Engineering the Self-Assembly Induced Emission of Copper Nanoclusters as 3D Nanomaterials with Mesoporous Sphere Structures by the Crosslinking of Ce ³⁺

Abstract

Aggregation-induced emission has provided fluorescence enhancement strategies for metal nanoclusters. However, the morphology of the aggregated nanoclusters tended to be irregular due to the random aggregated route, which would result in the formation of an unstable product. Herein, copper nanoclusters were directly synthesized by using l-cysteine as both the reducing and protection ligand. Initially, the structure of the product was irregular. Furthermore, Ce ³⁺ was introduced to re-arrange the aggregates through a crosslinking avenue. It was interesting to find that well-ordered three-dimensional nanomaterials with mesoporous sphere structures were obtained after re-aggregation. On the basis of the stability test at a relatively high temperature and the light-emitting diode fabrication investigation, it revealed that the regulated product demonstrated more promising stability and color purity for practical applications than the random aggregated product with irregular structures.