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      Green Synthesis and Characterization of Biosilica Produced from Sugarcane Waste Ash

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      Journal of Chemistry
      Hindawi Limited

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          Abstract

          In this study, ash from sugarcane waste was used in the synthesis of biosilica using alkaline extraction followed by acid precipitation. Different parameters that could influence the silica particle synthesis were evaluated. The ash and synthesized biosilica were characterized by a combination of spectroscopic and chemical techniques such as XRD, XRF, SEM, particle size analyser, N 2 adsorption analysis, TGA, and FTIR. The best condition for biosilica production was achieved with fusion method and aging temperature of 80°C for 1 h during gel formation. X-ray powder diffraction pattern confirms the amorphous nature of synthesized silica. The purity of the prepared silica was 99% silica which was confirmed by means of XRF. The experimental data suggest that the sugarcane waste ash could be converted into a value-added product, minimizing the environmental impact of disposal problems.

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          Pozzolanic activity and filler effect of sugar cane bagasse ash in Portland cement and lime mortars

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              Use of Brazilian sugarcane bagasse ash in concrete as sand replacement.

              Sugarcane today plays a major role in the worldwide economy, and Brazil is the leading producer of sugar and alcohol, which are important international commodities. The production process generates bagasse as a waste, which is used as fuel to stoke boilers that produce steam for electricity cogeneration. The final product of this burning is residual sugarcane bagasse ash (SBA), which is normally used as fertilizer in sugarcane plantations. Ash stands out among agroindustrial wastes because it results from energy generating processes. Many types of ash do not have hydraulic or pozzolanic reactivity, but can be used in civil construction as inert materials. The present study used ash collected from four sugar mills in the region of São Carlos, SP, Brazil, which is one of the world's largest producers of sugarcane. The ash samples were subjected to chemical characterization, sieve analysis, determination of specific gravity, X-ray diffraction, scanning electron microscopy, and solubilization and leaching tests. Mortars and concretes with SBA as sand replacement were produced and tests were carried out: compressive strength, tensile strength and elastic modulus. The results indicated that the SBA samples presented physical properties similar to those of natural sand. Several heavy metals were found in the SBA samples, indicating the need to restrict its use as a fertilizer. The mortars produced with SBA in place of sand showed better mechanical results than the reference samples. SBA can be used as a partial substitute of sand in concretes made with cement slag-modified Portland cement.
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                Author and article information

                Journal
                Journal of Chemistry
                Journal of Chemistry
                Hindawi Limited
                2090-9063
                2090-9071
                2017
                2017
                : 2017
                :
                : 1-9
                Article
                10.1155/2017/6129035
                ca9e4ac7-762a-4865-8e76-9d7d2ab68be1
                © 2017

                http://creativecommons.org/licenses/by/4.0/

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