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      A Brief Review of Nanocellulose Based Hybrid Membranes for CO2 Separation

      , , , ,
      Fibers
      MDPI AG

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          Abstract

          Due to the high specific surface area, high mechanical strength and broad possibility of surface modification, nanocellulose has obtained much attention as a new class of bio-based nanomaterials with promising potential in a wide variety of applications. Recently, a considerable amount of research has been aimed to the fabrication of nanocellulose based hybrid membranes for water treatment. However, nanocellulose based hybrid gas separation membrane is still a new research area. Herein, we force on recent advancements in the fabrication methods and separation performances of nanocellulose-based hybrid membranes for CO2 separation, the transport mechanisms involved, along with the challenges in the utilization of nanocellulose in membranes. Finally, some perspectives on future R&D of nanocellulose-based membranes for CO2 separation are proposed.

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          The upper bound revisited

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            Cellulose nanomaterials review: structure, properties and nanocomposites.

            This critical review provides a processing-structure-property perspective on recent advances in cellulose nanoparticles and composites produced from them. It summarizes cellulose nanoparticles in terms of particle morphology, crystal structure, and properties. Also described are the self-assembly and rheological properties of cellulose nanoparticle suspensions. The methodology of composite processing and resulting properties are fully covered, with an emphasis on neat and high fraction cellulose composites. Additionally, advances in predictive modeling from molecular dynamic simulations of crystalline cellulose to the continuum modeling of composites made with such particles are reviewed (392 references).
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              Cellulose: fascinating biopolymer and sustainable raw material.

              As the most important skeletal component in plants, the polysaccharide cellulose is an almost inexhaustible polymeric raw material with fascinating structure and properties. Formed by the repeated connection of D-glucose building blocks, the highly functionalized, linear stiff-chain homopolymer is characterized by its hydrophilicity, chirality, biodegradability, broad chemical modifying capacity, and its formation of versatile semicrystalline fiber morphologies. In view of the considerable increase in interdisciplinary cellulose research and product development over the past decade worldwide, this paper assembles the current knowledge in the structure and chemistry of cellulose, and in the development of innovative cellulose esters and ethers for coatings, films, membranes, building materials, drilling techniques, pharmaceuticals, and foodstuffs. New frontiers, including environmentally friendly cellulose fiber technologies, bacterial cellulose biomaterials, and in-vitro syntheses of cellulose are highlighted together with future aims, strategies, and perspectives of cellulose research and its applications.
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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                FIBECU
                Fibers
                Fibers
                MDPI AG
                2079-6439
                May 2019
                May 06 2019
                : 7
                : 5
                : 40
                Article
                10.3390/fib7050040
                731d43ef-7419-418c-9874-83d1e013b540
                © 2019

                https://creativecommons.org/licenses/by/4.0/

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