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      Vibrations and Spatial Patterns Change Effective Wetting Properties of Superhydrophobic and Regular Membranes

      review-article
      , *
      Biomimetics
      MDPI
      vibrations, micro/nanotopography, wetting, membrane, oil-water separation

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          Abstract

          Small-amplitude fast vibrations and small surface micropatterns affect properties of various systems involving wetting, such as superhydrophobic surfaces and membranes. We review a mathematical method of averaging the effect of small spatial and temporal patterns. For small fast vibrations, this method is known as the method of separation of motions. The vibrations are substituted by effective force or energy terms, leading to vibration-induced phase control. A similar averaging method can be applied to surface micropatterns leading surface texture-induced phase control. We argue that the method provides a framework that allows studying such effects typical to biomimetic surfaces, such as superhydrophobicity, membrane penetration and others. Patterns and vibration can effectively jam holes and pores in vessels with liquid, separate multi-phase flow, change membrane properties, result in propulsion, and lead to many other multiscale, non-linear effects. Here, we discuss the potential application of these effects to novel superhydrophobic membranes.

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          Most cited references42

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          A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation.

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            Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature.

            Oil spills and industrial organic pollutants have induced severe water pollution and threatened every species in the ecological system. To deal with oily water, special wettability stimulated materials have been developed over the past decade to separate oil-and-water mixtures. Basically, synergy between the surface chemical composition and surface topography are commonly known as the key factors to realize the opposite wettability to oils and water and dominate the selective wetting or absorption of oils/water. In this review, we mainly focus on the development of materials with either super-lyophobicity or super-lyophilicity properties in oil/water separation applications where they can be classified into four kinds as follows (in terms of the surface wettability of water and oils): (i) superhydrophobic and superoleophilic materials, (ii) superhydrophilic and under water superoleophobic materials, (iii) superhydrophilic and superoleophobic materials, and (iv) smart oil/water separation materials with switchable wettability. These materials have already been applied to the separation of oil-and-water mixtures: from simple oil/water layered mixtures to oil/water emulsions (including oil-in-water emulsions and water-in-oil emulsions), and from non-intelligent materials to intelligent materials. Moreover, they also exhibit high absorption capacity or separation efficiency and selectivity, simple and fast separation/absorption ability, excellent recyclability, economical efficiency and outstanding durability under harsh conditions. Then, related theories are proposed to understand the physical mechanisms that occur during the oil/water separation process. Finally, some challenges and promising breakthroughs in this field are also discussed. It is expected that special wettability stimulated oil/water separation materials can achieve industrial scale production and be put into use for oil spills and industrial oily wastewater treatment in the near future.
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              A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water.

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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Biomimetics (Basel)
                Biomimetics (Basel)
                biomimetics
                Biomimetics
                MDPI
                2313-7673
                04 August 2016
                December 2016
                : 1
                : 1
                : 4
                Affiliations
                Mechanical Engineering Department, University of Wisconsin-Milwaukee, 3200 N Cramer St., Milwaukee, WI 53211, USA; ramacha6@ 123456uwm.edu
                Author notes
                [* ]Correspondence: nosonovs@ 123456uwm.edu ; Tel.: +1-414-229-2816
                [†]

                On a sabbatical leave at The Racah Institute of Physics, The Hebrew University, Jerusalem 91904, Israel.

                Article
                biomimetics-01-00004
                10.3390/biomimetics1010004
                6477627
                3cfd218c-b404-40ca-8a07-34645b2a6f1f
                © 2016 by the authors;

                licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 09 June 2016
                : 28 July 2016
                Categories
                Review

                vibrations,micro/nanotopography,wetting,membrane,oil-water separation

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