In-situ Mg77Cu12Zn5Y6 bulk metallic glass matrix composite with extraordinary plasticity

Results are presented for a ductile metal reinforced bulk metallic glass matrix composite based on glass forming compositions in the Zr-Ti-Cu-Ni-Be system. Primary dendrite growth and solute partitioning in the molten state yields a microstructure consisting of a ductile crystalline Ti-Zr-Nb beta phase, with bcc structure, in a Zr-Ti-Nb-Cu-Ni-Be bulk metallic glass matrix. Under unconstrained mechanical loading organized shear band patterns develop throughout the sample. This results in a dramatic increase in the plastic strain to failure, impact resistance, and toughness of the metallic glass.

We report a brittle Mg-based bulk metallic glass which approaches the ideal brittle behavior. However, a dimple structure is observed at the fracture surface by high resolution scanning electron microscopy, indicating some type of "ductile" fracture mechanism in this very brittle glass. We also show, from the available data, a clear correlation between the fracture toughness and plastic process zone size for various glasses. The results indicate that the fracture in brittle metallic glassy materials might also proceed through the local softening mechanism but at different length scales.