 1
Using Boranes
pp. 1
Functionalization of α-Hydroxy Carbonyl Compounds
pp. 1
Oxidation with Sodium Perborate and Sodium Percarbonate
pp. 1
With Less Than a Stoichiometric Amount of Selenium Dioxide
pp. 1
Allylation of β-Hydroxy Aldehydes
pp. 1
By Elimination
pp. 1
Synthesis by Metalation of an Alkanol Equivalent
pp. 1
Direct Addition Using Additives
pp. 1
In Aqueous Media
pp. 1
Addition of Organocerium Compounds
pp. 1
In Methanesulfonates
pp. 1
Synthesis Using Other Organometallic Reagents
pp. 1
Allylic Substitution
pp. 1
Using Silanes and Siloxanes
pp. 1
Reductive Ring Opening of Cyclic Ethers
pp. 1
Synthesis of Product Subclass 6
pp. 1
Addition of Organoiron Compounds
pp. 1
Intramolecular Epoxide-Opening Reactions
pp. 1
[1,2]-Wittig Rearrangements
pp. 1
Using Single-Electron-Transfer Reduction Strategies
pp. 1
Resolution of 3-(Ethoxycarbonyl)but-3-en-2-ol
pp. 1
Rearrangement of Epoxides Using Lithium Amides
pp. 1
Oxidation with Alkyl Hydroperoxides
pp. 1
Oxidation with Bis(trimethylsilyl) Peroxide
pp. 1
Additions to Boron Enolates
pp. 1
Using Mercury(II) Trifluoroacetate–Sodium Borohydride
pp. 1
Diastereoselective Additions to Acyclic Carbonyl Derivatives
pp. 1
Resolution of Pentane-1,2-diol
pp. 1
Using Mercury(II) Acetate–Sodium Trithiocarbonate
pp. 1
In Reactions with Chiral Aldehydes
pp. 1
Reduction of Carboxylic Acids
pp. 1
Using Aluminum Hydrides and Related Reagents
pp. 1
Using Lipase QL
pp. 1
Addition via Transmetalation
pp. 1
Asymmetric Transition-Metal-Catalyzed Hydrogenation and Transfer Hydrogenation
pp. 1
Oxidation of Trichlorosilanes
pp. 1
Reaction of Organolithium Compounds with Epoxides
pp. 1
Of Samarium Enolates
pp. 1
Reduction of Acid Halides and Acid Anhydrides
pp. 1
Synthesis Using Organochromium Reagents
pp. 1
Rearrangement of a Carbolithiate
pp. 1
Oxidation with Selenium Reagents
pp. 1
Synthesis Using Organosilicon Reagents
pp. 1
Transition-Metal-Catalyzed Hydrogenation and Transfer Hydrogenation
pp. 1
Diastereoselective Additions of Organozinc Reagents
pp. 1
Resolution of 4-Phenylbut-3-en-2-ol
pp. 1
Cobalt- or Manganese-Catalyzed Hydration of Alkenes
pp. 1
Using Magnesium Reagents
pp. 1
Diols by Cleavage of Cyclic Dioxysilanes
pp. 1
Additions of Aldehydes to Preformed Enolates
pp. 1
Using Reusable Osmium(VIII) Oxide on Ion Exchanger
pp. 1
Reduction of α-Halo Epoxides
pp. 1
1,3-Diols
pp. 1
Aldol Additions
pp. 1
Using Borohydride Reducing Agents
pp. 1
Synthesis of Product Subclass 1
pp. 1
Using a Chiral Atropisomeric 4-(Dimethylamino)pyridine Equivalent
pp. 1
Intramolecular Nucleophilic Additions to Ketones
pp. 1
Additions to α-Epoxy Hydrazones
pp. 1
Hydrolytic Kinetic Resolution of Terminal Epoxides
pp. 1
Achiral Catalytic Alkenylations of Carbonyl Compounds
pp. 1
Resolution of 2-[(-Butoxycarbonyl)amino]-3-(hydroxymethyl)bicyclo[2.2.1]heptane
pp. 1
