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      Recent advances in chemical recycling of polyethylene terephthalate waste into value added products for sustainable coating solutions – hope vs. hype

      1 , 1
      Materials Advances
      Royal Society of Chemistry (RSC)

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          Abstract

          In this article, we have reviewed how polyethylene terephthalate can be recycled into value-added products so that it can be used as a raw material for coating applications.

          Abstract

          In the current era of globalization, plastics are an indispensable part of our daily life; from our morning toothbrush to night dinner table, plastics are everywhere in our daily life. In such a polymer governing era, the problems related to their pollution are inevitable as most of the commercially used synthetic plastics are non-biodegradable in nature. Among these non-biodegradable polymers, polyethylene terephthalate (PET) constitutes a significant percentage due to its widespread application in the packaging, food and beverage, and automotive industries. This ever-increasing application of PET generates a large volume of post-consumer waste materials which have to be dumped in most of the cases after a certain time. However, with growing environmental awareness, the recycling of polymeric waste materials into valuable ones has become one of the hot topics in mainstream research. There are already a few research articles where researchers have demonstrated that these polymeric waste material derived products can be used further to synthesize new polymeric materials which have applications in various sectors (such as in the fields of regenerative medicine and organic coatings). From this point of view, here we have summarized the recent progress in recycling of PET waste into value-added products and their subsequent utilization in the field of organic coatings. In addition to that we have reviewed, all the major research studies carried out in chemical recycling of PET waste across the globe which can be later used in the coating industry. The review also highlights the existing challenges in this field involved with upscaling of these processes in industry. Additionally, we have predicted future directions on how these recycled products can be used in a sustainable and economically feasible way, so that this can reduce the carbon footprint significantly and help in achieving a closed-loop circular economy.

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          Production, use, and fate of all plastics ever made

          We present the first ever global account of the production, use, and end-of-life fate of all plastics ever made by humankind.
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            A bacterium that degrades and assimilates poly(ethylene terephthalate).

            Poly(ethylene terephthalate) (PET) is used extensively worldwide in plastic products, and its accumulation in the environment has become a global concern. Because the ability to enzymatically degrade PET has been thought to be limited to a few fungal species, biodegradation is not yet a viable remediation or recycling strategy. By screening natural microbial communities exposed to PET in the environment, we isolated a novel bacterium, Ideonella sakaiensis 201-F6, that is able to use PET as its major energy and carbon source. When grown on PET, this strain produces two enzymes capable of hydrolyzing PET and the reaction intermediate, mono(2-hydroxyethyl) terephthalic acid. Both enzymes are required to enzymatically convert PET efficiently into its two environmentally benign monomers, terephthalic acid and ethylene glycol.
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              Plastics recycling: challenges and opportunities.

              Plastics are inexpensive, lightweight and durable materials, which can readily be moulded into a variety of products that find use in a wide range of applications. As a consequence, the production of plastics has increased markedly over the last 60 years. However, current levels of their usage and disposal generate several environmental problems. Around 4 per cent of world oil and gas production, a non-renewable resource, is used as feedstock for plastics and a further 3-4% is expended to provide energy for their manufacture. A major portion of plastic produced each year is used to make disposable items of packaging or other short-lived products that are discarded within a year of manufacture. These two observations alone indicate that our current use of plastics is not sustainable. In addition, because of the durability of the polymers involved, substantial quantities of discarded end-of-life plastics are accumulating as debris in landfills and in natural habitats worldwide. Recycling is one of the most important actions currently available to reduce these impacts and represents one of the most dynamic areas in the plastics industry today. Recycling provides opportunities to reduce oil usage, carbon dioxide emissions and the quantities of waste requiring disposal. Here, we briefly set recycling into context against other waste-reduction strategies, namely reduction in material use through downgauging or product reuse, the use of alternative biodegradable materials and energy recovery as fuel. While plastics have been recycled since the 1970s, the quantities that are recycled vary geographically, according to plastic type and application. Recycling of packaging materials has seen rapid expansion over the last decades in a number of countries. Advances in technologies and systems for the collection, sorting and reprocessing of recyclable plastics are creating new opportunities for recycling, and with the combined actions of the public, industry and governments it may be possible to divert the majority of plastic waste from landfills to recycling over the next decades.
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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                MAADC9
                Materials Advances
                Mater. Adv.
                Royal Society of Chemistry (RSC)
                2633-5409
                February 21 2022
                2022
                : 3
                : 4
                : 1974-1992
                Affiliations
                [1 ]Research & Development Laboratory, Shalimar Paints Limited, Nashik, Maharashtra, 422403, India
                Article
                10.1039/D1MA01112J
                a6e5008b-6d4a-471b-a976-c36ccecc46b9
                © 2022

                http://creativecommons.org/licenses/by/3.0/

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