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      The role of AlF3 coatings in improving electrochemical cycling of Li-enriched nickel-manganese oxide electrodes for Li-ion batteries.

      Advanced Materials (Deerfield Beach, Fla.)
      Aluminum Compounds, chemistry, Electric Power Supplies, Electrodes, Fluorides, Lithium, Manganese, Nickel, Oxides, Surface Properties

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          Abstract

          A Li[Li(0.19)Ni(0.16)Co(0.08)Mn(0.57)]O(2) cathode was coated with AlF(3) on the surface. The AlF(3)-coating enhanced the overall electrochemical characteristics of the electrode while overcoming the typical shortcomings of lithium-enriched cathodes. This improvement was attributed to the transformation of the initial electrode layer to a spinel phase, induced by the Li chemical leaching effect of the AlF(3) coating layer. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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          Author and article information

          Journal
          22362564
          10.1002/adma.201104106

          Chemistry
          Aluminum Compounds,chemistry,Electric Power Supplies,Electrodes,Fluorides,Lithium,Manganese,Nickel,Oxides,Surface Properties

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