-Selective Reduction of β-Hydroxy Ketones by Tetramethylammonium Triacetoxyborohydride
pp. 1
Group 2 Metal Alcoholates
pp. 1
By In Situ Derivatization
pp. 1
Synthesis of 1-Deuterooct-2-yn-1-ol
pp. 1
Resolution of ()-3-(Trimethylsilyl)oct-3-en-2-ol
pp. 1
Thiirane Substitution Reactions
pp. 1
By Organometallics
pp. 1
Resolution of 2,2,2-Trifluoro-1-(1-naphthyl)ethanol
pp. 1
1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Aluminum Hydride Reagents
pp. 1
Carboalumination Catalyzed by Bis(cyclopentadienyl)zirconium(IV) Complexes with In Situ Oxygenation
pp. 1
Catalytic Asymmetric Reduction with Chiral Oxazaborolidines
pp. 1
Resolution of 1-(4-Methoxyphenyl)ethanol
pp. 1
Nucleophilic Addition of Sulfur-, Selenium-, or Tellurium-Stabilized Carbanions to Carbonyl Groups
pp. 1
Enzymatic Reduction
pp. 1
Using Meerwein–Ponndorf–Verley-Type Reactions
pp. 1
Upjohn Dihydroxylation
pp. 1
Using Bis(dipivaloylmethanato)manganese(II), Phenylsilane, and Oxygen
pp. 1
Direct Aldol Reactions Catalyzed by Proline
pp. 1
Resolution of 1-(2-Thienyl)butan-1-ol
pp. 1
Reactions of α-Halo Epoxides with Grignard Reagents
pp. 1
Synthesis of Product Subclass 3
pp. 1
Resolution of Pentane-2,4-diol Using Lipase
pp. 1
Addition to Carboxylic Acids
pp. 1
Alcohols by Cleavage of Sulfonates and Sulfenates
pp. 1
Addition to Allylic Alcohols
pp. 1
Using Boranes, Alanes, and Related Reagents
pp. 1
By Sulfonylation Followed by Stereospecific S2 Inversion
pp. 1
Hydrogenolysis
pp. 1
Oxidative Cleavage
pp. 1
Using Grignard Reagents
pp. 1
Substitution of Halides
pp. 1
Using Enolate Ions
pp. 1
Synthesis of Product Subclass 2
pp. 1
Addition of Grignard Reagents
pp. 1
Hydride Reduction of Substituted 2,4-Diene-1,6-dials
pp. 1
Synthesis of Product Class 3
pp. 1
Of Acyclic Allylic Alcohols by Osmium(VIII) Oxide
pp. 1
Oxidation with Trimethylamine -Oxide
pp. 1
Reaction with Electrophiles
pp. 1
Using Borohydrides and Aluminum Hydrides
pp. 1
Resolution of 1-Phenylethane-1,2-diol
pp. 1
Hydroboration of Allylic Substrates
pp. 1
Hydrogenolytic Cleavage
pp. 1
Synthesis of β-Amino Alcohols by Aminohydroxylation of Alkenes
pp. 1
Zirconium-Mediated Ring Contractions of 4-Vinylfuranosides
pp. 1
Using Rhodium Reagents
pp. 1
Resolution of --(2-Hydroxycyclohexyl)acetamide
pp. 1
Using a Planar-Chiral 4-(Dimethylamino)pyridine Equivalent Complex
pp. 1
Reductive Decomplexation of π-Allyltricarbonyliron Lactone Complexes
pp. 1
Synthesis of Product Subclass 2
pp. 1
Additions to Lithium Enolates
pp. 1
Additions via Transmetalation
pp. 1
From Aryldimethylsilanes
pp. 1
Synthesis by Allylation of Carbonyl Compounds
pp. 1
Alkenylation of Carbonyl Compounds
pp. 1
Using Metal Borohydrides and Related Systems
pp. 1
Rearrangement of Allyl Lithiomethyl Ethers
pp. 1
Of 1,2-Bis(trimethylsiloxy)cyclobutenes
pp. 1
Using a Manganese(III)–salen Complex
pp. 1
