1
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: not found

      Advances in Conjugated Microporous Polymers

      review-article

      ,

      Chemical Reviews

      American Chemical Society

      Read this article at

      ScienceOpenPublisherPMC
      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          Conjugated microporous polymers (CMPs) are a unique class of materials that combine extended π-conjugation with a permanently microporous skeleton. Since their discovery in 2007, CMPs have become established as an important subclass of porous materials. A wide range of synthetic building blocks and network-forming reactions offers an enormous variety of CMPs with different properties and structures. This has allowed CMPs to be developed for gas adsorption and separations, chemical adsorption and encapsulation, heterogeneous catalysis, photoredox catalysis, light emittance, sensing, energy storage, biological applications, and solar fuels production. Here we review the progress of CMP research since its beginnings and offer an outlook for where these materials might be headed in the future. We also compare the prospect for CMPs against the growing range of conjugated crystalline covalent organic frameworks (COFs).

          Related collections

          Most cited references 201

          • Record: found
          • Abstract: not found
          • Article: not found

          Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

            Bookmark
            • Record: found
            • Abstract: not found
            • Article: not found

            The pervasive chemistry of metal-organic frameworks.

              Bookmark
              • Record: found
              • Abstract: found
              • Article: not found

              Polymer-fullerene bulk-heterojunction solar cells.

              Solution-processed bulk heterojunction organic photovoltaic (OPV) devices have gained serious attention during the last few years and are established as one of the leading next generation photovoltaic technologies for low cost power production. This article reviews the OPV development highlights of the last two decades, and summarizes the key milestones that have brought the technology to today's efficiency performance of over 7%. An outlook is presented on what will be required to drive this young photovoltaic technology towards the next major milestone, a 10% power conversion efficiency, considered by many to represent the efficiency at which OPV can be adopted in wide-spread applications. With first products already entering the market, sufficient lifetime for the intended application becomes more and more critical, and the status of OPV stability as well as the current understanding of degradation mechanisms will be reviewed in the second part of this article.
                Bookmark

                Author and article information

                Journal
                Chem Rev
                Chem. Rev
                cr
                chreay
                Chemical Reviews
                American Chemical Society
                0009-2665
                1520-6890
                28 January 2020
                26 February 2020
                : 120
                : 4
                : 2171-2214
                Affiliations
                [1]Department of Chemistry and Materials Innovation Factory, University of Liverpool , 51 Oxford Street, Liverpool L7 3NY, United Kingdom
                Author notes
                Article
                10.1021/acs.chemrev.9b00399
                7145355
                31990527
                6d86d262-4a94-43a8-a52b-ef46676c03fe
                Copyright © 2020 American Chemical Society

                This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.

                Categories
                Review
                Custom metadata
                cr9b00399
                cr9b00399

                Chemistry

                Comments

                Comment on this article