Catalysis-tunable Heusler alloys in selective hydrogenation of alkynes: A new potential for old materials

Abstract

Heusler alloys are well known in other fields but little known in catalysis, where we demonstrate that they have great potential.

Abstract

Heusler alloys ( X ₂ YZ) are well-established intermetallic compound materials in various fields because their function can be precisely adjusted by elemental substitution (e.g., X ₂ YZ _{1− x} Z′ _x ). Although intermetallic compound catalysts started attracting attention recently, catalysis researchers are not familiar with Heusler alloys. We report their potential as novel catalysts focusing on the selective hydrogenation of alkynes. We found that Co ₂MnGe and Co ₂FeGe alloys have great alkene selectivity. Mutual substitution of Mn and Fe (Co ₂Mn _x Fe _{1− x} Ge) enhanced the reaction rate without changing selectivity. The substitution of Ga for Ge decreased the selectivity but increased the reaction rate monotonically with Ga composition. Elucidation of these mechanisms revealed that the fine tuning of catalytic properties is possible in Heusler alloys by separately using ligand and ensemble effects of elemental substitution.