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      Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions

      research-article
      1 , 1 , 2 , 1 , , 3 ,
      Royal Society Open Science
      The Royal Society
      reliability, interface health, cerium, green inhibitor, pH, high-voltage insulator

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          Abstract

          Pin corrosion is a critical issue that causes premature rupture of high-voltage insulators. The development of efficient, defect-free, thermal resistive, hard, economical and environment-friendly sealing coating system is required to replace the current polymer-based highly toxic coatings for insulators. This study investigates the suitability of noble cerium (Ce)-based sealing coating film for use as an anti-corrosion coating for insulator pins installed in low-pH and highly corrosive sites. The coating bath parameters are optimized for the formation of a high-performance Ce-based protective sealing coating. After immersion in a 60 000 ppm CeCl 3.7H 2O sealing coating bath for 60 min, a Ce-rich and dense protective coating (24 µm) is formed on the pin surface. The life expectancy of the coated pin is 2.5 times higher than that of the non-coated galvanized pins. Electrochemical experiments and microstructural analysis demonstrate that Ce-based protective layers are suitable for long-term protection of high-voltage insulator pins in low-pH and high-corrosion-rate sites. We believe that this work would pave the way of developing ecofriendly anti-corrosion coatings for electric insulators and power industries.

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          Most cited references30

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          Corrosion protection mechanism of Ce 4+ /organic inhibitor for AA2024 in 3.5% NaCl

          Cerium is a rare earth element that has been widely proposed for the corrosion protection of aluminium alloys (AA). Both cerium salts, Ce3+ and Ce4+, have been used in combination with other compounds to offer synergistic inhibition, however, the inhibitive corrosion mechanism when using Ce4+ with organic compounds is still not clear. In this study, the synergistic inhibition effect of Ce4+ and melamine (M) on the corrosion of aluminium alloy 2024 (AA2024) in 3.5% NaCl solution was investigated. Potentiodynamic Polarization (PDP) and Electrochemical Impedance Spectroscopy (EIS) techniques were used to study the synergistic effect of different Ce4+/M ratios on the corrosion behaviour of AA2024. The PDP study showed that a combination of 50% Ce4+ and 50% M leads to the lowest corrosion rates, both acting as cathodic inhibitors. Both PDP and EIS results indicated that M or Ce4+ in isolation did not offer effective corrosion protection, while the combination of M and Ce4+ significantly enhances the corrosion protection with a synergism parameter equal to 3.5. SEM and EDX observations confirm the findings from the electrochemical techniques. XPS was used to investigate the mechanism of protection, revealing that the reduction of Ce4+ to Ce3+ occurs during protection of AA2024. A new mechanism of corrosion synergistic inhibition by Ce4+ and organic compounds is postulated where the role of the organic compounds is to enhance the reduction of Ce4+.
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            Effects of polyethylene glycol (PEG) on the corrosion inhibition of mild steel by cerium nitrate in chloride solution

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              • Abstract: not found
              • Article: not found

              Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts

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                Author and article information

                Contributors
                Role: Formal analysisRole: InvestigationRole: MethodologyRole: Writing – original draft
                Role: ConceptualizationRole: Formal analysis
                Role: ResourcesRole: Visualization
                Role: SupervisionRole: Writing – review & editing
                Role: Funding acquisitionRole: Project administrationRole: Supervision
                Journal
                R Soc Open Sci
                R Soc Open Sci
                RSOS
                royopensci
                Royal Society Open Science
                The Royal Society
                2054-5703
                April 6, 2022
                April 2022
                April 6, 2022
                : 9
                : 4
                : 211786
                Affiliations
                [ 1 ] Department of Electrical and Computer Engineering, Sungkyunkwan University, , Suwon 16419, Republic of Korea
                [ 2 ] Interdisciplinary Program in Photovoltaic System Engineering, Sungkyunkwan University, , Suwon 16419, Republic of Korea
                [ 3 ] College of Information and Communication Engineering, Sungkyunkwan University, , Suwon 16419, Republic of Korea
                Author notes

                This article has been edited by the Royal Society of Chemistry, including the commissioning, peer review process and editorial aspects up to the point of acceptance.

                Electronic supplementary material is available online at https://doi.org/10.6084/m9.figshare.c.5921798.

                Author information
                http://orcid.org/0000-0002-6196-0035
                Article
                rsos211786
                10.1098/rsos.211786
                8984353
                35425624
                b2675976-ed3b-4c6a-8de9-70362e76de61
                © 2022 The Authors.

                Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.

                History
                : November 18, 2021
                : March 15, 2022
                Funding
                Funded by: Korea Electric Power Corporation, http://dx.doi.org/10.13039/501100010193;
                Award ID: R20XO03-08
                Categories
                1006
                1002
                38
                154
                84
                Chemistry
                Research Articles

                reliability,interface health,cerium,green inhibitor,ph,high-voltage insulator

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