Addition to Acyl Chlorides
pp. 1
Addition of Organolanthanum Compounds
pp. 1
Using a Chiral Dianiline/Ruthenium Mediated Enantioselective Hydrogenation
pp. 1
Oxymercuration of Homoallylic Hemiacetals
pp. 1
Reactions of Chiral Allyltin Reagents with Chiral Aldehydes (Double Stereodifferentiation)
pp. 1
Using Copper–Zinc Reagents
pp. 1
Intramolecular Ketyl Radical Cyclizations
pp. 1
Resolution of Oct-1-yn-3-ol
pp. 1
Synthesis by Carbonylation of Alkyl Halides
pp. 1
Using Zinc Reagents
pp. 1
Oxidation of Alkoxysilanes with Hydrogen Peroxide
pp. 1
Epoxide Ring Opening with Phosphorus Nucleophiles
pp. 1
Reduction of β-Dicarbonyls
pp. 1
Norrish–Yang Photocyclization of Aryl Ketones
pp. 1
[2+2]-Cycloaddition Reactions
pp. 1
Rearrangement of Oxaspiropentanes
pp. 1
Cycloadditions of 1-Alkoxylated Dienes
pp. 1
Metalated Epoxide Rearrangements
pp. 1
Using a [(4,5-Dihydrooxazolyl)ferrocenyl]phosphine–Ruthenium Complex
pp. 1
Pinacol Couplings
pp. 1
Using Baker's Yeast
pp. 1
Reaction of Allylic Alcohols with Singlet Oxygen
pp. 1
Elimination Reactions of Iodo Ketals
pp. 1
Using Borane, Alane, and Related Systems
pp. 1
With Carbenes Derived from Chloromethyl Ethers
pp. 1
Diastereoselective Reduction of Ketones Possessing α- and β-Stereogenic Centers
pp. 1
Ring Opening of Epoxides with Carbon Nucleophiles
pp. 1
Using Lithium Reagents
pp. 1
Coupling of Vinyloxiranes and Ketones
pp. 1
Of Bis(epoxides) and Tris(epoxides)
pp. 1
Lewis Base Catalyzed Aldol Additions
pp. 1
Cyclization of Allylmetal Epoxides
pp. 1
In Secondary Haloalkanes
pp. 1
Stoichiometric Asymmetric Reduction with Chiral Boranes
pp. 1
Resolution of 1-Phenylethanol by Enantioselective Oxidation
pp. 1
Epoxidation of Allylic Alcohols
pp. 1
With Chloromethyllithium
pp. 1
Nonmetallic Methods
pp. 1
Resolution of -2-[4-(Dimethylamino)benzoyloxy]cyclohexanol
pp. 1
C-Alkylation of Allylic Alcohols by Boration
pp. 1
Addition of Organoboron, Organotin, Organosilicon, and Organoindium Reagents
pp. 1
Decarboxylation
pp. 1
Asymmetric Nickel-Catalyzed Alkenylation of Carbonyl Compounds
pp. 1
Enzymatic Hydrolysis
pp. 1
Intramolecular Additions of Organometallic Reagents
pp. 1
Synthesis from Other Propargylic Alcohols
pp. 1
With a Catalytic Amount of Selenium Dioxide
pp. 1
Dihydroxylation of Hydroxyalkenes
pp. 1
Resolution of 2-Ethylhexan-1-ol
pp. 1
Vanadium Alcoholates
pp. 1
Enantioselective Addition of Organotitanium Reagents
pp. 1
Using Single-Electron-Transfer Methods
pp. 1
Synthesis by Nucleophilic Ring Opening
pp. 1
Titanium(IV) Isopropoxide Mediated Coupling of Butylmagnesium Chloride with Aldehydes and Ketones
pp. 1
Reactions of Chiral Allylboron Reagents with Chiral Aldehydes (Double Stereodifferentiation)
pp. 1
Resolution of Cyclohex-2-en-1-ol
pp. 1
Hydroxyselenation Using Electrophilic Selenium
pp. 1
Ring Contractions
pp. 1
Reduction of Propargylic Alcohols to -Alk-2-enols
