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      Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo 3PdS 4}

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          Abstract

          Reaction of heterometallic cubane-type cluster complexes—[Mo 3{Pd(dba)}S 4Cl 3(dbbpy) 3]PF 6, [Mo 3{Pd(tu)}S 4Cl 3(dbbpy) 3]Cl and [Mo 3{Pd(dba)}S 4(acac) 3(py) 3]PF 6, where dba—dibenzylideneacetone, dbbpy—4,4′-di- tert-butyl-2,2′-bipyridine, tu—thiourea, acac—acetylacetonate, py—pyridine, with white phosphorus (P 4) in the presence of water leads to the formation of phosphorous acid H 3PO 3 as the major product. The crucial role of the Pd atom in the cluster core {Mo 3PdS 4} has been established in the hydrolytic activation of P 4 molecule. The main intermediate of the process, the cluster complex [Mo 3{PdP(OH) 3}S 4Cl 3(dbbpy) 3] + with coordinated P(OH) 3 molecule and phosphine PH 3, have been detected by 31P NMR spectroscopy in the reaction mixture.

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          Chemistry of dibenzylideneacetone-palladium(0) complexes

          J.J. Bonnet, James A. Ibers, Yoshio Ishii … (1974)
          Article 0 comments Cited 48 times – based on 0 reviews     Review now
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            Catalytic functions of cubane-type M4S4 clusters

            Hidetake Seino, Masanobu. Hidai (2011)
            Article 0 comments Cited 16 times – based on 0 reviews     Review now
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              Syntheses of sulphur-bridged molybdenum and tungsten coordination compounds

              Takashi Shibahara (1993)
              Article 0 comments Cited 15 times – based on 0 reviews     Review now
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                Author and article information

                Contributors
                Ana Lourenço: Role: Academic Editor
                Jorge Gominho: Role: Academic Editor
                Journal
                Journal ID (nlm-ta): Molecules
                Journal ID (iso-abbrev): Molecules
                Journal ID (publisher-id): molecules
                Title: Molecules
                Publisher: MDPI
                ISSN (Electronic): 1420-3049
                Publication date (Electronic): 21 January 2021
                Publication date Collection: February 2021
                Volume: 26
                Issue: 3
                Electronic Location Identifier: 538
                Affiliations
                [1 ]Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia; 95ka@ 123456bk.ru (A.M.K.); nikulek94@ 123456mail.ru (N.Y.S.); kuchkaev95@ 123456mail.ru (A.M.K.); alex.suhoff@ 123456rambler.ru (A.V.S.); babaev@ 123456iopc.ru (V.M.B.); oleg@ 123456iopc.ru (O.G.S.)
                [2 ]Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russia; khayarov.kh@ 123456gmail.com (K.R.K.)
                [3 ]Nikolaev Institute of Inorganic Chemistry SB RAS Lavrentiev av. 3, 630090 Novosibirsk, Russia; caesar@ 123456niic.nsc.ru (M.N.S.)
                [4 ]Department of Natural Sciences, Novosibirsk State University, Pirogov Str. 2, 630090 Novosibirsk, Russia
                Author notes
                [* ]Correspondence: gushchin@ 123456niic.nsc.ru (A.L.G.); yakhvar@ 123456iopc.ru (D.G.Y.); Tel.: +7-(843)-2732253 (D.G.Y.)
                Author information
                https://orcid.org/0000-0003-4845-2674
                https://orcid.org/0000-0002-3918-7031
                https://orcid.org/0000-0003-2913-5120
                https://orcid.org/0000-0003-3214-1433
                https://orcid.org/0000-0001-9361-4594
                https://orcid.org/0000-0002-3906-8841
                Article
                Publisher ID: molecules-26-00538
                DOI: 10.3390/molecules26030538
                PMC ID: 7864515
                PubMed ID: 33494201
                SO-VID: 17642bdd-3854-4bee-a44b-fe8402e5062a
                Copyright © © 2021 by the authors.
                License:

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                Date received : 28 December 2020
                Date accepted : 18 January 2021
                Categories
                Subject: Article

                Keywords: white phosphorus,heterometallic cubane-type clusters,molybdenum,palladium,phosphorous acid,phosphine
                Data availability:
                Keywords: white phosphorus, heterometallic cubane-type clusters, molybdenum, palladium, phosphorous acid, phosphine

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