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      Poly[bis­(1 H-imidazole)(μ 3-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]

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          Abstract

          The title compound, [Cd(C 8H 8O 5)(C 3H 4N 2) 2] n , was synthesized by the reaction of 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The Cd II atom is seven-coordinated in a distorted penta­gonal-bipyramidal configuration by five O atoms from carboxyl­ate groups of three 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding and C—H⋯π inter­actions.

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          Author and article information

          Journal
          Acta Crystallogr Sect E Struct Rep Online
          Acta Cryst. E
          Acta Crystallographica Section E: Structure Reports Online
          International Union of Crystallography
          1600-5368
          01 July 2009
          17 June 2009
          17 June 2009
          : 65
          : Pt 7 ( publisher-idID: e090700 )
          : m782
          Affiliations
          [a ]Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People’s Republic of China, and, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People’s Republic of China
          Author notes
          Correspondence e-mail: sky51@ 123456zjnu.cn
          Article
          at2804 ACSEBH S1600536809021801
          10.1107/S1600536809021801
          2969310
          21582710
          7f75193f-ff12-41f6-bfc2-e949e293c6fb
          © Wang et al. 2009

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          : 31 May 2009
          : 09 June 2009
          Categories
          Metal-Organic Papers

          Materials characterization
          Materials characterization

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