Influence of Processing Conditions on the Thermal Stability and Mechanical Properties of PP/Silica-Lignin Composites

Abstract

Functional silica-lignin dual fillers were obtained via mechanical grinding of the components (Syloid 244 silica and kraft lignin). Of particular importance here is the fact that lignin is a natural polymer and particularly that it is a waste by-product of paper production, whose recycling is highly desirable. The product underwent comprehensive dispersive-morphological and thermal analysis. SiO ₂-lignin hybrid fillers were also used in polypropylene-based composites, extruded via corotating a twin screw machine with different screw speeds. The thermogravimetric data obtained for the extrudates confirmed that the application of the lignin into PP produces a significant char residue. Addition of silica to lignin via this new hybrid formulation has a positive effect on the thermal stability of PP/silica-lignin composites, which can be seen even when observing the temperature for the maximum rate of weight reduction. Tensile test results show that the addition of silica by means of dual filler incorporation improves the mechanical parameters in comparison with pure PP and PP/lignin composite.