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      Reassigning CI chondrite parent bodies based on reflectance spectroscopy of samples from carbonaceous asteroid Ryugu and meteorites

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      1 , * , , 2 , 1 , 1 , 1 , 3 , 4 , 5 , 4 , 6 , 6 , 7 , 8 , 9 , 10 , 9 , 11 , 12 , 1 , 1 , 1 , 13 , 14 , 15 , 16 , 15 , 15 , 1 , 1 , 17 , 18 , 19 , 20 , 19 , 5 , 9 , 5 , 5 , 5 , 5 , 5 , 5 , 5 , 5 , 5 , 5 , 5 , 21 , 5 , 22 , 5
      Science Advances
      American Association for the Advancement of Science

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          Abstract

          The carbonaceous asteroid Ryugu has been explored by the Hayabusa2 spacecraft to elucidate the actual nature of hydrous asteroids. Laboratory analyses revealed that the samples from Ryugu are comparable to unheated CI carbonaceous chondrites; however, reflectance spectra of Ryugu samples and CIs do not coincide. Here, we demonstrate that Ryugu sample spectra are reproduced by heating Orgueil CI chondrite at 300°C under reducing conditions, which caused dehydration of terrestrial weathering products and reduction of iron in phyllosilicates. Terrestrial weathering of CIs accounts for the spectral differences between Ryugu sample and CIs, which is more severe than space weathering that likely explains those between asteroid Ryugu and the collected samples. Previous assignments of CI chondrite parent bodies, i.e., chemically most primitive objects in the solar system, are based on the spectra of CI chondrites. This study indicates that actual spectra of CI parent bodies are much darker and flatter at ultraviolet to visible wavelengths than the spectra of CI chondrites.

          Abstract

          The samples from the carbonaceous asteroid Ryugu demonstrate actual reflectance spectra of parent bodies of primitive meteorites.

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          Mineralogy and composition of matrix and chondrule rims in carbonaceous chondrites

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            Hayabusa2 arrives at the carbonaceous asteroid 162173 Ryugu—A spinning top–shaped rubble pile

            The Hayabusa2 spacecraft arrived at the near-Earth carbonaceous asteroid 162173 Ryugu in 2018. We present Hayabusa2 observations of Ryugu’s shape, mass, and geomorphology. Ryugu has an oblate ‘spinning top’ shape with a prominent circular equatorial ridge. Its bulk density, 1.19 ± 0.02 g cm–3, indicates a high porosity (>50%) interior. Large surface boulders suggest a rubble-pile structure. Surface slope analysis shows Ryugu’s shape may have been produced if it once spun at twice the current rate. Coupled with the observed global material homogeneity, this suggests that Ryugu was reshaped by centrifugally induced deformation during a period of rapid rotation. From these remote-sensing investigations, we identify a suitable sample collection site on the equatorial ridge.
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              Ammoniated phyllosilicates with a likely outer Solar System origin on (1) Ceres

              Studies of the dwarf planet (1) Ceres using ground-based and orbiting telescopes have concluded that its closest meteoritic analogues are the volatile-rich CI and CM carbonaceous chondrites. Water in clay minerals, ammoniated phyllosilicates, or a mixture of Mg(OH)2 (brucite), Mg2CO3 and iron-rich serpentine have all been proposed to exist on the surface. In particular, brucite has been suggested from analysis of the mid-infrared spectrum of Ceres. But the lack of spectral data across telluric absorption bands in the wavelength region 2.5 to 2.9 micrometres--where the OH stretching vibration and the H2O bending overtone are found--has precluded definitive identifications. In addition, water vapour around Ceres has recently been reported, possibly originating from localized sources. Here we report spectra of Ceres from 0.4 to 5 micrometres acquired at distances from ~82,000 to 4,300 kilometres from the surface. Our measurements indicate widespread ammoniated phyllosilicates across the surface, but no detectable water ice. Ammonia, accreted either as organic matter or as ice, may have reacted with phyllosilicates on Ceres during differentiation. This suggests that material from the outer Solar System was incorporated into Ceres, either during its formation at great heliocentric distance or by incorporation of material transported into the main asteroid belt.
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                Author and article information

