For Publishers
DiscoveryMetadataPeer reviewHostingPublishing
For Researchers
JoinPublishReviewCollect
Register
Blog
About
Search
Advanced search
My ScienceOpen
Search
For Publishers
For Researchers
Blog
About
14
views
72
references
 Top references
cited by
8
    
0 reviews
 Review
0
comments
 Comment
0
recommends
+1 Recommend
0 collections
    0
    shares
      7
      similar
       All similar
      • Record: found
      • Abstract: found
      • Article: found
      Is Open Access

      Gold(I)‐Catalyzed Synthesis of Indenes and Cyclopentadienes: Access to (±)‐Laurokamurene B and the Skeletons of the Cycloaurenones and Dysiherbols

      brief-report

      Read this article at

      ScienceOpenPublisherPMC
      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generated by a retro‐Buchner reaction of 7‐substituted 1,3,5‐cycloheptatrienes led to indenes and cyclopentadienes, respectively. These cycloaddition processes have been applied to the construction of the carbon skeleton of the cycloaurenones and the dysiherbols as well as to the total synthesis of (±)‐laurokamurene B.

          Related collections

          Most cited references72

          • Record: found
          • Abstract: found
          • Article: not found

          Indene-C(60) bisadduct: a new acceptor for high-performance polymer solar cells.

          Youjun He, Hsiang-Yu Chen, Jianhui Hou … (2010)
          Polymer solar cells (PSCs) are commonly composed of a blend film of a conjugated polymer donor and a soluble C(60) derivative acceptor sandwiched between an ITO anode and a low-workfunction metal cathode. Poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) are the most widely used donor and acceptor materials, respectively. However, the low LUMO energy level of PCBM limits the open circuit voltage (V(oc)) of the P3HT-based PSCs to ca. 0.6 V. Here we synthesized a new soluble C(60) derivative, indene-C(60) bisadduct (ICBA), with a LUMO energy level 0.17 eV higher than that of PCBM. The PSC based on P3HT with ICBA as acceptor shows a higher V(oc) of 0.84 V and higher power conversion efficiency (PCE) of 5.44% under the illumination of AM1.5, 100 mW/cm(2), while the PSC based on P3HT/PCBM displays a V(oc) of 0.58 V and PCE of 3.88% under the same experimental conditions. The results indicate that ICBA is an alternative high-performance acceptor and could be widely used in high-performance PSCs.
          Article 0 comments Cited 303 times – based on 0 reviews     Review now
            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            Fullerene derivative acceptors for high performance polymer solar cells.

            Youjun He, Yongfang Li (2011)
            Polymer solar cells (PSCs) are composed of a blend film of a conjugated polymer donor and a soluble fullerene derivative acceptor sandwiched between a PEDOT : PSS coated ITO positive electrode and a low workfunction metal negative electrode. The conjugated polymer donor and the fullerene derivative acceptor are the key photovoltaic materials for high performance PSCs. For the acceptors, although [6,6]-phenyl-C(61)-butyric acid methyl ester (PC(60)BM) and its corresponding C(70) derivative PC(70)BM are dominantly used as the acceptors in PSC at present, several series of new fullerene derivatives with higher-lying LUMO energy level and better solubility were reported in recent years for further improving the power conversion efficiency of the PSCs. In this perspective paper, we reviewed the recent research progress on the new fullerene derivative acceptors, including various PC(60)BM-like C(60) derivatives, PC(60)BM bisadduct, PC(70)BM bisadduct, indene-C(60) bisadduct and indene-C(70) bisadduct, trimetallic nitride endohedral fullerenes and other C(60) derivatives with multi side chains. The synthesis and physicochemical properties of PC(60)BM and PC(70)BM were also introduced considering the importance of the two fullerene acceptors.
            Article 0 comments Cited 238 times – based on 0 reviews     Review now
              Bookmark
              • Record: found
              • Abstract: found
              • Article: not found

              Chiral cyclopentadienyl ligands as stereocontrolling element in asymmetric C-H functionalization.

              Baihua Ye, Nicolai Cramer (2012)
              Metal complexes coordinated by a single cyclopentadienyl (Cp) ligand are widely used, versatile catalysts, but their application to asymmetric reactions has been hindered by the difficulty of designing Cp substituents that effectively bias the coordination sphere. Here, we report on a class of simple C(2)-symmetric Cp derivatives that finely control the spatial arrangement of the transiently coordinated reactants around the central metal atom. Rhodium(III) complexes bearing these ligands proved to be highly enantioselective catalysts for directed carbon-hydrogen (C-H) bond functionalizations of hydroxamic acid derivatives.
              Article 0 comments Cited 212 times – based on 0 reviews     Review now
                Bookmark
                All references

                Author and article information

                Contributors
                Prof. Antonio M. Echavarren:
                ORCID: http://orcid.org/0000-0001-6808-3007
                aechavarren@iciq.es
                Journal
                Journal ID (nlm-ta): Angew Chem Int Ed Engl
                Journal ID (iso-abbrev): Angew. Chem. Int. Ed. Engl
                Journal ID (doi): 10.1002/(ISSN)1521-3773
                Journal ID (publisher-id): ANIE
                Title: Angewandte Chemie (International Ed. in English)
                Publisher: John Wiley and Sons Inc. (Hoboken )
                ISSN (Print): 1433-7851
                ISSN (Electronic): 1521-3773
                Publication date (Electronic): 11 October 2017
                Publication date (Print): 13 November 2017
                Volume: 56
                Issue: 46 ( doiID: 10.1002/anie.v56.46 )
                Pages: 14591-14595
                Affiliations
                [ 1 ] Institute of Chemical Research of Catalonia (ICIQ) Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain
                [ 2 ] Departament de Química Analítica i Química Orgànica Universitat Rovira i Virgili C/ Marcel⋅li Domingo s/n 43007 Tarragona Spain
                Author information
                http://orcid.org/0000-0001-6808-3007
                Article
                Publisher ID: ANIE201708947
                DOI: 10.1002/anie.201708947
                PMC ID: 5698700
                PubMed ID: 28941059
                SO-VID: 3fda63ee-79a0-47e6-99a6-3614f3c9f148
                Copyright © © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
                License:

                This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.

                History
                Date received : 30 August 2017
                Page count
                Figures: 12, Tables: 4, References: 87, Pages: 5, Words: 0
                Funding
                Funded by: H2020 European Research Council
                Award ID: Advanced Grant No. 321066
                Funded by: MINECO/FEDER
                Award ID: CTQ2016-75960-P
                Funded by: Severo Ochoa Excellence Accreditation
                Award ID: SEV-2013-0319
                Categories
                Subject: Communication
                Subject: Communications
                Subject: Synthetic Methods
                Custom metadata
                source-schema-version-number 2.0
                component-id anie201708947
                cover-date November 13, 2017
                details-of-publishers-convertor Converter:WILEY_ML3GV2_TO_NLMPMC version:5.2.6 mode:remove_FC converted:22.11.2017

                ScienceOpen disciplines: Chemistry
                Keywords: cycloaddition,cyclopentadienes,gold catalysis,indenes,total synthesis
                Data availability:
                ScienceOpen disciplines: Chemistry
                Keywords: cycloaddition, cyclopentadienes, gold catalysis, indenes, total synthesis

                Comments

                Comment on this article

                scite_

                Similar content7

                See all similar

                Cited by7

                See all cited by

                Most referenced authors1,007

                See all reference authors