Magnetization measurements of a truly axial symmetry molecular nanomagnet with a spin ground state of S = 10 show resonant tunneling. This compound has the same magnetic anisotropy as but the molecules are better isolated and the crystals have less disorder and a higher symmetry. Hysteresis loop measurements at several temperatures reveal a well-resolved step fine structure which is due to level crossings of excited states. All step positions can be modeled by a simple spin Hamiltonian. The results establish a sharp crossover between thermally assisted and pure quantum tunneling, as had been previously predicted.