pp. 1
Resolution of 2,2-Dimethylcyclopentan-1-ol
pp. 1
Oxidation with Molecular Oxygen
pp. 1
Reduction of Peroxides and Related Systems
pp. 1
Synthesis of Product Subclass 5
pp. 1
Titanium(IV) Chloride Mediated Addition of Octa-2,6-diene to Aldehydes
pp. 1
Using a Combination of Lipase and a Rhodium Catalyst
pp. 1
Using Alkali Metal and Alkaline Earth Metal Hydrides and Related Systems
pp. 1
Rearrangement of Sulfoxides
pp. 1
Miscellaneous Reductions
pp. 1
Resolution of 6,10,14-Trimethylpentadecan-2-ol
pp. 1
Using AK
pp. 1
Additions via Transmetalation to Palladium
pp. 1
Hydroxytelluration Using Electrophilic Tellurium
pp. 1
Reduction of Hydroperoxides, Peroxides, and Related Systems
pp. 1
Using a (–)-Sparteine–Palladium(II) Complex
pp. 1
Using Silver–Zirconium Reagents
pp. 1
Intramolecular Pinacol Reactions
pp. 1
Other Methods of Nonenzymatic Resolution
pp. 1
Using Tricarbonylcobalt Complexes and Carbon Monoxide/Hydrogen
pp. 1
Rearrangement of Epoxy Silyl Ethers
pp. 1
Elimination of α-Epoxystannanes
pp. 1
Ketyl Radical Cyclization Reactions
pp. 1
Addition of Organocadmium Reagents
pp. 1
Using Titanium Reagents
pp. 1
Alcohols by Cleavage of Esters
pp. 1
Acid-Catalyzed Addition of Water
pp. 1
Direct Addition of Alkyl- and Arylzinc Reagents
pp. 1
Using a Phosphabicyclooctane Acyl-Transfer Catalyst
pp. 1
With Chiral Allyl Groups or Chiral Lewis Acids
pp. 1
Using Mercury(II) Salts–Sodium Borohydride
pp. 1
In Primary Haloalkanes
pp. 1
Palladium-Catalyzed Eliminations
pp. 1
In Reactions Using Chiral Lewis Acids
pp. 1
Lewis Acid Mediated Hydrolysis
pp. 1
Photolytic Cleavage
pp. 1
Using Silver Lewis Acids
pp. 1
Addition of Carbon Groups to Alkynones
pp. 1
Using Organochromium Reagents
pp. 1
Addition of Organoaluminum Compounds
pp. 1
By Hydroboration–Rearrangement of 1,2-Disubstituted Cyclobutenes
pp. 1
Oxidation with Methyltrioxorhenium(VII)
pp. 1
Using Indium Reagents
pp. 1
Using Samarium(II) Iodide
pp. 1
Of Epoxy Alcohols
pp. 1
Using Boranes and Neutral Aluminum Hydride Reagents
pp. 1
Resolution of Ethyl Hydroxy(phenyl)acetate
pp. 1
Synthesis of Product Class 8
pp. 1
Enantioselective Hydroxylation with Manganese–salen Catalysts
pp. 1
Additions of Metalated Selenoxides
pp. 1
Zinc Additions
pp. 1
Radical Cyclization with In Situ Oxygenation
pp. 1
Using Titanium Lewis Acids
pp. 1
By Radical Carbonylation
pp. 1
Synthesis of Product Subclass 3
pp. 1
With Organometallics
pp. 1
Using Neutral Organoaluminum Reagents
pp. 1
Using a Double-Inversion Method
pp. 1
Resolution of -2-Pyrrolidin-1-ylcyclohexanol
pp. 1
Ring Opening of Epoxy Alcohols
pp. 1
Using Organozinc Reagents
pp. 1
Synthesis of ()- and ()-1-Phenylethanol Using Acyl-Transfer Processes
pp. 1
Transition-Metal-Catalyzed Hydrogenolysis of Cyclic Ethers
pp. 1
Using Silanes and Related Systems
pp. 1