                Contributors
                Role: ConceptualizationRole: Data curationRole: Formal analysisRole: Funding acquisitionRole: InvestigationRole: MethodologyRole: Project administrationRole: ResourcesRole: SoftwareRole: SupervisionRole: ValidationRole: VisualizationRole: Writing - original draftRole: Writing - review & editing
                Role: InvestigationRole: MethodologyRole: Project administrationRole: Writing - original draftRole: Writing - review & editing
                Role: ConceptualizationRole: Funding acquisitionRole: InvestigationRole: MethodologyRole: Project administrationRole: SupervisionRole: Validation
                Role: Investigation
                Role: Investigation
                Role: Data curationRole: Formal analysisRole: MethodologyRole: ResourcesRole: SoftwareRole: VisualizationRole: Writing - review & editing
                Role: InvestigationRole: SupervisionRole: Validation
                Role: ConceptualizationRole: Writing - original draftRole: Writing - review & editing
                Role: ConceptualizationRole: Writing - review & editing
                Role: ConceptualizationRole: InvestigationRole: Writing - original draft
                Role: Writing - review & editing
                Role: InvestigationRole: ValidationRole: Writing - review & editing
                Role: Formal analysisRole: MethodologyRole: Software
                Role: InvestigationRole: Methodology
                Role: Investigation
                Role: MethodologyRole: Resources
                Role: Methodology
                Role: InvestigationRole: MethodologyRole: Writing - review & editing
                Role: InvestigationRole: Validation
                Role: ResourcesRole: ValidationRole: Writing - review & editing
                Role: ConceptualizationRole: MethodologyRole: ValidationRole: Writing - original draftRole: Writing - review & editing
                Role: Formal analysisRole: SupervisionRole: Validation
                Role: Validation
                Role: ConceptualizationRole: MethodologyRole: ValidationRole: Writing - review & editing
                Role: ConceptualizationRole: MethodologyRole: Validation
                Role: InvestigationRole: Resources
                Role: InvestigationRole: MethodologyRole: Project administrationRole: ResourcesRole: Writing - review & editing
                Role: ValidationRole: Writing - review & editing
                Role: Writing - review & editing
                Role: Writing - review & editing
                Role: Project administration
                Role: ConceptualizationRole: Resources
                Role: Project administration
                Role: Funding acquisitionRole: Project administrationRole: Supervision
                Role: Resources
                Role: Resources
                Role: Resources
                Role: Resources
                Role: Resources
                Role: Resources
                Role: Project administration
                Role: Project administration
                Role: InvestigationRole: Resources
                Role: Resources
                Role: Investigation
                Role: Funding acquisitionRole: Project administration
                Role: Project administrationRole: Supervision
                Role: ConceptualizationRole: Data curationRole: InvestigationRole: Project administrationRole: Supervision
                Journal
                Sci Adv
                Sci Adv
                sciadv
                advances
                Science Advances
                American Association for the Advancement of Science
                2375-2548
                08 December 2023
                06 December 2023
                : 9
                : 49
                : eadi3789
                Affiliations
                [ 1 ]Department of Earth Science, Tohoku University, Sendai 980-8578, Japan.
                [ 2 ]Geological Survey of Japan, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8567, Japan.
                [ 3 ]Faculty of Aerospace Engineering, Delft University of Technology, 2629 HS Delft, Netherlands.
                [ 4 ]Department of Earth, Environmental, and Planetary Sciences, Brown University, Providence, RI 02912, USA.
                [ 5 ]Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara 252-5210, Japan.
                [ 6 ]Institut de Planétologie et d’Astrophysique de Grenoble (IPAG), CNRS, Université Grenoble Alpes, Grenoble 38000, France.
                [ 7 ]Institut d’Astrophysique Spatiale, Université Paris-Saclay, CNRS, Orsay 91405, France.
                [ 8 ]Scattering and Imaging Division, Japan Synchrotron Radiation Research Institute, Sayo 679-5198, Japan.
                [ 9 ]Department of Earth and Planetary Science, The University of Tokyo, Tokyo 113-0033, Japan.
                [ 10 ]Isotope Science Center, The University of Tokyo, Tokyo 113-0032, Japan.
                [ 11 ]Department of Materials Structure Science, The Graduate University for Advanced Studies (SOKENDAI), Tsukuba 305-0801, Japan.
                [ 12 ]Institute of Materials Structure Science, High-Energy Accelerator Research Organization, Tsukuba 305-0801, Japan.
