The dual observables as order parameters for center symmetry are tested at finite isospin chemical potential \(\mu_I\) in a Polyakov-loop enhanced chiral model of QCD with physical quark masses. As a counterpart of the dressed Polyakov-loop, the first Fourier moment of pion condensate is introduced for \(\mu_I>{m_\pi}/{2}\) under the temporal twisted boundary conditions for quarks. We demonstrate that this dual condensate exhibits the similar temperature dependence as the conventional Polyakov-loop. We confirm that its rapid increase with \(T\) is driven by the evaporating of pion condensation. On the other hand, the dressed Polyakov-loop shows abnormal thermal behavior, which even decreases with \(T\) at low temperatures due to the influence of pion condensate. We thus argue that in QCD the critical temperature extracting from a dual observable may have nothing to do with the quark confinement-deconfinement transition if the quark mass is very small.