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      Diverse glasses revealed from Chang’E-5 lunar regolith

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          ABSTRACT

          Lunar glasses with different origins act as snapshots of their formation processes, providing a rich archive of the Moon's formation and evolution. Here, we reveal diverse glasses from Chang’E-5 (CE-5) lunar regolith, and clarify their physical origins of liquid quenching, vapor deposition and irradiation damage respectively. The series of quenched glasses, including rotation-featured particles, vesicular agglutinates and adhered melts, record multiple-scale impact events. Abundant micro-impact products, like micron- to nano-scale glass droplets or craters, highlight that the regolith is heavily reworked by frequent micrometeorite bombardment. Distinct from Apollo samples, the indigenous ultra-elongated glass fibers drawn from viscous melts and the widespread ultra-thin deposited amorphous rims without nanophase iron particles both indicate a relatively gentle impact environment at the CE-5 landing site. The clarification of multitype CE-5 glasses also provides a catalogue of diverse lunar glasses, meaning that more of the Moon's mysteries, recorded in glasses, could be deciphered in future.

          Abstract

          There are diverse glassy materials transforming from liquid, vapor and solid in the Chang'E-5 lunar soils. Particularly, the discovery of ultra-elongated glass fibers and ultra-thin deposited amorphous rims reveals a gentle impact environment of the landing site.

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          Most cited references68

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          Space weathering from Mercury to the asteroid belt

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            Formation of glasses from liquids and biopolymers.

            C Angell (1995)
            Glasses can be formed by many routes. In some cases, distinct polyamorphic forms are found. The normal mode of glass formation is cooling of a viscous liquid. Liquid behavior during cooling is classified between "strong" and "fragile," and the three canonical characteristics of relaxing liquids are correlated through the fragility. Strong liquids become fragile liquids on compression. In some cases, such conversions occur during cooling by a weak first-order transition. This behavior can be related to the polymorphism in a glass state through a recent simple modification of the van der Waals model for tetrahedrally bonded liquids. The sudden loss of some liquid degrees of freedom through such first-order transitions is suggestive of the polyamorphic transition between native and denatured hydrated proteins, which can be interpreted as single-chain glass-forming polymers plasticized by water and cross-linked by hydrogen bonds. The onset of a sharp change in d dT( is the Debye-Waller factor and T is temperature) in proteins, which is controversially indentified with the glass transition in liquids, is shown to be general for glass formers and observable in computer simulations of strong and fragile ionic liquids, where it proves to be close to the experimental glass transition temperature. The latter may originate in strong anharmonicity in modes ("bosons"), which permits the system to access multiple minima of its configuration space. These modes, the Kauzmann temperature T(K), and the fragility of the liquid, may thus be connected.
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              Volatile content of lunar volcanic glasses and the presence of water in the Moon's interior.

              The Moon is generally thought to have formed and evolved through a single or a series of catastrophic heating events, during which most of the highly volatile elements were lost. Hydrogen, being the lightest element, is believed to have been completely lost during this period. Here we make use of considerable advances in secondary ion mass spectrometry to obtain improved limits on the indigenous volatile (CO(2), H(2)O, F, S and Cl) contents of the most primitive basalts in the Moon-the lunar volcanic glasses. Although the pre-eruptive water content of the lunar volcanic glasses cannot be precisely constrained, numerical modelling of diffusive degassing of the very-low-Ti glasses provides a best estimate of 745 p.p.m. water, with a minimum of 260 p.p.m. at the 95 per cent confidence level. Our results indicate that, contrary to prevailing ideas, the bulk Moon might not be entirely depleted in highly volatile elements, including water. Thus, the presence of water must be considered in models constraining the Moon's formation and its thermal and chemical evolution.
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                Author and article information

                Contributors
                Journal
                Natl Sci Rev
                Natl Sci Rev
                nsr
                National Science Review
                Oxford University Press
                2095-5138
                2053-714X
                December 2023
                21 March 2023
                21 March 2023
                : 10
                : 12
                : nwad079
                Affiliations
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences , Beijing 100049, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences , Beijing 100049, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences , Beijing 100049, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences , Beijing 100049, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology , Beijing 100094, China
                Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology , Beijing 100094, China
                Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology , Beijing 100094, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Songshan Lake Materials Laboratory , Dongguan 523808, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences , Beijing 100049, China
                Songshan Lake Materials Laboratory , Dongguan 523808, China
                Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology , Beijing 100094, China
                College of Engineering and Applied Sciences, Nanjing University , Nanjing 210093, China
                Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology , Beijing 100094, China
                China Academy of Space Technology , Beijing 100094, China
                Institute of Physics, Chinese Academy of Sciences , Beijing 100190, China
                Songshan Lake Materials Laboratory , Dongguan 523808, China
                Qian Xuesen Laboratory of Space Technology, China Academy of Space Technology , Beijing 100094, China
                Author notes
                Corresponding authors. E-mails: shenlaiquan@ 123456iphy.ac.cn
                Corresponding authors. E-mails: hybai@ 123456iphy.ac.cn

                Equally contributed to this work.

                Author information
                https://orcid.org/0000-0001-7882-5959
                https://orcid.org/0000-0001-7687-7624
                Article
                nwad079
                10.1093/nsr/nwad079
                10632798
                130f4ea4-55e0-4200-8035-46e17a9a8b98
                © The Author(s) 2023. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd.

                This is an Open Access article distributed under the terms of the Creative Commons Attribution License ( https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 02 November 2022
                : 13 February 2023
                : 23 February 2023
                : 10 October 2023
                Page count
                Pages: 14
                Funding
                Funded by: Chinese Academy of Sciences, DOI 10.13039/501100002367;
                Award ID: XDB30000000
                Funded by: National Natural Science Foundation of China, DOI 10.13039/501100001809;
                Award ID: 52001220
                Award ID: 52192600
                Award ID: 11790291
                Award ID: 61888102
                Funded by: Guangdong Major Project of Basic and Applied Basic Research;
                Award ID: 2019B030302010
                Categories
                Research Article
                Physics
                Nsr/6
                AcademicSubjects/MED00010
                AcademicSubjects/SCI00010

                lunar glasses,glass fibers,amorphous rims,micrometeorite impacts,gentle impact environment

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