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      Nematic order in iron superconductors - who is in the driver's seat?

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          Abstract

          Although the existence of nematic order in iron-based superconductors is now a well-established experimental fact, its origin remains controversial. Nematic order breaks the discrete lattice rotational symmetry by making the \(x\) and \(y\) directions in the Fe plane non-equivalent. This can happen because of (i) a tetragonal to orthorhombic structural transition, (ii) a spontaneous breaking of an orbital symmetry, or (iii) a spontaneous development of an Ising-type spin-nematic order - a magnetic state that breaks rotational symmetry but preserves time-reversal symmetry. The Landau theory of phase transitions dictates that the development of one of these orders should immediately induce the other two, making the origin of nematicity a physics realization of a "chicken and egg problem". The three scenarios are, however, quite different from a microscopic perspective. While in the structural scenario lattice vibrations (phonons) play the dominant role, in the other two scenarios electronic correlations are responsible for the nematic order. In this review, we argue that experimental and theoretical evidence strongly points to the electronic rather than phononic mechanism, placing the nematic order in the class of correlation-driven electronic instabilities, like superconductivity and density-wave transitions. We discuss different microscopic models for nematicity in the iron pnictides, and link nematicity to other ordered states of the global phase diagram of these materials -- magnetism and superconductivity. In the magnetic model nematic order pre-empts stripe-type magnetic order, and the same interaction which favors nematicity also gives rise to an unconventional \(s^{+-}\) superconductivity. In the charge/orbital model magnetism appears as a secondary effect of ferro-orbital order, and the interaction which favors nematicity gives rise to a conventional \(s^{++}\) superconductivity.

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          High-temperature superconductivity in iron-based materials

          The surprising discovery of superconductivity in layered iron-based materials, with transition temperatures climbing as high as 55 K, has lead to thousands of publications on this subject over the past two years. While there is general consensus on the unconventional nature of the Cooper pairing state of these systems, several central questions remain - including the role of magnetism, the nature of chemical and structural tuning, and the resultant pairing symmetry - and the search for universal properties and principles continues. Here we review the progress of research on iron-based superconducting materials, highlighting the major experimental benchmarks that have been so far reached and the important questions that remain to be conclusively answered.
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            Ising transition in frustrated Heisenberg models.

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              Nematic electronic structure in the "parent" state of the iron-based superconductor Ca(Fe(1-x)Co(x))2As2.

              The mechanism of high-temperature superconductivity in the newly discovered iron-based superconductors is unresolved. We use spectroscopic imaging-scanning tunneling microscopy to study the electronic structure of a representative compound CaFe1.94Co0.06As2 in the "parent" state from which this superconductivity emerges. Static, unidirectional electronic nanostructures of dimension eight times the inter-iron-atom distance a(Fe-Fe) and aligned along the crystal a axis are observed. In contrast, the delocalized electronic states detectable by quasiparticle interference imaging are dispersive along the b axis only and are consistent with a nematic alpha2 band with an apparent band folding having wave vector q vector congruent with +/-2pi/8a(Fe-Fe) along the a axis. All these effects rotate through 90 degrees at orthorhombic twin boundaries, indicating that they are bulk properties. As none of these phenomena are expected merely due to crystal symmetry, underdoped ferropnictides may exhibit a more complex electronic nematic state than originally expected.
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                Author and article information

                Journal
                20 December 2013
                Article
                10.1038/nphys2877
                1312.6085
                63a9569d-10f2-4285-a560-677fd3bf8049

                http://arxiv.org/licenses/nonexclusive-distrib/1.0/

                History
                Custom metadata
                Nature Phys. 10, 97 (2014)
                10-page review article; a revised version has been accepted for publication in Nature Physics
                cond-mat.str-el cond-mat.supr-con

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