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      Optimisation of Bioethanol Production in a Potato Processing Industry

      , , , ,
      Fermentation
      MDPI AG

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          Abstract

          Nowadays, there is a requirement for industries to eliminate carbon from their energy mix and substitute it with greener options. This calls for investment in efforts to facilitate the scaling up of technical advancements. Because of the huge amount of waste, a life cycle strategy has been used by industries, especially the food industry, to lessen the environmental impact of their products. One of the sectors that burdens the environment with a significant amount of waste is the potato processing industrial sector. The current study focuses on the valorisation of all the potato processing waste streams (potato peels, potato tubers and slices, starch and low-quality chips) towards bioethanol production at a pilot level. After their physico-chemical characterisations, several experimental trials were performed in order to determine the optimum pretreatment and hydrolysis conditions for each waste stream. Acid hydrolysis, alkaline hydrolysis and hydrothermal pretreatment were examined when no pretreatment resulted in low ethanol yields (below 60%). The optimum results that were obtained were applied in a pilot plant of 200L to examine the upscaling factor. It was verified that upscaling by 1000 times generates comparable and, in some cases, greater results. From the integration of the results and the mass balances of a typical potato processing company, a full-scale implementation plan was also set up, where it was calculated that around 2 m3 bioethanol per week could be produced.

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          Use of Dinitrosalicylic Acid Reagent for Determination of Reducing Sugar

          G L Miller (1959)
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            A review on alkaline pretreatment technology for bioconversion of lignocellulosic biomass.

            The native form of lignocellulosic biomass is resistant to enzymatic breakdown. A well-designed pretreatment that can promote enzymatic hydrolysis of biomass with reasonable processing cost is therefore necessary. To this end, a number of different types of pretreatment technologies have been developed with a common goal of making biomass more susceptible to enzymatic saccharification. Among those, a pretreatment method using alkaline reagent has emerged as one of the most viable process options due primarily to its strong pretreatment effect and relatively simple process scheme. The main features of alkaline pretreatment are that it selectively removes lignin without degrading carbohydrates, and increases porosity and surface area, thereby enhancing enzymatic hydrolysis. In this review, the leading alkaline pretreatment technologies are described and their features and comparative performances are discussed from a process viewpoint. Attempts were also made to give insights into the chemical and physical changes of biomass brought about by pretreatment.
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              Optimization of hydrothermal pretreatment of lignocellulosic biomass in the bioethanol production process.

              The natural resistance to enzymatic deconstruction exhibited by lignocellulosic materials has designated pretreatment as a key step in the biological conversion of biomass to ethanol. Hydrothermal pretreatment in pure water represents a challenging approach because it is a method with low operational costs and does not involve the use of organic solvents, difficult to handle chemicals, and "external" liquid or solid catalysts. In the present work, a systematic study has been performed to optimize the hydrothermal treatment of lignocellulosic biomass (beech wood) with the aim of maximizing the enzymatic digestibility of cellulose in the treated solids and obtaining a liquid side product that could also be utilized for the production of ethanol or valuable chemicals. Hydrothermal treatment experiments were conducted in a batch-mode, high-pressure reactor under autogeneous pressure at varying temperature (130-220 °C) and time (15-180 min) regimes, and at a liquid-to-solid ratio (LSR) of 15. The intensification of the process was expressed by the severity factor, log R(o). The major changes induced in the solid biomass were the dissolution/removal of hemicellulose to the process liquid and the partial removal and relocation of lignin on the external surface of biomass particles in the form of recondensed droplets. The above structural changes led to a 2.5-fold increase in surface area and total pore volume of the pretreated biomass solids. The enzymatic hydrolysis of cellulose to glucose increased from less than 7 wt% for the parent biomass to as high as 70 wt% for the treated solids. Maximum xylan recovery (60 wt%) in the hydrothermal process liquid was observed at about 80 wt% hemicellulose removal; this was accomplished by moderate treatment severities (log R(o)=3.8-4.1). At higher severities (log R(o)=4.7), xylose degradation products, mainly furfural and formic acid, were the predominant chemicals formed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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                Author and article information

                Contributors
                (View ORCID Profile)
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                Journal
                FERMC4
                Fermentation
                Fermentation
                MDPI AG
                2311-5637
                February 2023
                January 23 2023
                : 9
                : 2
                : 103
                Article
                10.3390/fermentation9020103
                0312d015-7813-4e17-8d89-71f63ff1c30b
                © 2023

                https://creativecommons.org/licenses/by/4.0/

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