We have recently performed a relativistic \(O(q^4)\) chiral expansion of the two-pion
exchange \(NN\) potential, and here we explore its configuration space content. Interactions
are determined by three families of diagrams, two of which involve just \(g_A\) and
\(f_{\pi}\), whereas the third one depends on empirical coefficients fixed by subthreshold
\(\pi N\) data. In this sense, the calculation has no adjusted parameters and gives
rise to predictions, which are tested against phenomenological potentials. The dynamical
structure of the eight leading non-relativistic components of the interaction is investigated
and, in most cases, found to be clearly dominated by a well defined class of diagrams.
In particular, the central isovector and spin-orbit, spin-spin, and tensor isoscalar
terms are almost completely fixed by just \(g_A\) and \(f_{\pi}\). The convergence of
the chiral series in powers of the ratio (pion mass/nucleon mass) is studied as a
function of the internucleon distance and, for \(r>\) 1 fm, found to be adequate for
most components of the potential. An important exception is the dominant central isoscalar
term, where the convergence is evident only for \(r>\) 2.5 fm. Finally, we compare the
spatial behavior of the functions that enter the relativistic and heavy baryon formulations
of the interaction and find that, in the region of physical interest, they differ
by about 5%.