                [ 13 ]NASA Johnson Space Center, Houston, TX 77058, USA.
                [ 14 ]Jacobs, NASA Johnson Space Center, Houston, TX 77058, USA.
                [ 15 ]Planetary Science Institute, Tucson, AZ 85179, USA.
                [ 16 ]The Pennsylvania State University, University Park, PA 16802, USA.
                [ 17 ]Department of Earth and Planetary Sciences, Hokkaido University, Sapporo 060-0810, Japan.
                [ 18 ]Division of Earth and Planetary Sciences, Kyoto University, Kyoto 606-8502, Japan.
                [ 19 ]Department of Earth and Planetary Sciences, Kyushu University, Fukuoka 819-0395, Japan.
                [ 20 ]Department of Earth and Planetary Systems Science, Hiroshima University, Higashi-Hiroshima 739-8526, Japan.
                [ 21 ]Department of Mechanical Engineering, Kanagawa Institute of Technology, Atsugi 243-0292, Japan.
                [ 22 ]Department of Earth and Environmental Sciences, Nagoya University, Nagoya 464-8601, Japan.
                Author notes
                [* ]Corresponding author. Email: amakana@ 123456dc.tohoku.ac.jp
                Author information
                https://orcid.org/0000-0003-4466-4426
                https://orcid.org/0000-0003-1091-3041
                https://orcid.org/0000-0001-9525-4086
                https://orcid.org/0009-0009-1719-6058
                https://orcid.org/0000-0001-6907-3409
                https://orcid.org/0000-0003-2866-9091
                https://orcid.org/0000-0002-6142-9842
                https://orcid.org/0000-0003-3240-4918
                https://orcid.org/0000-0003-2768-0694
                https://orcid.org/0000-0002-6532-5602
                https://orcid.org/0000-0003-3001-9362
                https://orcid.org/0000-0001-6261-9034
                https://orcid.org/0000-0001-7860-2341
                https://orcid.org/0009-0002-7086-1896
                https://orcid.org/0000-0002-3274-6689
                https://orcid.org/0009-0001-1570-9499
                https://orcid.org/0000-0001-7241-530X
                https://orcid.org/0000-0002-3181-1303
                https://orcid.org/0000-0003-4942-2741
                https://orcid.org/0000-0002-7594-4634
                https://orcid.org/0000-0003-1181-1733
                https://orcid.org/0000-0003-4723-5870
                https://orcid.org/0000-0002-0435-8224
                https://orcid.org/0009-0002-2769-3567
                https://orcid.org/0000-0003-0702-0533
                https://orcid.org/0000-0001-7211-2595
                https://orcid.org/0000-0003-0177-7527
                https://orcid.org/0000-0002-4625-5362
                https://orcid.org/0000-0002-2373-8759
                https://orcid.org/0000-0001-5138-5324
                https://orcid.org/0000-0002-4603-9440
                https://orcid.org/0000-0002-7971-510X
                https://orcid.org/0000-0003-3143-8171
                https://orcid.org/0000-0003-2392-1497
                https://orcid.org/0000-0001-7427-2285
                https://orcid.org/0000-0002-3717-9185
                https://orcid.org/0000-0003-4780-800X
                https://orcid.org/0000-0001-6381-8107
                https://orcid.org/0000-0002-4653-293X
                https://orcid.org/0000-0002-3118-7475
                https://orcid.org/0000-0003-3100-420X
                https://orcid.org/0000-0002-4874-0417
                https://orcid.org/0000-0001-6422-0983
                https://orcid.org/0000-0003-4250-1826
                https://orcid.org/0000-0002-5820-2102
                https://orcid.org/0000-0002-9161-6171
                Article
                adi3789
                10.1126/sciadv.adi3789
                10699774
                38055820
                af1cb77f-6033-45aa-b2f9-cecf0eceb458
                Copyright © 2023 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution License 4.0 (CC BY).

                This is an open-access article distributed under the terms of the Creative Commons Attribution license, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                : 21 April 2023
                : 03 November 2023
                Funding
                Funded by: FundRef http://dx.doi.org/10.13039/100020994, Centre national d’études spatiales;
                Award ID: CNES-France, Hayabusa2 mission
                Funded by: FundRef http://dx.doi.org/10.13039/501100001691, Japan Society for the Promotion of Science;
                Award ID: JP21J13337
                Funded by: FundRef http://dx.doi.org/10.13039/501100001691, Japan Society for the Promotion of Science;
                Award ID: JP20H00188
                Funded by: FundRef http://dx.doi.org/10.13039/501100006004, Tohoku University;
                Award ID: GP-EES Research Grant
                Categories
                Research Article
                Earth, Environmental, Ecological, and Space Sciences
                SciAdv r-articles
                Geochemistry
                Planetary Science
                Planetary Science
                Custom metadata
                Lou Notario

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