0
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: not found

      Solid Suspension Flow Batteries Using Earth Abundant Materials.

      ACS Applied Materials & Interfaces
      American Chemical Society (ACS)
      energy storage, flow batteries, metals, charge transport, electrodes

      Read this article at

      ScienceOpenPublisherPubMed
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          The technical features of solid-electrode batteries (e.g., high energy density, relatively low capital cost ($/kWh)) and flow batteries (e.g., long cycle life, design flexibility) are highly complementary. It is therefore extremely desirable to integrate their advantages into a single storage device for large-scale energy storage applications where lifetime cost ($/kW-h/cycle) is an extremely important parameter. Here, we demonstrate a non-Li-based-flow battery concept that replaces the aqueous solution of redox-active molecules found in typical redox flow batteries with suspensions of hydrophilic carbon particles ("solid suspension electrodes") coated with earth-abundant redox-active metals. The solid suspension electrodes charge by depositing earth-abundant redox-active metals onto the carbon particle suspension, which are then stripped during discharge operation. The electrical contact to the solid suspension electrodes is fed through fixed redox-inert hydrophobic carbon current collectors through "contact charge transfer" mechanism. The hydrophobicity of the current collectors prevents direct plating of redox-active metals onto their surfaces. The above concept was successfully used to demonstrate several non-Li-based battery chemistries including zinc-copper, zinc-manganese oxide, zinc-bromine, and zinc-sulfur, providing a pathway for potential applications in medium and large-scale electrical energy storage.

          Related collections

          Author and article information

          Journal
          26727225
          10.1021/acsami.5b09515

          energy storage,flow batteries,metals,charge transport,electrodes

          Comments

          Comment on this article

          scite_