One-Pot Synthesis of α-Amino Acids from Imines through CO2 Incorporation: An Alternative Method for Strecker Synthesis

Mita, Tsuyoshi; Chen, Jianyang; Sugawara, Masumi; Sato, Yoshihiro

doi:10.1002/ange.201006422

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One-Pot Synthesis of α-Amino Acids from Imines through CO2 Incorporation: An Alternative Method for Strecker Synthesis

Author(s): Tsuyoshi Mita , Jianyang Chen , Masumi Sugawara , Yoshihiro Sato

Publication date Created: February 07 2011

Publication date (Print): February 07 2011

Journal: Angewandte Chemie

Publisher: Wiley-Blackwell

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Transformation of carbon dioxide.

Toshiyasu Sakakura, Jun-Chul Choi, Hiroyuki Yasuda (2007)

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Carboxylation of C-H bonds using N-heterocyclic carbene gold(I) complexes.

Ine Boogaerts, Steven P. Nolan (2010)

A highly efficient [(NHC)Au(I)]-based (NHC = N-heterocyclic carbene) catalytic system for the carboxylation of aromatic and heteroaromatic C-H bonds was developed. The significant base strength of the Au-OH species is at the origin of the activation process and permits the facile functionalization of C-H bonds without the use of other organometallic reagents.