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      “Lantern-Shaped” Platinum(III) Complexes with Axially Bound 9-Ethylguanine or 1-Methylcytosine (L) of General Formula [Pt 2{HN=C(Bu t)O} 4L 2](NO 3) 2

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          Abstract

          The synthesis, NMR characterization, and X-ray crystallography of “lantern-shaped” platinum(III) complexes with four pivaloamidate bridging ligands and two 9-ethylguanines (9-EtG) or 1-methylcytosines (1-MeC) in axial positions are reported: cis-N 2O 2-[Pt 2{HN=C(Bu t)O} 4(9-EtG) 2](NO 3) 2 and cis-N 2O 2-[Pt 2{HN=C(Bu t)O} 4(1-MeC) 2](NO 3) 2. The last complex is, to the best of our knowledge, the first dinuclear compound of platinum(III) with axially bound 1-MeC.

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          WinGXsuite for small-molecule single-crystal crystallography

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            Encoding and decoding hydrogen-bond patterns of organic compounds

            Margaret C. Etter (2002)
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              PARST95 – an update to PARST: a system of Fortran routines for calculating molecular structure parameters from the results of crystal structure analyses

              M. Nardelli (1995)
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                Author and article information

                Journal
                Journal ID (nlm-ta): Bioinorg Chem Appl
                Journal ID (publisher-id): BCA
                Title: Bioinorganic Chemistry and Applications
                Publisher: Hindawi Publishing Corporation
                ISSN (Print): 1565-3633
                ISSN (Electronic): 1687-479X
                Publication date (Print): 2010
                Publication date (Electronic): 8 June 2010
                Volume: 2010
                Electronic Location Identifier: 102863
                Affiliations
                Dipartimento Farmaco-Chimico, Università degli Studi di Bari, Via E. Orabona 4, 70125 Bari, Italy
                Author notes

                Academic Editor: Spyros Perlepes

                Article
                DOI: 10.1155/2010/102863
                PMC ID: 2901605
                PubMed ID: 20631827
                SO-VID: c402cec8-9181-402f-b645-ba8b3f7d7f1b
                Copyright © Copyright © 2010 Concetta Pacifico et al.
                License:

                This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

                History
                Date received : 27 January 2010
                Date accepted : 4 March 2010
                Categories
                Subject: Research Article

                ScienceOpen disciplines: Biochemistry
                Data availability:
                ScienceOpen disciplines: Biochemistry

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