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      Noble Metals in Polyoxometalates

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      Angewandte Chemie International Edition
      Wiley-Blackwell

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          Heteropoly and Isopoly Oxometalates

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            Catalytic oxidation of water by an oxo-bridged ruthenium dimer

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              Efficient water oxidation at carbon nanotube-polyoxometalate electrocatalytic interfaces.

              Water is the renewable, bulk chemical that nature uses to enable carbohydrate production from carbon dioxide. The dream goal of energy research is to transpose this incredibly efficient process and make an artificial device whereby the catalytic splitting of water is finalized to give a continuous production of oxygen and hydrogen. Success in this task would guarantee the generation of hydrogen as a carbon-free fuel to satisfy our energy demands at no environmental cost. Here we show that very efficient and stable nanostructured, oxygen-evolving anodes are obtained by the assembly of an oxygen-evolving polyoxometalate cluster (a totally inorganic ruthenium catalyst) with a conducting bed of multiwalled carbon nanotubes. Our bioinspired electrode addresses the one major challenge of artificial photosynthesis, namely efficient water oxidation, which brings us closer to being able to power the planet with carbon-free fuels.
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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley-Blackwell
                14337851
                September 17 2012
                September 17 2012
                : 51
                : 38
                : 9492-9510
                Article
                10.1002/anie.201202750
                22907913
                a4e86fef-5bab-4c04-a561-6c09f9431b5a
                © 2012

                http://doi.wiley.com/10.1002/tdm_license_1.1

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