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      Creating superhydrophobic mild steel surfaces for water proofing and oil–water separation

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          Abstract

          The fabricated superhydrophobic–superoleophilic mesh is bent into a V-shape-channel to guarantee floating oils are always in contact with the mesh.

          Abstract

          A simple and inexpensive two-step immersion method is reported to make mild steel superhydrophobic. Micro–nano-scale roughness and surface chemistry modifications were created via immersing mild steel into a salt solution followed by treatment with a low surface-energy polymer. The fabricated mild steel has water contact angles greater than 150° and remarkable water bouncing properties. This method was also used to treat a mild steel mesh for oil–water separation. In this paper, a new, facile and reusable gravity-induced separation system is proposed to collect floating oil, the oil collection rate can reach >96%.

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          Most cited references37

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          Biophysics: water-repellent legs of water striders.

          Water striders (Gerris remigis) have remarkable non-wetting legs that enable them to stand effortlessly and move quickly on water, a feature believed to be due to a surface-tension effect caused by secreted wax. We show here, however, that it is the special hierarchical structure of the legs, which are covered by large numbers of oriented tiny hairs (microsetae) with fine nanogrooves, that is more important in inducing this water resistance.
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            Liquid marbles.

            The transport of a small amount of liquid on a solid is not a simple process, owing to the nature of the contact between the two phases. Setting a liquid droplet in motion requires non-negligible forces (because the contact-angle hysteresis generates a force opposing the motion), and often results in the deposition of liquid behind the drop. Different methods of levitation-electrostatic, electromagnetic, acoustic, or even simpler aerodynamic techniques-have been proposed to avoid this wetting problem, but all have proved to be rather cumbersome. Here we propose a simple alternative, which consists of encapsulating an aqueous liquid droplet with a hydrophobic powder. The resulting 'liquid marbles' are found to behave like a soft solid, and show dramatically reduced adhesion to a solid surface. As a result, motion can be generated using gravitational, electrical and magnetic fields. Moreover, because the viscous friction associated with motion is very small, we can achieve quick displacements of the droplets without any leaks. All of these features are of potential benefit in microfluidic applications, and also permit the study of a drop in a non-wetting situation-an issue of renewed interest following the recent achievement of super-hydrophobic substrates.
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              On-demand separation of oil-water mixtures.

              In this work, the first-ever membrane-based single unit operation that enables gravity driven, on-demand separation of various oil-water mixtures is developed. Using this methodology, the on-demand separation of free oil and water, oil-in-water emulsions, and water-in-oil emulsions is demonstrated, with ≥99.9% separation efficiency. A scaled-up apparatus to separate larger quantities (several liters) of oil-water emulsions is also developed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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                Author and article information

                Journal
                JMCAET
                J. Mater. Chem. A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                2014
                2014
                : 2
                : 30
                : 11628-11634
                Article
                10.1039/C4TA02181A
                8070e231-8851-4cc6-97e5-c2945fba8a02
                © 2014
                History

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