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Hydroacylation of α,β-unsaturated esters via aerobic C–H activation

Author(s): Vijay Chudasama , Richard J. Fitzmaurice , Stephen Caddick

Publication date Created: June 6 2010

Publication date (Print): June 6 2010

Journal: Nature Chemistry

Publisher: Springer Nature

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Carbon-heteroatom bond formation catalysed by organometallic complexes.

John Hartwig (2008)

At one time the synthetic chemist's last resort, reactions catalysed by transition metals are now the preferred method for synthesizing many types of organic molecule. A recent success in this type of catalysis is the discovery of reactions that form bonds between carbon and heteroatoms (such as nitrogen, oxygen, sulphur, silicon and boron) via complexes of transition metals with amides, alkoxides, thiolates, silyl groups or boryl groups. The development of these catalytic processes has been supported by the discovery of new elementary reactions that occur at metal-heteroatom bonds and by the identification of factors that control these reactions. Together, these findings have led to new synthetic processes that are in daily use and have formed a foundation for the development of processes that are likely to be central to synthetic chemistry in the future.

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Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

Robert Bergman, Bruce Arndtsen, Thomas H. Peterson … (2002)

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Chemistry of Acyl Radicals.

Chryssostomos Chatgilialoglu, David Crich, Mitsuo Komatsu … (1999)

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Author and article information

Journal

Title: Nature Chemistry

Abbreviated Title: Nature Chem

Publisher: Springer Nature

ISSN (Print): 1755-4330

ISSN (Electronic): 1755-4349

Publication date Created: June 6 2010

Publication date (Print): June 6 2010

Volume: 2

Issue: 7

Pages: 592-596

Article

DOI: 10.1038/nchem.685

SO-VID: 7eec24f1-e425-46f4-a719-a419233aa984

Copyright © © 2010

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