Using α-Allyloxylated Carboxamides
pp. 1
Wittig Rearrangement
pp. 1
Synthesis from Alkylboranes
pp. 1
Resolution of -2-(1-Pyrazol-1-yl)cyclohexanol
pp. 1
Criegee Rearrangement of Bis(peroxosulfonates)
pp. 1
Using Platinum Lewis Acids
pp. 1
Synthesis of Product Subclass 9
pp. 1
Addition of Organolithium Compounds
pp. 1
Synthesis of Product Subclass 8
pp. 1
Synthesis of Primary Aliphatic Alkanols
pp. 1
[2+2] Cycloadditions of Allenes with Enol Ethers
pp. 1
Pentenyl Dianion Synthons for Ene-1,5-Diol Synthesis
pp. 1
Sharpless Asymmetric Epoxidation
pp. 1
Using α-Allyloxylated Ketones
pp. 1
Using Borohydride Reducing Agents and Related Systems
pp. 1
By Kinetic Resolution
pp. 1
Using Grignard Reagents
pp. 1
Hex-3-ene-1,6-diols by Reduction of Organozinc Intermediates
pp. 1
Resolution of 2-Aminopropan-1-ol
pp. 1
Oxidation with Fluorine
pp. 1
Cyclopropanation of Enol Ether Derivatives
pp. 1
Using a (Bicyclo[2.2.1]heptadiene)dichloropalladium(II)/(–)-Sparteine Complex
pp. 1
Using α-Allyloxylated Carboxylic Acids and Esters
pp. 1
C-Alkylation of Alcohols by Oxidation Followed by Addition
pp. 1
Synthesis of ()- and ()-Octan-2-ol
pp. 1
Chromium(II) Chloride Catalyzed Reductive Cyclization of α,β-Unsaturated Carbonyl Compounds with Aldehydes
pp. 1
Using a Chiral 2,3-Dihydroimidazo[1,2-]pyridine
pp. 1
Grignard Additions
pp. 1
Alkylation of the C=C Bond of Allylic Alcohols
pp. 1
Oxidation of Dimethyl(phenyl)silanes
pp. 1
Lewis Acid Mediated Silane Reduction of Cyclic Ethers
pp. 1
Intramolecular Radical Addition Reactions
pp. 1
Alcohols by Cleavage of Stannoxanes
pp. 1
Cleavage by Lewis Acids
pp. 1
Cleavage with Transition Metals
pp. 1
Cyclopropanation of Acid Chlorides
pp. 1
Of Cyclic Hydroxyalkenes by Osmium(VIII) Oxide
pp. 1
Enantioselective Additions of Grignard Reagents
pp. 1
With Allyl Groups Containing Stereocenters at C1
pp. 1
Direct Addition of Alkenyl- and Alkynyllithiums
pp. 1
Resolution of Pent-4-ene-2,3-diol
pp. 1
Using Dissolving Metals
pp. 1
Using Organotitanium Reagents
pp. 1
By Enantioselective Oxidation
pp. 1
Miscellaneous Strategies
pp. 1
Addition of Organolithium Reagents
pp. 1
Synthesis of Product Subclass 4
pp. 1
1,7-Diols
pp. 1
Lewis Acid Catalyzed Addition of Allylic Silane and Stannane Reagents
pp. 1
Palladium-Catalyzed Vinylic Arylation of Allylic Alcohols
pp. 1
Epoxide Ring Opening
pp. 1
In Ethers
pp. 1
Biocatalytic Reduction Methods
pp. 1
Resolution of Hexane-2,5-diol
pp. 1
Addition of Organomagnesium Compounds
pp. 1
Using (Tributylstannyl)methyl Ethers
pp. 1
Larger-Ring Cycloalkanols
pp. 1
Transition-Metal-Catalyzed Reduction: Hydrogenation and Transfer Hydrogenation
pp. 1
Reduction of Cyano Esters or Ketones
pp. 1
Stereoselective Reduction of Allylic Alcohols
pp. 1
Using Boranes and Related Compounds
pp. 1
Using Zirconium Reagents
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