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      1′,6-Dimethyl-4′-phenyl­dispiro­[1-benzopyran-3(4 H),3′-pyrrolidine-2′,3′′-indoline]-2,2′′-dione

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          Abstract

          In the title compound, C 27H 24N 2O 3, the five-membered pyrroldine ring adopts an envelope conformation (with the N atom in the flap position) and the six-membered pyran­one ring of the coumarine ring system adopts a slightly distorted boat conformation. The oxindole unit makes dihedral angles of 89.7 (1) and 25.6 (1)°, respectively, with the pyrrolidine ring and the coumarin ring system. The mol­ecular structure is stabilized by two intra­molecular C—H⋯O contacts and two intra­molecular π–π inter­actions [centroid–centroid seperations of 3.514 (1) and 3.623 (1) Å]. The crystal packing features N—H⋯O hydrogen bonds, which link the mol­ecules into cyclic centrosymmetric R 2 2(8) dimers, and C—H⋯π inter­actions.

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          Author and article information

          Journal
          Acta Crystallogr Sect E Struct Rep Online
          Acta Cryst. E
          Acta Crystallographica Section E: Structure Reports Online
          International Union of Crystallography
          1600-5368
          01 December 2011
          30 November 2011
          30 November 2011
          : 67
          : Pt 12 ( publisher-idID: e111200 )
          : o3516-o3517
          Affiliations
          [a ]Department of Physics, C. Abdul Hakeem College of Engineering & Technology, Melvisharam, Vellore 632 509, India
          [b ]Department of Physics, Thanthai Periyar Government Institute of Technology, Vellore 632 002, India
          [c ]Department of Organic Chemistry, University of Madras, Maraimalai Campus, Chennai 600 025, India
          Author notes
          Correspondence e-mail: smurugavel27@ 123456gmail.com
          [‡]

          Additional correspondence author, e-mail: bhakthadoss@yahoo.com.

          Article
          bt5722 ACSEBH S1600536811050768
          10.1107/S1600536811050768
          3239137
          22199985
          b01cf03b-d39c-4c1f-88b6-c0cb60264720
          © Lakshmanan' et al. 2011

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          : 21 November 2011
          : 25 November 2011
          Categories
          Organic Papers

          Materials characterization
          Materials characterization

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